Artículo

Gisele, G.V.; Montenegro, A.C.; Tudino, M.B.; Lavado, R.S.; Molina, F.V. "Time evolution of Pb(II) speciation in Pampa soil fractions" (2014) Chemical Speciation and Bioavailability. 26(4):210-218
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Abstract:

Soil pollution by heavy metals, particularly lead, is an important environmental concern; the bioavailability of such pollutants is strongly dependent on their chemical form. Here, the speciation of Pb(II) in soil fractions as a function of time shortly after its incorporation is studied, using a selective sequential extraction method. The sample came from an Argentinean Pampas region and was extensively characterised, including Rietveld analysis of the silt+clay fraction XRD pattern to find the major mineral components. Experiments were run twice, once in the winter and once in the summer. The results show different speciation time profiles in both cases, showing faster changes in winter due to the higher water content. The summer experiment corresponds to an earlier stage in the speciation profile evolution compared with winter. The soluble/exchangeable fraction decreases with time in summer but shows a lower and constant value in the winter. A high proportion is found to be adsorbed onto the stable (aluminosilicates+quartz) mineral fraction. The results strongly suggest that, even at a short time following soil pollution with Pb, a high proportion is adsorbed onto the mineral fraction, with only a low fraction being bioavailable. The most stable (mineral incorporated) form is observed to increase with time. Soil water content appears to be more important than temperature in determining the differences between the two.

Registro:

Documento: Artículo
Título:Time evolution of Pb(II) speciation in Pampa soil fractions
Autor:Gisele, G.V.; Montenegro, A.C.; Tudino, M.B.; Lavado, R.S.; Molina, F.V.
Filiación:Instituto de Química Física de Materiales, Ambiente y Energía (INQUIMAE), Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina
Instituto de Investigaciones en Biociencias Agrícolas y Ambientales (INBA), Facultad de Agronomía, Universidad de Buenos Aires, Buenos Aires, Argentina
Palabras clave:Bioavailability of pollutants; Heavy metals; Sequential selective extraction
Año:2014
Volumen:26
Número:4
Página de inicio:210
Página de fin:218
DOI: http://dx.doi.org/10.3184/095422914X14142516366997
Título revista:Chemical Speciation and Bioavailability
Título revista abreviado:Chem. Speciation Bioavailab.
ISSN:09542299
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09542299_v26_n4_p210_Gisele

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Citas:

---------- APA ----------
Gisele, G.V., Montenegro, A.C., Tudino, M.B., Lavado, R.S. & Molina, F.V. (2014) . Time evolution of Pb(II) speciation in Pampa soil fractions. Chemical Speciation and Bioavailability, 26(4), 210-218.
http://dx.doi.org/10.3184/095422914X14142516366997
---------- CHICAGO ----------
Gisele, G.V., Montenegro, A.C., Tudino, M.B., Lavado, R.S., Molina, F.V. "Time evolution of Pb(II) speciation in Pampa soil fractions" . Chemical Speciation and Bioavailability 26, no. 4 (2014) : 210-218.
http://dx.doi.org/10.3184/095422914X14142516366997
---------- MLA ----------
Gisele, G.V., Montenegro, A.C., Tudino, M.B., Lavado, R.S., Molina, F.V. "Time evolution of Pb(II) speciation in Pampa soil fractions" . Chemical Speciation and Bioavailability, vol. 26, no. 4, 2014, pp. 210-218.
http://dx.doi.org/10.3184/095422914X14142516366997
---------- VANCOUVER ----------
Gisele, G.V., Montenegro, A.C., Tudino, M.B., Lavado, R.S., Molina, F.V. Time evolution of Pb(II) speciation in Pampa soil fractions. Chem. Speciation Bioavailab. 2014;26(4):210-218.
http://dx.doi.org/10.3184/095422914X14142516366997