Abstract:
In this communication, we review the details of the oxygen electroreduction reaction on rust layers, passive iron and well defined iron oxides as cathodes for the reaction. In particular, we highlight the important electrocatalytic role of Fe(II) sites at the surface of the oxides in contact with the aqueous electrolyte. When the same reaction takes place at bifunctional cathodes with separated metal anodes which gives rise to metal-air batteries on which much attention has been paid recently in connection with electric vehicles. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Registro:
Documento: |
Artículo
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Título: | The kinetics of oxygen electroreduction: A long way from iron rust to lithium-air batteries |
Autor: | Calvo, E.J. |
Filiación: | Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria, Pabellón 2, AR-1428 Buenos Aires, Argentina
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Palabras clave: | Electrolytic reduction; Oxygen; Aqueous electrolyte; Bi-functional; Electrocatalytic; Lithium-air battery; Metal anodes; Metal-air battery; Oxygen electro reductions; Oxygen electroreduction reactions; Cathodes |
Año: | 2014
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Volumen: | 65
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Número: | 4
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Página de inicio: | 345
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Página de fin: | 350
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DOI: |
http://dx.doi.org/10.1002/maco.201407614 |
Título revista: | Materials and Corrosion
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Título revista abreviado: | Mater. Corros.
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ISSN: | 09475117
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CODEN: | WSKRA
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09475117_v65_n4_p345_Calvo |
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Citas:
---------- APA ----------
(2014)
. The kinetics of oxygen electroreduction: A long way from iron rust to lithium-air batteries. Materials and Corrosion, 65(4), 345-350.
http://dx.doi.org/10.1002/maco.201407614---------- CHICAGO ----------
Calvo, E.J.
"The kinetics of oxygen electroreduction: A long way from iron rust to lithium-air batteries"
. Materials and Corrosion 65, no. 4
(2014) : 345-350.
http://dx.doi.org/10.1002/maco.201407614---------- MLA ----------
Calvo, E.J.
"The kinetics of oxygen electroreduction: A long way from iron rust to lithium-air batteries"
. Materials and Corrosion, vol. 65, no. 4, 2014, pp. 345-350.
http://dx.doi.org/10.1002/maco.201407614---------- VANCOUVER ----------
Calvo, E.J. The kinetics of oxygen electroreduction: A long way from iron rust to lithium-air batteries. Mater. Corros. 2014;65(4):345-350.
http://dx.doi.org/10.1002/maco.201407614