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Abstract:

Solid photocatalysts in which the 2,4,6-triphenylpyrylium (TP) or 2,4,6-triphenylthiapyrylium cation (TTP) are encapsulated within zeolite Y or deposited on mesoporous silica are used as photosensitizers for the oxidation of sulfides, both aromatic and aliphatic, in solvents of various polarity. Contrary to the same cations in solution, these solid sensitizers are not significantly degraded during operation. An effective oxygenation takes place leading to sulfoxides, disulfides, sulfinic and sulfenic esters as well as sulfonic acids. This large scope method shows a limited dependence on the substrate structure and on conditions and is suitable for the abatement of sulfur-containing pollutants. © 2007 Elsevier B.V. All rights reserved.

Registro:

Documento: Artículo
Título:Photocatalytic oxidation of aliphatic and aromatic sulfides in the presence of silica adsorbed or zeolite-encapsulated 2,4,6-triphenyl(thia)pyrylium
Autor:Bonesi, S.M.; Carbonell, E.; Garcia, H.; Fagnoni, M.; Albini, A.
Filiación:CIHIDECAR, CONICET, Departamento de Química Orgánica, Int. Güiraldes s/n, 1428 Buenos Aires, Argentina
Dipartimento di Chimica Organica, Università, via Taramelli 10, 27100 Pavia, Italy
Instituto de Tecnologia Quimica CSIC-UPV, Universidad Politecnica de Valencia, av. De los Naranjos s/n, 46012 Valencia, Spain
Palabras clave:2,4,6-Triphenylpyrilium; Oxidation; Photocatalyst; Sulfides; Zeolite; Oxidation; Oxygenation; Silica; Solvents; Zeolites; Aromatic sulfides; Sulfenic esters; Triphenylpyrilium; Photocatalysts; Thia
Año:2008
Volumen:79
Número:4
Página de inicio:368
Página de fin:375
DOI: http://dx.doi.org/10.1016/j.apcatb.2007.10.037
Título revista:Applied Catalysis B: Environmental
Título revista abreviado:Appl. Catal. B Environ.
ISSN:09263373
CODEN:ACBEE
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09263373_v79_n4_p368_Bonesi

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Citas:

---------- APA ----------
Bonesi, S.M., Carbonell, E., Garcia, H., Fagnoni, M. & Albini, A. (2008) . Photocatalytic oxidation of aliphatic and aromatic sulfides in the presence of silica adsorbed or zeolite-encapsulated 2,4,6-triphenyl(thia)pyrylium. Applied Catalysis B: Environmental, 79(4), 368-375.
http://dx.doi.org/10.1016/j.apcatb.2007.10.037
---------- CHICAGO ----------
Bonesi, S.M., Carbonell, E., Garcia, H., Fagnoni, M., Albini, A. "Photocatalytic oxidation of aliphatic and aromatic sulfides in the presence of silica adsorbed or zeolite-encapsulated 2,4,6-triphenyl(thia)pyrylium" . Applied Catalysis B: Environmental 79, no. 4 (2008) : 368-375.
http://dx.doi.org/10.1016/j.apcatb.2007.10.037
---------- MLA ----------
Bonesi, S.M., Carbonell, E., Garcia, H., Fagnoni, M., Albini, A. "Photocatalytic oxidation of aliphatic and aromatic sulfides in the presence of silica adsorbed or zeolite-encapsulated 2,4,6-triphenyl(thia)pyrylium" . Applied Catalysis B: Environmental, vol. 79, no. 4, 2008, pp. 368-375.
http://dx.doi.org/10.1016/j.apcatb.2007.10.037
---------- VANCOUVER ----------
Bonesi, S.M., Carbonell, E., Garcia, H., Fagnoni, M., Albini, A. Photocatalytic oxidation of aliphatic and aromatic sulfides in the presence of silica adsorbed or zeolite-encapsulated 2,4,6-triphenyl(thia)pyrylium. Appl. Catal. B Environ. 2008;79(4):368-375.
http://dx.doi.org/10.1016/j.apcatb.2007.10.037