Artículo

Marco-Brown, J.L.; Areco, M.M.; Torres Sánchez, R.M.; Dos Santos Afonso, M. "Adsorption of picloram herbicide on montmorillonite: Kinetic and equilibrium studies" (2014) Colloids and Surfaces A: Physicochemical and Engineering Aspects. 449(1):121-128
Estamos trabajando para incorporar este artículo al repositorio
Consulte el artículo en la página del editor
Consulte la política de Acceso Abierto del editor

Abstract:

The kinetics of the adsorption of picloram (PCM) onto montmorillonite (Mt) was studied in situ by attenuated total reflectance Fourier-transform infrared spectra (ATR-FTIR). Pseudo-first-order, pseudo-second-order, intra-particle diffusion and mixed surface reaction intra-particle diffusion-controlled kinetic models were applied to the experimental results. The latter was the model that best represented the experimental results. The adsorption equilibrium isotherms revealed the presence of two independent adsorption processes on different surface sites. The adsorption isotherms normalized by the surface area were fitted with the Langmuir and Freundlich models to obtain the respective parameters.Due to the anionic form of PCM, the adsorption onto the external clay mineral surface sites followed by the entrance of the PCM molecule into the Mt basal space in a less energetically favorable pathway was proposed. The interaction of PCM with montmorillonite surface sites through nitrogen of the pyridine ring and carboxylic group by forming an inner sphere complex was confirmed by ATR-FTIR. © 2014 Elsevier B.V.

Registro:

Documento: Artículo
Título:Adsorption of picloram herbicide on montmorillonite: Kinetic and equilibrium studies
Autor:Marco-Brown, J.L.; Areco, M.M.; Torres Sánchez, R.M.; Dos Santos Afonso, M.
Filiación:Dept. de Química Inorgánica, Analitica y Quimica Fisica Inst. de Química Física de los Materiales, Ambiente y Energia, Fac. de Ciencias Exactas y Naturales (FCEyN), Univ. de Buenos Aires, Ciudad Universitaria, Pabellón II, C1428EHA Buenos Aires, Argentina
Centro de Tecnología en Minerales y Cerámica (CETMIC) - Camino Centenario, B1897ZCA M. B. Gonnet, Argentina
Palabras clave:Adsorption isotherms; Adsorption kinetics; Herbicide; Montmorillonite; Picloram; Adsorption; Adsorption isotherms; Clay minerals; Diffusion in solids; Dyes; Fourier transform infrared spectroscopy; Kinetics; Pyridine; Surface reactions; Weed control; Adsorption equilibrium isotherms; Adsorption kinetics; Attenuated total reflectance; Fourier transform infra reds; Inner sphere complexes; Intra-particle diffusion; Montmorillonite surface; Picloram; Herbicides; montmorillonite; picloram; adsorption; adsorption kinetics; aqueous solution; article; bioavailability; biosorption; diffusion; equilibrium constant; infrared spectroscopy; isotherm; kinetics; priority journal; reaction analysis; scanning electron microscopy
Año:2014
Volumen:449
Número:1
Página de inicio:121
Página de fin:128
DOI: http://dx.doi.org/10.1016/j.colsurfa.2014.02.038
Título revista:Colloids and Surfaces A: Physicochemical and Engineering Aspects
Título revista abreviado:Colloids Surf. A Physicochem. Eng. Asp.
ISSN:09277757
CODEN:CPEAE
CAS:montmorillonite, 1318-93-0, 61029-13-8; picloram, 1918-02-1
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09277757_v449_n1_p121_MarcoBrown

Referencias:

