Artículo
Caballero, G.M.; Gros, E.G. "On the Mechanism of Cleavage of Thioacetals Promoted by Copper(II) Sulphate Adsorbed on Silica Gel" (1997) Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences. 52(9):1147-1151
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Abstract:
A probable mechanism of the cleavage reaction of thioacetals by copper(II) sulphate adsorbed on silica gel involves: formation of a chelate between sulphur atoms and copper(II), previously coordinated with hydroxyl groups on the silica surface, and the subsequent hydrolysis promoted by hydroxyl groups on the silica gel surface.
Registro:
| Documento: | Artículo |
| Título: | On the Mechanism of Cleavage of Thioacetals Promoted by Copper(II) Sulphate Adsorbed on Silica Gel |
| Autor: | Caballero, G.M.; Gros, E.G. |
| Filiación: | Depto. de Quim. Orgánica, Fac. de Ciencias Exactas y Naturales, Ciudad Universitaria, Pabellón 2, 1428 Buenos Aires, Argentina |
| Palabras clave: | Copper(II) Sulphate; Thioacetats |
| Año: | 1997 |
| Volumen: | 52 |
| Número: | 9 |
| Página de inicio: | 1147 |
| Página de fin: | 1151 |
| DOI: | http://dx.doi.org/10.1515/znb-1997-0921 |
| Título revista: | Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences |
| Título revista abreviado: | Z. Naturforsch. Sect. B J. Chem. Sci. |
| ISSN: | 09320776 |
| CODEN: | ZNBSE |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09320776_v52_n9_p1147_Caballero |
Referencias:
- Caballero, G.M., Gros, E.G., (1989) J. Chem. Res. (S), p. 320
- Caballero, G.M., Gros, E.G., (1995) Synth. Commun., 25, p. 395
- Nishiguchi, T., Asano, F., (1989) J. Org. Chem., 54, p. 1531
- Nishiguchi, T., Machina, N., Yamamoto, E., (1987) Tetrahedron Lett., 28, p. 4565
- Barton, D.H.R., Ollis, W.D., (1979) Comprehensive Organic Chemistry, 1, p. 718. , Pergamon Press, Oxford
- Murov, S.L., (1973) Handbook of Photochemistry, , Marcel Dekker Inc., New York
- El-Wassimy, M.T.M., Jorgensen, K.A., Lawesson, S.O., (1983) J. Chem. Soc., Perkin Trans. I, p. 2201
- Balogh, M., Cornelis, A., Laszlo, P., (1984) Tetrahedron Lett., 25, p. 3313
- Farwaha, R., De Mayo, P., Herman Schauble, J., Toong, Y.C., (1985) J. Org. Chem., 50, p. 245
- Mukaiyama, T., Maekawa, K., Narasaka, K., (1970) Tetrahedron Lett., 11, p. 4669
- Satchell, D.P.N., Satchell, R.S., (1987) J. Chem. Soc., Perkin Trans. 2, p. 513
- Williams, J.R., Sarkisian, G.M., (1974) Synthesis, p. 32
- Caballero, G.M., Gros, E.G., (1991) J. Lab. Comp. Radiopharm., 29, p. 805
Citas:
---------- APA ----------
Caballero, G.M. & Gros, E.G. (1997) . On the Mechanism of Cleavage of Thioacetals Promoted by Copper(II) Sulphate Adsorbed on Silica Gel. Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 52(9), 1147-1151.http://dx.doi.org/10.1515/znb-1997-0921
---------- CHICAGO ----------
Caballero, G.M., Gros, E.G. "On the Mechanism of Cleavage of Thioacetals Promoted by Copper(II) Sulphate Adsorbed on Silica Gel" . Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences 52, no. 9 (1997) : 1147-1151.http://dx.doi.org/10.1515/znb-1997-0921
---------- MLA ----------
Caballero, G.M., Gros, E.G. "On the Mechanism of Cleavage of Thioacetals Promoted by Copper(II) Sulphate Adsorbed on Silica Gel" . Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, vol. 52, no. 9, 1997, pp. 1147-1151.http://dx.doi.org/10.1515/znb-1997-0921
---------- VANCOUVER ----------
Caballero, G.M., Gros, E.G. On the Mechanism of Cleavage of Thioacetals Promoted by Copper(II) Sulphate Adsorbed on Silica Gel. Z. Naturforsch. Sect. B J. Chem. Sci. 1997;52(9):1147-1151.http://dx.doi.org/10.1515/znb-1997-0921
