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Abstract:

Activated carbons from invasive Parkinsonia aculeata wood sawdust were developed by microwave assisted H3PO4 acid activation varying the radiation time (2–10 min). Their main physicochemical characteristics were determined, and compared with those of a sample previously obtained by conventional heating using the same precursor, chemical agent, and impregnation ratio. The activated carbons developed for radiation times of 5 and 10 min showed higher BET surface areas (~1300 m2/g) and total pore volume (1 cm3/g) than those obtained at 2 min (~710 m2/g) or by conventional heating (~970 m2/g). Microwave assisted activation also led to activated carbons with higher total amounts of acidic oxygen and basic functionalities in comparison with the sample arising from conventional heating. Phenol adsorption capacity for all the samples was also evaluated from determination of the adsorption isotherms and their proper description by the Freundlich model. The adsorption capacity for the activated carbons obtained at 5 and 10 min was almost twice that measured for the samples prepared at 2 min and by conventional heating, in agreement with the higher BET surface areas characterizing the former. Compared with conventional heating, the process assistance by microwave energy not only reduced operation time, but also improved the characteristics of the resulting activated carbons. © 2016, Springer Science+Business Media New York.

Registro:

Documento: Artículo
Título:Development and characterization of microwave-assisted activated carbons from Parkinsonea aculeata wood
Autor:Nunell, G.V.; Fernandez, M.E.; Bonelli, P.R.; Cukierman, A.L.
Filiación:Programa de Investigación Y Desarrollo de Fuentes Alternativas de Materias Primas y Energía (PINMATE) - Departamento de Industrias, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires. Pabellón de Industrias, Intendente Güiraldes 2620. Ciudad Universitaria. (C1428BGA), Ciudad Autónoma de Buenos Aires, Argentina
Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Av. Rivadavia 1917. (C1033AAJ), Ciudad Autónoma de Buenos Aires, Argentina
Cátedra de Tecnología Farmacéutica II - Departamento de Tecnología Farmacéutica - Facultad de Farmacia y Bioquímica, Universidad de Buenos Aires, Junín 956. (C1113AAD), Ciudad Autónoma de Buenos Aires, Argentina
Palabras clave:Activated carbon; H3PO4 acid activation; Microwave assistance; Phenol adsorption; Adsorption; Chemical activation; Heating; Microwaves; Phenols; Acid activation; Adsorption capacities; Conventional heating; Impregnation ratios; Microwave energies; Parkinsonia aculeata; Phenol adsorption; Physicochemical characteristics; Activated carbon
Año:2016
Volumen:22
Número:3
Página de inicio:347
Página de fin:356
DOI: http://dx.doi.org/10.1007/s10450-016-9783-z
Título revista:Adsorption
Título revista abreviado:Adsorpt
ISSN:09295607
CODEN:ADSOF
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09295607_v22_n3_p347_Nunell

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Citas:

---------- APA ----------
Nunell, G.V., Fernandez, M.E., Bonelli, P.R. & Cukierman, A.L. (2016) . Development and characterization of microwave-assisted activated carbons from Parkinsonea aculeata wood. Adsorption, 22(3), 347-356.
http://dx.doi.org/10.1007/s10450-016-9783-z
---------- CHICAGO ----------
Nunell, G.V., Fernandez, M.E., Bonelli, P.R., Cukierman, A.L. "Development and characterization of microwave-assisted activated carbons from Parkinsonea aculeata wood" . Adsorption 22, no. 3 (2016) : 347-356.
http://dx.doi.org/10.1007/s10450-016-9783-z
---------- MLA ----------
Nunell, G.V., Fernandez, M.E., Bonelli, P.R., Cukierman, A.L. "Development and characterization of microwave-assisted activated carbons from Parkinsonea aculeata wood" . Adsorption, vol. 22, no. 3, 2016, pp. 347-356.
http://dx.doi.org/10.1007/s10450-016-9783-z
---------- VANCOUVER ----------
Nunell, G.V., Fernandez, M.E., Bonelli, P.R., Cukierman, A.L. Development and characterization of microwave-assisted activated carbons from Parkinsonea aculeata wood. Adsorpt. 2016;22(3):347-356.
http://dx.doi.org/10.1007/s10450-016-9783-z