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Abstract:

In this communication, we review the details of the oxygen electroreduction reaction on rust layers, passive iron and well defined iron oxides as cathodes for the reaction. In particular, we highlight the important electrocatalytic role of Fe(II) sites at the surface of the oxides in contact with the aqueous electrolyte. When the same reaction takes place at bifunctional cathodes with separated metal anodes which gives rise to metal-air batteries on which much attention has been paid recently in connection with electric vehicles. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Registro:

Documento: Artículo
Título:The kinetics of oxygen electroreduction: A long way from iron rust to lithium-air batteries
Autor:Calvo, E.J.
Filiación:Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria, Pabellón 2, AR-1428 Buenos Aires, Argentina
Palabras clave:Electrolytic reduction; Oxygen; Aqueous electrolyte; Bi-functional; Electrocatalytic; Lithium-air battery; Metal anodes; Metal-air battery; Oxygen electro reductions; Oxygen electroreduction reactions; Cathodes
Año:2014
Volumen:65
Número:4
Página de inicio:345
Página de fin:350
DOI: http://dx.doi.org/10.1002/maco.201407614
Título revista:Materials and Corrosion
Título revista abreviado:Mater. Corros.
ISSN:09475117
CODEN:WSKRA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09475117_v65_n4_p345_Calvo

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Citas:

---------- APA ----------
(2014) . The kinetics of oxygen electroreduction: A long way from iron rust to lithium-air batteries. Materials and Corrosion, 65(4), 345-350.
http://dx.doi.org/10.1002/maco.201407614
---------- CHICAGO ----------
Calvo, E.J. "The kinetics of oxygen electroreduction: A long way from iron rust to lithium-air batteries" . Materials and Corrosion 65, no. 4 (2014) : 345-350.
http://dx.doi.org/10.1002/maco.201407614
---------- MLA ----------
Calvo, E.J. "The kinetics of oxygen electroreduction: A long way from iron rust to lithium-air batteries" . Materials and Corrosion, vol. 65, no. 4, 2014, pp. 345-350.
http://dx.doi.org/10.1002/maco.201407614
---------- VANCOUVER ----------
Calvo, E.J. The kinetics of oxygen electroreduction: A long way from iron rust to lithium-air batteries. Mater. Corros. 2014;65(4):345-350.
http://dx.doi.org/10.1002/maco.201407614