Abstract:
Demetalation of zinc 5,10,15,20-tetraphenylporphyrin (ZnTPP) under acidic conditions and ion exchange with Cu2+ions at neutral pH are both rapid reactions in the liquid medium. However, for ZnTPP monolayers adsorbed on a Au(111) surface exposed to aqueous solution, we find that, although ion exchange takes place rapidly as expected, demetalation does not occur, even at pH values as low as 0. Based on this, we conclude that metal center exchange on the surface does not proceed through a free-base porphyrin as an intermediate. Furthermore, once formed, CuTPP is stable on the surface and the reverse exchange from CuTPP to ZnTPP in the presence of Zn2+ions could not be achieved. The preference for copper is so strong that even an attempt to exchange adsorbed ZnTPP with Ni2+ions in the presence of traces of Cu2+yielded CuTPP rather than NiTPP. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Registro:
Documento: |
Artículo
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Título: | Zinc Porphyrin Metal-Center Exchange at the Solid–Liquid Interface |
Autor: | Franke, M.; Marchini, F.; Jux, N.; Steinrück, H.-P.; Lytken, O.; Williams, F.J. |
Filiación: | Institute of Physical Chemistry II, Friedrich-Alexander-University Erlangen-Nürnberg, Erlangen, Germany Department of Inorganic, Analytical and Physical Chemistry, University of Buenos Aires, Buenos Aires, Argentina Institute of Organic Chemistry II, Friedrich-Alexander-University Erlangen-Nürnberg, Erlangen, Germany
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Palabras clave: | ion exchange; metalation; porphyrins; solid–liquid interfaces; zinc; Ions; Liquids; Phase interfaces; Porphyrins; Solutions; Zinc; Zinc compounds; Acidic conditions; Au(111) surfaces; Free base porphyrins; Metal centers; Metalations; Rapid reactions; Solid-liquid interfaces; Zinc porphyrins; Ion exchange |
Año: | 2016
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Volumen: | 22
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Número: | 25
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Página de inicio: | 8520
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Página de fin: | 8524
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DOI: |
http://dx.doi.org/10.1002/chem.201600634 |
Título revista: | Chemistry - A European Journal
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Título revista abreviado: | Chem. Eur. J.
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ISSN: | 09476539
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CODEN: | CEUJE
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09476539_v22_n25_p8520_Franke |
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Citas:
---------- APA ----------
Franke, M., Marchini, F., Jux, N., Steinrück, H.-P., Lytken, O. & Williams, F.J.
(2016)
. Zinc Porphyrin Metal-Center Exchange at the Solid–Liquid Interface. Chemistry - A European Journal, 22(25), 8520-8524.
http://dx.doi.org/10.1002/chem.201600634---------- CHICAGO ----------
Franke, M., Marchini, F., Jux, N., Steinrück, H.-P., Lytken, O., Williams, F.J.
"Zinc Porphyrin Metal-Center Exchange at the Solid–Liquid Interface"
. Chemistry - A European Journal 22, no. 25
(2016) : 8520-8524.
http://dx.doi.org/10.1002/chem.201600634---------- MLA ----------
Franke, M., Marchini, F., Jux, N., Steinrück, H.-P., Lytken, O., Williams, F.J.
"Zinc Porphyrin Metal-Center Exchange at the Solid–Liquid Interface"
. Chemistry - A European Journal, vol. 22, no. 25, 2016, pp. 8520-8524.
http://dx.doi.org/10.1002/chem.201600634---------- VANCOUVER ----------
Franke, M., Marchini, F., Jux, N., Steinrück, H.-P., Lytken, O., Williams, F.J. Zinc Porphyrin Metal-Center Exchange at the Solid–Liquid Interface. Chem. Eur. J. 2016;22(25):8520-8524.
http://dx.doi.org/10.1002/chem.201600634