Artículo

Alcober, C.; Bilmes, S.A.; Calvo, E.; Posadas, D. "Underpotential deposition and dielectric electronegativity scale" (1994) Journal of the Chemical Society, Faraday Transactions. 90(16):2395-2399
Estamos trabajando para incorporar este artículo al repositorio
Consulte el artículo en la página del editor
Consulte la política de Acceso Abierto del editor

Abstract:

The in situ differential reflectance spectrum of a polycrystalline gold electrode in 1 mol dm -3 HClO 4 solutions as a function of coverage of Pb, Ag and Cu adatoms, has been measured in the visible region. The optical response of the metal modified surfaces was analysed through correlations with parameters related to the electronic properties of the surface such as the electronic work function difference between the substrate and the metal adatoms and the dielectric electronegativity difference. A reasonable correlation between the interband threshold and the dielectric electronegativity difference was found.

Registro:

Documento: Artículo
Título:Underpotential deposition and dielectric electronegativity scale
Autor:Alcober, C.; Bilmes, S.A.; Calvo, E.; Posadas, D.
Filiación:Departamento de Química Inorgánica, Analítica y Quimica Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, 1428 Buenos Aires, Argentina
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas (INIFTA), Facultad de Ciencias Exactas, Universidad Nacional de la Plata, Casilla de Correo 16, 1900 La Plata, Argentina
Año:1994
Volumen:90
Número:16
Página de inicio:2395
Página de fin:2399
DOI: http://dx.doi.org/10.1039/FT9949002395
Título revista:Journal of the Chemical Society, Faraday Transactions
ISSN:09565000
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09565000_v90_n16_p2395_Alcober

Referencias:

  • Kolb, D.M., (1978) Advances in Electrochemistry and Electrochemical Engineering, 11. , H. Gerischer, C. W. Tobias, Wiley, New York
  • Jüttner, K., (1986) Electrochim. Acta, 31, p. 917
  • Adzic, R.R., (1984) Advances in Electrochemistry and Electrochemical Engineering, 13. , H. Herischer, C. W. Tobias, Wiley, New York
  • Leiva, E.P.M., Schmickler, W., (1989) Chem. Phys. Lett., 160, p. 75
  • Leiva, E.P.M., (1993) J. Electroanal. Chem., 350, p. 1
  • Szabò, S., (1991) Int. Rev. Phys. Chem., 10, p. 207
  • Motoo, S., (1984) Proceedings of the Symposium on the Chemistry and Physics of Electrocatalysis, p. 331. , J. E. D. McIntyre, M. J. Weaver, E. B. Yeager, The Electrochemical Society, Princeton
  • Feliu, J.M., (1992) 43rd ISE Meeting, , Cordoba, Argentina, Abstract IL 1-10
  • Kolb, D.M., Przansnyski, M., Gerischer, H., (1974) J. Electroanal. Chem., 54, p. 25
  • Trasatti, S., (1975) Z. Phys. Chem. N F, 98, p. 75
  • Kolb, D.M., Leutloff, D., Przasnyski, M., (1975) Surf. Sci., 47, p. 622
  • Pauling, L., (1960) The Nature of Chemical Bond, , Cornell University Press, Ithaca
  • Vijh, A.K., (1974) Surf. Sci., 46, p. 282
  • Kolb, D.M., Gerischer, H., (1975) Surf. Sci., 51, p. 323
  • Trasatti, S., (1977) Advances in Electrochemistry and Electrochemical Engineering, 10, p. 213. , H. Gerischer, C. W. Tobias, Wiley, New York
  • Abelès, F., (1972) Optical Properties of Solids, , Ch. 3, ed. F. Abelès, North Holland, Amsterdam
  • Mott, N.F., Jones, H., (1936) The Theory of the Properties of Metals and Alloys, , Oxford University Press
  • Cooper, B.R., Ehrenreich, H., Philipp, H.R., (1965) Phys. Rev., 138A, p. 494
  • Kolb, D.M., Kötz, R., Yamamoto, K., (1979) Surf. Sci., 87, p. 20
  • Takamura, K., Watanabe, F., Takamura, T., (1981) Electrochim. Acta, 26, p. 979
  • Adzic, R., Yeager, E., Cahan, B.D., (1974) J. Electrochem. Soc., 121, p. 474
  • Adzic, R., Jovancicevic, V., Podlavicky, M., (1980) Electrochim. Acta, 25, p. 1143
  • Takamura, T., Sato, Y., (1975) J. Electroanal. Chem., 47, p. 622
  • McIntyre, J.D.E., Aspnes, D.E., (1971) Surf. Sci., 24, p. 417
  • Bennett, A.J., Penn, D., (1975) Phys. Rev. B, 11, p. 3644
  • Lazorenko-Manevich, R.M., Brick, E.B., Kolotyrkin, Y.M., (1975) Electrochim. Acta, 22, p. 151
  • Brodskii, A.M., Urbakh, M.I., (1979) Sov. Electrochem., 15, p. 819
  • Phillips, J.C., (1970) Rev. Modern. Phys., 42, p. 317
  • Van Vechten, J.A., (1969) Phys. Rev., 182, p. 891
  • Phillips, J.C., (1973) Surf. Sci., 37, p. 2
  • Romeo, F.M., Tucceri, R.I., Posadas, D., (1988) Surf. Sci., 203, p. 186
  • Cahan, B.D., Horkans, J., Yeager, E., (1970) Symp. Faraday Soc., 4, p. 36
  • Trassatti, S., (1971) J. Electroanal. Chem., 33, p. 351
  • Van Huong, N., Clavilier, J., (1971) C. R. Acad. Sci., 272, p. 1404
  • Lezna, R.O., de Tacconi, N.R., Rapallini, J.A., Arvia, A.J., (1988) An. Asoc. Quim. Argent., 76, p. 25
  • Tourillon, G., Gouan, D., Tadjeddine, A., (1990) J. Electroanal. Chem., 289, p. 263
  • Tadjeddine, A., Gouan, D., Ladouceur, M., Tourillon, G., (1991) Phys. Rev. Lett., 66, p. 2235
  • Penn, D., (1962) Phys. Rev., 128, p. 2093
  • Gyftopoulos, E.P., Levine, J.D., (1962) J. Appl. Phys., 33, p. 67

Citas:

---------- APA ----------
Alcober, C., Bilmes, S.A., Calvo, E. & Posadas, D. (1994) . Underpotential deposition and dielectric electronegativity scale. Journal of the Chemical Society, Faraday Transactions, 90(16), 2395-2399.
http://dx.doi.org/10.1039/FT9949002395
---------- CHICAGO ----------
Alcober, C., Bilmes, S.A., Calvo, E., Posadas, D. "Underpotential deposition and dielectric electronegativity scale" . Journal of the Chemical Society, Faraday Transactions 90, no. 16 (1994) : 2395-2399.
http://dx.doi.org/10.1039/FT9949002395
---------- MLA ----------
Alcober, C., Bilmes, S.A., Calvo, E., Posadas, D. "Underpotential deposition and dielectric electronegativity scale" . Journal of the Chemical Society, Faraday Transactions, vol. 90, no. 16, 1994, pp. 2395-2399.
http://dx.doi.org/10.1039/FT9949002395
---------- VANCOUVER ----------
Alcober, C., Bilmes, S.A., Calvo, E., Posadas, D. Underpotential deposition and dielectric electronegativity scale. 1994;90(16):2395-2399.
http://dx.doi.org/10.1039/FT9949002395