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Abstract:

Manganese-doped CdS/ZnS quantum dots have been used as energy donors in a Förster-like resonance energy transfer (FRET) process to enhance the effective lifetime of organic fluorophores. It was possible to tune the effective lifetime of the fluorophores by about six orders of magnitude from the nanosecond (ns) up to the millisecond (ms) region. Undoped and Mn-doped CdS/ZnS quantum dots functionalized with different dye molecules were selected as a model system for investigating the multiple energy transfer process and the specific interaction between Mn ions and the attached dye molecules. While the lifetime of the free dye molecules was about 5 ns, their linking to undoped CdS/ZnS quantum dots led to a long effective lifetime of about 150 ns, following a non-exponential transient. Manganese-doped core-shell quantum dots further enhanced the long-lasting decay time of the dye to several ms. This opens up a pathway to analyse different fluorophores in the time domain with equal spectral emissions. Such lifetime multiplexing would be an interesting alternative to the commonly used spectral multiplexing in fluorescence detection schemes. © 2016 IOP Publishing Ltd.

Registro:

Documento: Artículo
Título:Förster resonance energy transfer mediated enhancement of the fluorescence lifetime of organic fluorophores to the millisecond range by coupling to Mn-doped CdS/ZnS quantum dots
Autor:Kaiser, U.; Sabir, N.; Carrillo-Carrion, C.; Del Pino, P.; Bossi, M.; Heimbrodt, W.; Parak, W.J.
Filiación:Department of Physics and Material Sciences Center (WZMW), Philipps-University Marburg, Renthof 5, Marburg, D-35032, Germany
CIC BiomaGUNE, Paseo de Miramón 182, Donostia - San Sebastián, 20009, Spain
CONICET, Piso3, Ciudad Universitaria, Pabellón 2, Buenos Aires, Argentina
Palabras clave:energy transfer; quantum dots; time-resolved fluorescence; Cadmium sulfide; Energy transfer; Fluorescence; Manganese; Molecules; Multiplexing; Nanocrystals; Semiconductor quantum dots; Core-shell quantum dots; Energy transfer process; Fluorescence detection; Fluorescence lifetimes; Resonance energy transfer; Specific interaction; Spectral multiplexing; Time-resolved fluorescence; Fluorophores
Año:2015
Volumen:27
Número:5
DOI: http://dx.doi.org/10.1088/0957-4484/27/5/055101
Título revista:Nanotechnology
Título revista abreviado:Nanotechnology
ISSN:09574484
CODEN:NNOTE
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09574484_v27_n5_p_Kaiser

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Citas:

---------- APA ----------
Kaiser, U., Sabir, N., Carrillo-Carrion, C., Del Pino, P., Bossi, M., Heimbrodt, W. & Parak, W.J. (2015) . Förster resonance energy transfer mediated enhancement of the fluorescence lifetime of organic fluorophores to the millisecond range by coupling to Mn-doped CdS/ZnS quantum dots. Nanotechnology, 27(5).
http://dx.doi.org/10.1088/0957-4484/27/5/055101
---------- CHICAGO ----------
Kaiser, U., Sabir, N., Carrillo-Carrion, C., Del Pino, P., Bossi, M., Heimbrodt, W., et al. "Förster resonance energy transfer mediated enhancement of the fluorescence lifetime of organic fluorophores to the millisecond range by coupling to Mn-doped CdS/ZnS quantum dots" . Nanotechnology 27, no. 5 (2015).
http://dx.doi.org/10.1088/0957-4484/27/5/055101
---------- MLA ----------
Kaiser, U., Sabir, N., Carrillo-Carrion, C., Del Pino, P., Bossi, M., Heimbrodt, W., et al. "Förster resonance energy transfer mediated enhancement of the fluorescence lifetime of organic fluorophores to the millisecond range by coupling to Mn-doped CdS/ZnS quantum dots" . Nanotechnology, vol. 27, no. 5, 2015.
http://dx.doi.org/10.1088/0957-4484/27/5/055101
---------- VANCOUVER ----------
Kaiser, U., Sabir, N., Carrillo-Carrion, C., Del Pino, P., Bossi, M., Heimbrodt, W., et al. Förster resonance energy transfer mediated enhancement of the fluorescence lifetime of organic fluorophores to the millisecond range by coupling to Mn-doped CdS/ZnS quantum dots. Nanotechnology. 2015;27(5).
http://dx.doi.org/10.1088/0957-4484/27/5/055101