Abstract:
Lipase B from Candida antarctica catalyzed regioselectively the polyesterification of glycerol and adipic acid. UV-MALDI-TOF-MS analysis of the polymers shows low molecular weight polyesters (1314-1716) with very narrow polydispersities (1.0-1.2).
Registro:
Documento: |
Artículo
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Título: | A simple enzymatic procedure for the synthesis of a hydroxylated polyester from glycerol and adipic acid |
Autor: | Iglesias, L.E.; Fukuyama, Y.; Nonami, H.; Erra-Balsells, R.; Baldessari, A. |
Filiación: | Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria, 1428 Buenos Aires, Argentina Plant Biophysics/Biochemistry Research Laboratory, College of Agriculture, Ehime University, 3-5-7 Tarumi, Matsuyama 790-8566, Japan Centra de Estudios e Investigaciones, Universidad Nacional de Quilmes, Roque Sáenz Peña 180, 1876 Bernal, Prov. de Buenos Aires, Argentina
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Palabras clave: | Enzymatic polymerization; Lipase; Regioselectivity; UV-MALDI-TOF-MS; adipic acid; catalysis; enzymic esterification; glycerol; hydroxylation; lipase B; mass spectrometry; molecular weight; polymer; Candida antarctica |
Año: | 1999
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Volumen: | 13
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Número: | 12
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Página de inicio: | 923
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Página de fin: | 926
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DOI: |
http://dx.doi.org/10.1023/A:1008958212814 |
Título revista: | Biotechnology Techniques
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Título revista abreviado: | Biotechnol. Tech.
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ISSN: | 0951208X
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CODEN: | BTECE
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0951208X_v13_n12_p923_Iglesias |
Referencias:
- Chaudhary, A.K., Beckman, E.J., Russell, A.J., Enzymes for polyester synthesis (1996) Enzymes in Polymer Synthesis, , Gross RA, Kaplan DL, Swift G, eds. Ch. 2, Washington: ACS
- Dordick, J.S., (1992) Trends Biotech., 19, pp. 287-293
- Kaplan, D.L., Dordick, J., Gross, R.A., Swift, G., Enzymes in polymer science: An introduction (1996) Enzymes in Polymer Synthesis, , Gross RA, Kaplan DI, Swift G, eds. Ch. 1, Washington: ACS
- Kline, B.J., Beckman, E.J., Russell, A.J., (1998) J. Am. Chem. Soc., 120, pp. 9475-9480
- Kobayashi, S., Uyama, H., Enzymatic polymerization for synthesis of polyesters and polyaromatics (1996) Enzymes in Polymer Synthesis, , Gross RA, Kaplan DL, Swift G, eds. Ch. 3, Washington: ACS
- Margolin, A.L., Crenne, J.-Y., Klibanov, A.M., (1987) Tetrahedron Lett., 28, pp. 1607-1610
- Nonami, H., Fukui, S., Erra-Balsells, R., (1997) J. Mass Spectrom., 32, pp. 287-296
- Nonami, H., Tanaka, K., Fukuyama, Y., Erra-Balsells, R., (1998) Rapid Commun. Mass Spect., 12, pp. 285-296
- Park, H.G., Chang, H.N., Dordick, J.S., (1994) Biocatalysis, 11, pp. 263-271
- (1992) Ulmann's Encyclopedia of Industrial Chemistry, A21, p. 227. , Weinheim, Germany: VCH
- Wallace, J.S., Morrow, C.J., (1989) J. Polym. Sci. Part A: Polym.Chem., 27, pp. 2553-2567
Citas:
---------- APA ----------
Iglesias, L.E., Fukuyama, Y., Nonami, H., Erra-Balsells, R. & Baldessari, A.
(1999)
. A simple enzymatic procedure for the synthesis of a hydroxylated polyester from glycerol and adipic acid. Biotechnology Techniques, 13(12), 923-926.
http://dx.doi.org/10.1023/A:1008958212814---------- CHICAGO ----------
Iglesias, L.E., Fukuyama, Y., Nonami, H., Erra-Balsells, R., Baldessari, A.
"A simple enzymatic procedure for the synthesis of a hydroxylated polyester from glycerol and adipic acid"
. Biotechnology Techniques 13, no. 12
(1999) : 923-926.
http://dx.doi.org/10.1023/A:1008958212814---------- MLA ----------
Iglesias, L.E., Fukuyama, Y., Nonami, H., Erra-Balsells, R., Baldessari, A.
"A simple enzymatic procedure for the synthesis of a hydroxylated polyester from glycerol and adipic acid"
. Biotechnology Techniques, vol. 13, no. 12, 1999, pp. 923-926.
http://dx.doi.org/10.1023/A:1008958212814---------- VANCOUVER ----------
Iglesias, L.E., Fukuyama, Y., Nonami, H., Erra-Balsells, R., Baldessari, A. A simple enzymatic procedure for the synthesis of a hydroxylated polyester from glycerol and adipic acid. Biotechnol. Tech. 1999;13(12):923-926.
http://dx.doi.org/10.1023/A:1008958212814