Navegar

Colección

Datos Estadísticas

Artículo

Estamos trabajando para incorporar este artículo al repositorio
Consulte el artículo en la página del editor
Consulte la política de Acceso Abierto del editor

Abstract:

The biosorption of basic dyes, methylene blue and rhodamine B, from binary aqueous solutions onto cypress cone chips, was analyzed through mathematical modeling. This study aimed at introducing a novel model to predict the dynamic binary sorption of the dyes. It consisted of a modified Langmuir multicomponent isotherm coupled with a linear driving force model. Experimental data from recent studies using the untreated and alkaline-treated biosorbent was used to determine the model parameters, and the breakthrough predictions are in good agreement with the experimental results. Useful information on the effects of bed length and feed concentration on the breakthrough time and mass transfer length was obtained. This can guide the design and optimization of the biosorbent column. © 2015, Springer Science+Business Media New York.

Registro:

Documento: Artículo
Título:Modeling the biosorption of basic dyes from binary mixtures
Autor:Fernandez, M.E.; Bonelli, P.R.; Cukierman, A.L.; Lemcoff, N.O.
Filiación:Programa de Investigación y Desarrollo de Fuentes Alternativas de Materias Primas y Energía-PINMATE, Departamento de Industrias, Universidad de Buenos Aires, Ciudad Universitaria, Buenos Aires, Argentina
Department of Engineering and Science, Rensselaer Polytechnic Institute Hartford, 275 Windsor Street, Hartford, CT 06120, United States
Palabras clave:Basic dyes; Biosorption; Dynamic studies; Modeling; Aromatic compounds; Biosorption; Dyes; Mass transfer; Models; Sorption; Basic dyes; Binary aqueous solutions; Breakthrough time; Design and optimization; Dynamic studies; Feed concentration; Linear driving force; Multi-component isotherms; Binary mixtures
Año:2015
Volumen:21
Número:3
Página de inicio:177
Página de fin:183
DOI: http://dx.doi.org/10.1007/s10450-015-9660-1
Título revista:Adsorption
Título revista abreviado:Adsorpt
ISSN:09295607
CODEN:ADSOF
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09295607_v21_n3_p177_Fernandez

Referencias:

