Abstract:
There has been substantial renewed interest in negative thermal expansion following the discovery that cubic ZrW2O8 contracts over a temperature range in excess of 1000 K. Substances of many different kinds show negative thermal expansion, especially at low temperatures. In this article we review the underlying thermodynamics, emphasizing the roles of thermal stress and elasticity. We also discuss vibrational and non-vibrational mechanisms operating on the atomic scale that are responsible for negative expansion, both isotropic and anisotropic, in a wide range of materials.
Registro:
Documento: |
Artículo
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Título: | Negative thermal expansion |
Autor: | Barrera, G.D.; Bruno, J.A.O.; Barron, T.H.K.; Allan, N.L. |
Filiación: | Departamento de Química, Univ. Nacional de la Patagonia SJB, Ciudad Universitaria, 9000 Cotnodoro Rivadavia, Argentina Universidad de Buenos Aires, Fac. de Ciencias Exactas y Naturales, Ciudad Universitaria, Pabellón 2, 1428 Buenos Aires, Argentina School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, United Kingdom
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Palabras clave: | Anisotropy; Computer simulation; Dilatometers; Elasticity; Electronic structure; Free energy; Lattice vibrations; Mathematical models; Microstructure; Molecular dynamics; Perturbation techniques; Specific heat; Thermal stress; Thermodynamics; Thin films; Isotropy; Multilayer relaxations; Negative thermal expansion; Vibrational mechanisms; Thermal expansion |
Año: | 2005
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Volumen: | 17
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Número: | 4
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Página de inicio: | R217
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Página de fin: | R252
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DOI: |
http://dx.doi.org/10.1088/0953-8984/17/4/R03 |
Título revista: | Journal of Physics Condensed Matter
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Título revista abreviado: | J Phys Condens Matter
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ISSN: | 09538984
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CODEN: | JCOME
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09538984_v17_n4_pR217_Barrera |
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Citas:
---------- APA ----------
Barrera, G.D., Bruno, J.A.O., Barron, T.H.K. & Allan, N.L.
(2005)
. Negative thermal expansion. Journal of Physics Condensed Matter, 17(4), R217-R252.
http://dx.doi.org/10.1088/0953-8984/17/4/R03---------- CHICAGO ----------
Barrera, G.D., Bruno, J.A.O., Barron, T.H.K., Allan, N.L.
"Negative thermal expansion"
. Journal of Physics Condensed Matter 17, no. 4
(2005) : R217-R252.
http://dx.doi.org/10.1088/0953-8984/17/4/R03---------- MLA ----------
Barrera, G.D., Bruno, J.A.O., Barron, T.H.K., Allan, N.L.
"Negative thermal expansion"
. Journal of Physics Condensed Matter, vol. 17, no. 4, 2005, pp. R217-R252.
http://dx.doi.org/10.1088/0953-8984/17/4/R03---------- VANCOUVER ----------
Barrera, G.D., Bruno, J.A.O., Barron, T.H.K., Allan, N.L. Negative thermal expansion. J Phys Condens Matter. 2005;17(4):R217-R252.
http://dx.doi.org/10.1088/0953-8984/17/4/R03