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Abstract:

Activated carbon from orange (Citrus sinensis) peel was developed through H3PO4 acid activation. Its ability as an adsorbent for the removal of two representative basic dyes (methylene blue and rhodamine B) from single and binary dyes solutions in batch and continuous modes was examined. The orange peel-based activated carbon presented a high specific surface area (1090m2/g), predominance of mesopores and acidic character. It also showed a high adsorption capacity for both dyes in batch and dynamic modes. Experimental equilibrium isotherms obtained from single-dye solutions fitted the Langmuir-Freundlich model, and those obtained from binary solutions were properly described by single and multi-component models. Breakthrough curves obtained from single-dye solutions exhibited a better removal performance for rhodamine B. Adsorption capacity at exhaustion time for this dye was 11% higher than for methylene blue. Additional experiments in dynamic conditions with a binary solution of both dyes pointed to adsorption competition for the active sites of the developed carbon. Breakthrough curves were adequately represented by a modified two-parameter model. © 2014 Elsevier B.V.

Registro:

Documento: Artículo
Título:Activated carbon developed from orange peels: Batch and dynamic competitive adsorption of basic dyes
Autor:Fernandez, M.E.; Nunell, G.V.; Bonelli, P.R.; Cukierman, A.L.
Filiación:Departamento de Industrias, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Intendente Güiraldes 2620, Ciudad Universitaria, Buenos Aires, C1428BGA, Argentina
Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Av. Rivadavia 1917, Buenos Aires, C1033AAJ, Argentina
Cátedra de Farmacotecnia II, Departamento de Tecnología Farmacéutica, Facultad de Farmacia y Bioquímica, Universidad de Buenos Aires, Junín 956, Buenos Aires, C1113AAD, Argentina
Palabras clave:Basic dyes removal; Binary equilibrium isotherms; Competitive dynamic adsorption; Orange peel-based activated carbon; Phosphoric acid activation; Basic dyes; Competitive adsorption; Competitive dynamics; Equilibrium isotherms; Orange peels; Phosphoric acid activation; acid activation; activated carbon; adsorption; breakthrough curve; dicotyledon; dye; equilibrium; fruit; isotherm
Año:2014
Volumen:62
Página de inicio:437
Página de fin:445
DOI: http://dx.doi.org/10.1016/j.indcrop.2014.09.015
Título revista:Industrial Crops and Products
Título revista abreviado:Ind. Crops Prod.
ISSN:09266690
CODEN:ICRDE
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09266690_v62_n_p437_Fernandez

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Citas:

---------- APA ----------
Fernandez, M.E., Nunell, G.V., Bonelli, P.R. & Cukierman, A.L. (2014) . Activated carbon developed from orange peels: Batch and dynamic competitive adsorption of basic dyes. Industrial Crops and Products, 62, 437-445.
http://dx.doi.org/10.1016/j.indcrop.2014.09.015
---------- CHICAGO ----------
Fernandez, M.E., Nunell, G.V., Bonelli, P.R., Cukierman, A.L. "Activated carbon developed from orange peels: Batch and dynamic competitive adsorption of basic dyes" . Industrial Crops and Products 62 (2014) : 437-445.
http://dx.doi.org/10.1016/j.indcrop.2014.09.015
---------- MLA ----------
Fernandez, M.E., Nunell, G.V., Bonelli, P.R., Cukierman, A.L. "Activated carbon developed from orange peels: Batch and dynamic competitive adsorption of basic dyes" . Industrial Crops and Products, vol. 62, 2014, pp. 437-445.
http://dx.doi.org/10.1016/j.indcrop.2014.09.015
---------- VANCOUVER ----------
Fernandez, M.E., Nunell, G.V., Bonelli, P.R., Cukierman, A.L. Activated carbon developed from orange peels: Batch and dynamic competitive adsorption of basic dyes. Ind. Crops Prod. 2014;62:437-445.
http://dx.doi.org/10.1016/j.indcrop.2014.09.015