  • http://www.comsol.com/comsol-multiphysics, COMSOL: COMSOL Multiphysics, multipurpose software platform, (2015). Accessed 12 Jan 2015; Crini, G., Badot, P.-M., Application of chitosan, a natural aminopolysaccharide, for dye removal from aqueous solutions by adsorption processes using batch studies: A review of recent literature (2008) Prog. Polym. Sci., 33, pp. 399-447. , COI: 1:CAS:528:DC%2BD1cXktlejuro%3D
  • Dogan, M., Abak, H., Alkan, M., Adsorption of methylene blue onto hazelnut shell: Kinetics, mechanism and activation parameters (2009) J. Hazard. Mater., 164, pp. 172-181. , COI: 1:CAS:528:DC%2BD1MXislGmsbg%3D
  • Eftekari, S., Habibi-Yankgjeh, A., Sohrabnezhad, S., Application of AIMCM-41 for competitive adsorption of methylene blue and rhodamine B: Thermodynamic and kinetic studies (2010) J. Hazard. Mater., 178, pp. 349-355
  • Fernandez, M.E., Nunell, G.V., Bonelli, P.R., Cukierman, A.L., Effectiveness of Cupressus sempervirens cones as biosorbent for the removal of basic dyes from aqueous solutions in batch and dynamic modes (2010) Bioresour. Technol., 101, pp. 9500-9507. , COI: 1:CAS:528:DC%2BC3cXhtV2gt7nM
  • Fernandez, M.E., Nunell, G.V., Bonelli, P.R., Cukierman, A.L., Batch and dynamic biosorption of basic dyes from binary solutions by alkaline-treated cypress cone chips (2012) Bioresour. Technol., 106, pp. 55-62. , COI: 1:CAS:528:DC%2BC38Xksl2gsw%3D%3D
  • Ghaedi, M., Hajati, S., Barazesh, B., Karimi, F., Ghezelbash, G., Saccharomyces cerevisiae for the biosorption of basic dyes from binary component systems and high order derivative spectrophotometric method for simultaneous analysis of Brilliant green and Methylene blue (2013) J. Ind. Eng. Chem., 19, pp. 227-233. , COI: 1:CAS:528:DC%2BC38XhslKqt7rM
  • Gunn, D.J., Axial and radial dispersion in fixed beds (1987) Chem. Eng. Sci., 42, pp. 363-373. , COI: 1:CAS:528:DyaL2sXht1ahs7s%3D
  • Gupta, V.K., Suhas, Application of low-cost adsorbents for dye removal – A review (2009) J. Environ. Manage., 90, pp. 2313-2342. , COI: 1:CAS:528:DC%2BD1MXos1ekt7c%3D
  • Ho, Y.S., McKay, G., Pseudo-second order model for sorption processes (1999) Process Biochem., 34, pp. 451-465. , COI: 1:CAS:528:DyaK1MXlt1Omtbk%3D
  • Jafari-zare, F., Habibi-yangjeh, A., Competitive Adsorption of Methylene Blue and Rhodamine B on Natural Zeolite: Thermodynamic and Kinetic Studies (2010) Chin. J. Chem., 28, pp. 349-356. , COI: 1:CAS:528:DC%2BC3cXltFSrur8%3D
  • McKay, G., Al Duri, B., Simplified model for the equilibrium adsorption of dyes from mixtures using activated carbon (1987) Chem. Eng. Process., 22, pp. 145-156. , COI: 1:CAS:528:DyaL1cXhtVOjtg%3D%3D
  • Noroozi, B., Sorial, G.A., Applicable models for multi-component adsorption of dyes: A review (2013) Journal of Environmental Sciences, 25, pp. 419-429. , COI: 1:CAS:528:DC%2BC3sXpvVCgtLg%3D
  • Ozcan, A.S., Tetik, S., Ozcan, A., Adsorption of acid dyes from aqueous solutions onto sepiolite (2004) Sep. Sci. Technol., 39, pp. 301-320
  • Pereira, L., Alves, M., Dyes – Environmental impact and remediation (2012) Environmental protection strategies for sustainable development, pp. 111-154. , Malik A, Grohmann E, (eds), Springer, Netherlands:
  • Qiu, H., Pan, B.C., Zhang, Q.J., Zhang, W.M., Zhang, Q.X., Critical review in adsorption kinetic models (2009) J. Zhejiang Univ. Science A, 10, pp. 716-724. , COI: 1:CAS:528:DC%2BD1MXls1Kgtb0%3D
  • Ruthven, D.M., (1984) Principles of Adsorption and Adsorption Processes, , John Wiley, New York:
  • Ruthven, D.M., Farooq, S., Knaebel, K.S., (1994) Pressure Swing Adsorption, , VCH Publishers, New York:
  • Sheindorf, C., Rebhun, M., Sheintuch, M., A Freundlich-type multicomponent isotherm (1981) J. Colloid Interface Sci., 79, pp. 136-142. , COI: 1:CAS:528:DyaL3MXjs12mtQ%3D%3D
  • Sheindorf, C., Rebhun, M., Sheintuch, M., Organic pollutants adsorption from multicomponent systems modeled by Freundlich type isotherm (1982) Water Res., 16, pp. 357-362. , COI: 1:CAS:528:DyaL38Xkt1yisLw%3D
  • Turabik, M., Adsorption of basic dyes from single and binary component systems onto bentonite: simultaneous analysis of basic red 46 and basic yellow 28 by first order derivative spectrophotometric analysis method (2008) J. Hazard. Mater., 158, pp. 52-64. , COI: 1:CAS:528:DC%2BD1cXpt1enur8%3D
  • Environmental Protection Agency, U.S., Profile of the textile industry (1997) Sector Notebook Project EPA/310-R-97-009
  • Walker, G.M., Weatherley, L.R., Prediction of bisolute dye adsorption isotherms on activated carbon (2000) Trans. IChemE, 78, pp. 219-223. , COI: 1:CAS:528:DC%2BD3cXks1yqu74%3D, Part B
  • Xu, Z., Cai, J.G., Pan, B.C., Mathematically modeling fixed-bed adsorption in aqueous systems (2013) J. Zhejiang Univ. Science A, 14, pp. 155-176. , COI: 1:CAS:528:DC%2BC3sXksFentrw%3D

Citas:

---------- APA ----------
Fernandez, M.E., Bonelli, P.R., Cukierman, A.L. & Lemcoff, N.O. (2015) . Modeling the biosorption of basic dyes from binary mixtures. Adsorption, 21(3), 177-183.
http://dx.doi.org/10.1007/s10450-015-9660-1
---------- CHICAGO ----------
Fernandez, M.E., Bonelli, P.R., Cukierman, A.L., Lemcoff, N.O. "Modeling the biosorption of basic dyes from binary mixtures" . Adsorption 21, no. 3 (2015) : 177-183.
http://dx.doi.org/10.1007/s10450-015-9660-1
---------- MLA ----------
Fernandez, M.E., Bonelli, P.R., Cukierman, A.L., Lemcoff, N.O. "Modeling the biosorption of basic dyes from binary mixtures" . Adsorption, vol. 21, no. 3, 2015, pp. 177-183.
http://dx.doi.org/10.1007/s10450-015-9660-1
---------- VANCOUVER ----------
Fernandez, M.E., Bonelli, P.R., Cukierman, A.L., Lemcoff, N.O. Modeling the biosorption of basic dyes from binary mixtures. Adsorpt. 2015;21(3):177-183.
http://dx.doi.org/10.1007/s10450-015-9660-1