  • Zhang, J., Shi, B., Li, T., Wang, D., Adsorption of methyl parathion on PAC from natural waters: the effect of NOM on adsorption capacity and kinetics (2013) Adsorption, 19, pp. 91-99
  • Palma, G., Sánchez, A., Olave, Y., Encina, F., Palma, R., Barra, R., Pesticide levels in surface waters in an agricultural-forestry basin in Southern Chile (2004) Chemosphere, 57, pp. 763-770
  • Bansal, O.P., Fate of pesticides in the environment (2011) J. Indian Chem. Soc., 88, pp. 1525-1532
  • Loewy, M., Kirs, V., Carvajal, G., Groundwater contamination by azinphos methyl in the Northern Patagonic Region (1999) Sci. Total Environ., 225, pp. 211-218
  • http://www.fao.org/, Food and Agriculture Organization of the United Nations, FAO Specifications and evaluations for Agricultural Pesticides, Picloram; Lavy, T.L., Mattice, J.D., Massey, J.H., Skulman, B.W., Senseman, S.A., Gbur, E.E., Barrett, M.R., Long-term in situ leaching and degradation of six herbicides aged in subsoils (1996) J. Environ. Qual., 25, pp. 1268-1279
  • Cheung, M., Biggar, J., Solubility and molecular structure of 4-amino-3,5,6-trichloropicolinic acid in relation to pH and temperature (1974) J. Agr. Food Chem., 22, pp. 202-206
  • Biggar, J., Mingelgrin, U., Cheung, M., Equilibrium and kinetics of adsorption of picloram and parathion with soils (1978) J. Agr. Food Chem., 26, pp. 1306-1312
  • Bovey, R.W., Richardson, C.W., Organic chemicals in the environment: dissipation of clopyralid and picloram in soil and seep flow in the backlands of texas (1991) J. Environ. Qual., 20, pp. 528-531
  • Krzyszowska, A.J., Allen, R.D., Vance, G.F., Assessment of the fate of two herbicides in a Wyoming rangeland soil: Column studies (1994) J. Environ. Qual., 23, pp. 1051-1058
  • Celis, R., Hermosín, M., Cornejo, L., Carrizosa, M., Cornejo, J., Clay-herbicide complexes to retard picloram leaching in soil (2002) Int. J. Environ. Anal. Chem., 82, pp. 503-517
  • Close, M.E., Magesan, G.N., Lee, R., Stewart, M.K., Hadfield, J.C., Field study of pesticide leaching in an allophanic soil in New Zealand. 1: Experimental results (2003) Aust. J. Soil Res., 41, pp. 809-824
  • Kim, T.Y., Park, S.S., Cho, S.S.Y., Separation characteristics of some phenoxy herbicides from aqueous solution (2008) Adsorption, 14, pp. 611-619
  • Sahiner, N., Butun, S., Ilgin, P., Hydrogel particles with core shell morphology for versatile applications: environmental, biomedical and catalysis (2011) Colloids Surf. A, 386, pp. 16-24
  • Pavlovic, I., Barriga, C., Hermosín, M., Cornejo, J., Ulibarri, J., Adsorption of acidic pesticides 2,4-D, clopyralid and picloram on calcined hydrotalcite (2005) Appl. Clay Sci., 30, pp. 25-33
  • Prado, A.G.S., Tosta, A.H., Airoldi, C., Adsorption, separation, and thermochemical data on the herbicide picloram anchored on silica gel and its cation interaction behavior (2004) J. Colloid Interface Sci., 269, pp. 259-264
  • Marco-Brown, J.L., Barbosa-Lema, C.M., Torres Sánchez, R.M., Mercader, R.C., dos Santos Afonso, M., Adsorption of picloram herbicide on iron oxide pillared montmorillonite (2012) Appl. Clay Sci., 58, pp. 25-33
  • Grover, R., Adsorption of picloram by soil colloids and various other adsorbents (1971) Weed Sci., 19, pp. 417-418
  • Farmer, W., Aochi, Y., Picloram sorption by soils (1974) Proc. Soil Sci. Soc. Am., 38, pp. 418-423
  • Coquet, Y., Variation of pesticide sorption isotherm in soil at the catchment scale (2002) Pest Manag. Sci., 58, pp. 69-78
  • El Arfaoui, A., Sayen, S., Paris, M., Keziou, A., Couderchet, M., Guillon, E., Is organic matter alone sufficient to predict isoproturon sorption in calcareous soils? (2012) Sci. Total Environ., 432, pp. 251-256
  • Rauf, N., Tahir, S.S., Kang, J.-H., Chang, Y.-S., Equilibrium, thermodynamics and kinetics studies for the removal of alpha and beta endosulfan by adsorption onto bentonite clay (2012) Chem. Eng. J., 192, pp. 369-376
  • Barbier, F., Duc, G., Petit-Ramel, M., Adsorption of lead and cadmium ions from aqueous solution to the montmorillonite/water interface (2000) Colloids Surf. A, 166, pp. 153-159
  • Parolo, M.E., Avena, M.J., Savini, M.C., Baschini, M.T., Nicotra, V., Adsorption and circular dichroism of tetracycline on sodium and calcium-montmorillonites (2013) Colloids Surf. A, 417, pp. 57-64
  • Lombardi, B., Torres Sánchez, R.M., Eloy, P., Genet, M., Interaction of thiabendazole and benzimidazole with Montmorillonite (2006) Appl. Clay Sci., 33, pp. 59-65
  • Torres Sánchez, R.M., Genet, M.J., Gaigneaux, E.M., dos Santos Afonso, M., Yunes, S., Benzimidazole adsorption on the external and interlayer surfaces of raw and treated Montmorillonite (2011) Appl. Clay Sci., 53, pp. 366-373
  • Khoury, G.A., Gehris, T.C., Tribe, L., Torres Sánchez, R.M., dos Santos Afonso, M., Glyphosate adsorption on montmorillonite: an experimental and theoretical study of surface complexes (2010) Appl. Clay Sci., 50, pp. 167-175
  • Wang, L., Zhang, J., Wang, A., Removal of methylene blue from aqueous solution using chitosan-g-poly(acrylic acid)/montmorillonite superadsorbent nanocomposite (2008) Colloids Surf. A, 322, pp. 47-53
  • Roonasi, P., Holmgren, A., An ATR-FTIR study of sulphate sorption on magnetite: rate of adsorption, surface speciation, and effect of calcium ions (2009) J. Colloid Interface Sci., 333, pp. 27-32
  • Marco-Brown, J.L., (2011) Adsorción de Picloram sobre Minerales Arcillosos, , Ph.D. Dissertation, Buenos Aires University
  • Tschapek, M., Torres Sánchez, R.M., Wasowski, C., Handy methods for determining the isoelectric point of soils (1989) Z. Pfla. Boden., 152, pp. 73-76
  • Siguin, D., Ferreira, S., Froufe, L., García, F., Smectites, the relation-ship between their properties and isomorphic substitution (1994) J. Mater. Sci., 29, pp. 4379-4384
  • Michot, L.J., Villieras, F., Surface area and porosity (2006) Handbook of Clay Science. Developments in Clay Science, pp. 965-978. , Elsevier, Amsterdam, F. Bergaya, B.K. Theng, G. Lagaly (Eds.)
  • Bojemueller, E., Nennemann, A., Lagaly, G., Enhanced pesticide adsorption by thermally modified bentonites (2001) Appl. Clay Sci., 18, pp. 277-284
  • Magnoli, A., Tallone, L., Rosa, C., Dalcero, A.M., Chiacchiera, S.M., Torres Sánchez, R.M., Commercial bentonites as detoxifier as broiler feed contaminated with aflatoxinas (2008) Appl. Clay Sci., 40, pp. 63-71
  • Loring, J.S., Karlsson, M., Fawcett, W.R., Casey, W.H., Attenuated total reflection-Fourier-transform infrared and 27Al-nuclear magnetic resonance investigation of speciation and complexation in aqueous Al(III)-picolinate solutions (2000) Geochim. Cosmochim. Acta, 64, pp. 4115-4129
  • Haerifar, M., Azizian, S., Mixed surface reaction and diffusion-controlled kinetic model for adsorption at the solid/solution Interface (2013) J. Phys. Chem. C, 117, pp. 8310-8317
  • Areco, M.M., Saleh-Medina, L., Trinelli, M.A., Marco-Brown, J.L., dos Santos Afonso, M., Adsorption of Cu(II), Zn(II), Cd(II) and Pb(II) by dead Avena fatua biomass and the effect of these metals on their growth (2013) Colloids Surf. B., 110, pp. 305-312
  • Bhattacharya, A.K., Venkobachar, C., Removal of cadmium (II) by low cost adsorbents (1984) J. Environ. Eng., 110, pp. 110-122
  • Chintala, R., Mollinedo, J., Schumacher, T.E., Malo, D.D., Papiernik, S., Clay, D.E., Kumar, S., Gulbrandson, D.W., Nitrate sorption and desorption by biochars produced from microwave pyrolysis (2013) Microporous and Mesoporous Mater., 179, pp. 250-257
  • Fast, B.J., Ferrell, J.A., MacDonald, G.E., Krutz, L.J., Kline, W.N., Picloram and aminopyralid sorption to soil and clay minerals (2010) Weed Sci., 58, pp. 484-489

