Artículo

Boontum, A.; Phokharatkul, D.; Hodak, J.H.; Wisitsoraat, A.; Hodak, S.K. "H2S sensing characteristics of Ni-doped CaCu3Ti4O12 films synthesized by a sol-gel method" (2018) Sensors and Actuators, B: Chemical. 260:877-887
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Abstract:

The problem of detecting the toxic hydrogen sulfide (H2S) gas at part per million levels in air by means of simple solid state gas sensors is relevant to environmental and gas processing industries. In this work, high-performance H2S gas sensors are developed based on nickel-doped calcium copper titanate (Ni-doped CCTO) thin films synthesized by a sol-gel method. From gas-sensing measurements, the response of Ni-doped CCTO sensing films increased substantially with increasing Ni doping level from 1.5 to 7.3 wt%, revealing a catalytic effect of Ni on the surface reactions with adsorbed H2S molecules. In particular, 7.3 wt% Ni-doped CCTO sensors offered a high response of 120 for 10 ppm of H2S at the optimal operating temperature of 250 °C, an order of magnitude higher than that of undoped one. In addition, the response time dropped significantly from ∼80 s to ∼4 s while the recovery time slightly improved as the Ni doping content increased from 0 to 7.3 wt%. Moreover, the Ni-doped CCTO sensors exhibited good reproducibility and high H2S selectivity against ethanol, H2, NO2 and NH3. Therefore, the Ni-doped CCTO sensors are highly promising for sensitive and selective detections of H2S. © 2018

Registro:

Documento: Artículo
Título:H2S sensing characteristics of Ni-doped CaCu3Ti4O12 films synthesized by a sol-gel method
Autor:Boontum, A.; Phokharatkul, D.; Hodak, J.H.; Wisitsoraat, A.; Hodak, S.K.
Filiación:Department of Physics, Faculty of Science, Chulalongkorn University, Bangkok, 10330, Thailand
Carbon-based Devices and Nanoelectronics Laboratory, Pathumthani, 12120, Thailand
Universidad de Buenos Aires, Facultad de Ciencias Exactas y Naturales, Departamento de Química Inorgánica, Analítica y Química Física, Pabellón 2, Ciudad Universitaria, Buenos Aires, C1428EHA, Argentina
CONICET – Universidad de Buenos Aires, Instituto de Química-Física de Materiales, Ambientes y Energía (INQUIMAE), Buenos Aires, Argentina
Department of Common and Graduate Studies, Sirindhorn International Institute of Technology, Thammasat University, Pathumthani, Thailand
Palabras clave:Calcium copper titanate; Hydrogen sulfide; Ni doping; Semiconducting gas sensor; Sol-gel method; Calcium; Calcium compounds; Chemical sensors; Copper; Gas detectors; Gases; Hydrogen sulfide; Nickel; Nickel compounds; Semiconductor doping; Sol-gel process; Sol-gels; Solid-state sensors; Sulfur compounds; Sulfur determination; Surface reactions; Thin films; Titanium compounds; Calcium copper titanates; Catalytic effects; Ni-doping; Operating temperature; Reproducibilities; Selective detection; Sensing characteristics; Solid state gas sensors; Copper compounds
Año:2018
Volumen:260
Página de inicio:877
Página de fin:887
DOI: http://dx.doi.org/10.1016/j.snb.2018.01.090
Título revista:Sensors and Actuators, B: Chemical
Título revista abreviado:Sens Actuators, B Chem
ISSN:09254005
CODEN:SABCE
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09254005_v260_n_p877_Boontum

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Citas:

---------- APA ----------
Boontum, A., Phokharatkul, D., Hodak, J.H., Wisitsoraat, A. & Hodak, S.K. (2018) . H2S sensing characteristics of Ni-doped CaCu3Ti4O12 films synthesized by a sol-gel method. Sensors and Actuators, B: Chemical, 260, 877-887.
http://dx.doi.org/10.1016/j.snb.2018.01.090
---------- CHICAGO ----------
Boontum, A., Phokharatkul, D., Hodak, J.H., Wisitsoraat, A., Hodak, S.K. "H2S sensing characteristics of Ni-doped CaCu3Ti4O12 films synthesized by a sol-gel method" . Sensors and Actuators, B: Chemical 260 (2018) : 877-887.
http://dx.doi.org/10.1016/j.snb.2018.01.090
---------- MLA ----------
Boontum, A., Phokharatkul, D., Hodak, J.H., Wisitsoraat, A., Hodak, S.K. "H2S sensing characteristics of Ni-doped CaCu3Ti4O12 films synthesized by a sol-gel method" . Sensors and Actuators, B: Chemical, vol. 260, 2018, pp. 877-887.
http://dx.doi.org/10.1016/j.snb.2018.01.090
---------- VANCOUVER ----------
Boontum, A., Phokharatkul, D., Hodak, J.H., Wisitsoraat, A., Hodak, S.K. H2S sensing characteristics of Ni-doped CaCu3Ti4O12 films synthesized by a sol-gel method. Sens Actuators, B Chem. 2018;260:877-887.
http://dx.doi.org/10.1016/j.snb.2018.01.090