Abstract:
Mechanical dynamic measurements were used in this work to analyze the behavior of cured, carbon black-filled NR/SBR blends using a sulfur/accelerator system. The loss tangent (tan δ) of the compounds was studied in the frequency range between 10-3 and 10 Hz and temperatures between 80 and 260 K. Measurements were performed with an automated sub-resonant forced pendulum. A new model was applied to loss tangent data, based on the consideration of the phase network. A secondary transition (β relaxation) appears in the blends at temperatures between 100 K and 160 K, in addition to the glass transition. This peak is analyzed in terms of the rotation of the cis and vinyl units from butadiene of SBR.
Registro:
Documento: |
Artículo
|
Título: | Influence of the blend composition in the internal friction of NR/SBR compounds |
Autor: | Ghilarducci, A.; Cerveny, S.; Salva, H.; Matteo, C.L.; Marzocca, A.J. |
Filiación: | Pab. 1, Ciudad Universitaria, 1428 Buenos Aires, Argentina
|
Palabras clave: | Automated subresonant forced pendulum; NR/SBR blends; Sulfur/accelerator system; Butadiene; Carbon black; Composition effects; Curing; Glass transition; Internal friction; Relaxation processes; Rubber; Styrene; Temperature; Automated subresonant forced pendulum; Loss tangent; Phase network; Polymer blends |
Año: | 2001
|
Volumen: | 54
|
Número: | 7-8
|
Página de inicio: | 382
|
Página de fin: | 386
|
Título revista: | KGK-Kautschuk und Gummi Kunststoffe
|
Título revista abreviado: | KGK Kautsch Gummi Kunstst
|
ISSN: | 09483276
|
CODEN: | KGUKA
|
Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09483276_v54_n7-8_p382_Ghilarducci |
Referencias:
- Vilgis, T.A., Heinrich, G., (1995) Kautschuk Gummi Kunststoffe, 48, p. 323
- Sircar, A.K., (1997) Thermal Characterization of Polymeric Materials, p. 887. , (Ed. Turi, E.A.), Academic Press, California
- Yoshimura, N., Fujimoto, K., (1968) Rubber Chem. Technol., 41, p. 1009
- Fujimoto, K., Yoshimura, N., (1968) Rubber Chem. Technol., 41, p. 669
- Marzocca, A.J., Cerveny, S., Méndez, J., (2000) Polymer Int, 49, p. 216
- Klüppel, M., Schuster, R.H., Schaper, J., (1999) Rubber Chem. Technol., 72, p. 91
- D'Anna, G., Benoit, W., (1990) Rev. Sci. Instrum., 61, p. 3821
- Payne, A.R., (1965) Reinforcement of Elastomers, p. 69. , J. Wiley and Sons, New York
- Sircar, A.K., Galaske, M.L., Rodriguez, R., Chartoff, R.P., (1999) Rubber Chem. Technol., 72, p. 513
- Jha, A., Bhowmick, A.K., (1997) Rubber Chem and Technol, 70, p. 798
- Morbitzer, L., Ott, K.H., Schuster, H., Krank, D., (1972) Angew. Makromol. Chem., 7, p. 57
- Mc Crum, N.C., (1958) J. Polymer Sci., 27, p. 555
- Stauffer, D., Aharony, A., (1992) Introduction to Percolation Theory, , Taylor and Francis, London
- Ferry, J.D., (1980) Viscoelastic Properties of Polymers, , J. Wiley & Sons, New York
- Schaefer, R.J., (1995) Rubber Word, p. 18
- Cerveny, S., Ghilarducci, A., Salva, H., Marzocca, A.J., (2000) Polymer, 41, p. 2227
- Cerveny, S., (2000), Doctoral PhD Thesis, University of Buenos Aires
Citas:
---------- APA ----------
Ghilarducci, A., Cerveny, S., Salva, H., Matteo, C.L. & Marzocca, A.J.
(2001)
. Influence of the blend composition in the internal friction of NR/SBR compounds. KGK-Kautschuk und Gummi Kunststoffe, 54(7-8), 382-386.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09483276_v54_n7-8_p382_Ghilarducci [ ]
---------- CHICAGO ----------
Ghilarducci, A., Cerveny, S., Salva, H., Matteo, C.L., Marzocca, A.J.
"Influence of the blend composition in the internal friction of NR/SBR compounds"
. KGK-Kautschuk und Gummi Kunststoffe 54, no. 7-8
(2001) : 382-386.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09483276_v54_n7-8_p382_Ghilarducci [ ]
---------- MLA ----------
Ghilarducci, A., Cerveny, S., Salva, H., Matteo, C.L., Marzocca, A.J.
"Influence of the blend composition in the internal friction of NR/SBR compounds"
. KGK-Kautschuk und Gummi Kunststoffe, vol. 54, no. 7-8, 2001, pp. 382-386.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09483276_v54_n7-8_p382_Ghilarducci [ ]
---------- VANCOUVER ----------
Ghilarducci, A., Cerveny, S., Salva, H., Matteo, C.L., Marzocca, A.J. Influence of the blend composition in the internal friction of NR/SBR compounds. KGK Kautsch Gummi Kunstst. 2001;54(7-8):382-386.
Available from: https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09483276_v54_n7-8_p382_Ghilarducci [ ]