Citas:

---------- APA ----------
Marco-Brown, J.L., Areco, M.M., Torres Sánchez, R.M. & Dos Santos Afonso, M. (2014) . Adsorption of picloram herbicide on montmorillonite: Kinetic and equilibrium studies. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 449(1), 121-128.
http://dx.doi.org/10.1016/j.colsurfa.2014.02.038
---------- CHICAGO ----------
Marco-Brown, J.L., Areco, M.M., Torres Sánchez, R.M., Dos Santos Afonso, M. "Adsorption of picloram herbicide on montmorillonite: Kinetic and equilibrium studies" . Colloids and Surfaces A: Physicochemical and Engineering Aspects 449, no. 1 (2014) : 121-128.
http://dx.doi.org/10.1016/j.colsurfa.2014.02.038
---------- MLA ----------
Marco-Brown, J.L., Areco, M.M., Torres Sánchez, R.M., Dos Santos Afonso, M. "Adsorption of picloram herbicide on montmorillonite: Kinetic and equilibrium studies" . Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 449, no. 1, 2014, pp. 121-128.
http://dx.doi.org/10.1016/j.colsurfa.2014.02.038
---------- VANCOUVER ----------
Marco-Brown, J.L., Areco, M.M., Torres Sánchez, R.M., Dos Santos Afonso, M. Adsorption of picloram herbicide on montmorillonite: Kinetic and equilibrium studies. Colloids Surf. A Physicochem. Eng. Asp. 2014;449(1):121-128.
http://dx.doi.org/10.1016/j.colsurfa.2014.02.038