Artículo

Barja, B.C.; Bari, S.E.; Marchi, M.C.; Iglesias, F.L.; Bernardi, M. "Luminescent Eu(III) hybrid sensors for in situ copper detection" (2011) Sensors and Actuators, B: Chemical. 158(1):214-222
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Abstract:

In this work we used the sol-gel technique to develop luminescent Eu(III) transparent films deposited on glass slides to build for sensor devices capable of monitoring transition metal ions in aqueous solutions. The films were obtained from a bis(trialkoxysilyl) organic precursor synthesized from the amide of the 2,6-pyridinedicarboxylic acid (DPA) with aminopropyltriethoxysilane (APTES) in the presence or absence of cetyl trimethyl ammonium bromide (CTAB) surfactant as templating agent and triethylethoxysilane (TEOS) as crosslinker. These sensor devices were used to perform in situ quenching experiments by Cu(II), Fe(III), Co(II) and Ni(II) ions. The results indicate that the templated films allow the detection and quantification of these metals down to ppb levels by means of the values of the Stern-Volmer constants. In particular, it was shown that Cu(II) acts as an extremely efficient quencher (KSV = 3.5 × 105 M-1) when compared with the results obtained for the other metals, opening the possibility to use these devices as potential Cu(II) sensors for actual applications in aqueous media. © 2011 Elsevier B.V. Al rights reserved.

Registro:

Documento: Artículo
Título:Luminescent Eu(III) hybrid sensors for in situ copper detection
Autor:Barja, B.C.; Bari, S.E.; Marchi, M.C.; Iglesias, F.L.; Bernardi, M.
Filiación:INQUIMAE, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón 2, C1428EHA Buenos Aires, Argentina
Centro de Microscopías Avanzadas (CMA), Facultad de Ciencias Exactas y Naturales (FCEyN), Universidad de Buenos Aires, Ciudad Universitaria, Pabellón 1, C1428EHA Buenos Aires, Argentina
Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón 2, C1428EHA Buenos Aires, Argentina
Palabras clave:Cu(II) sensor; Europium(III); Hybrid materials; Luminescence quenching; Sol-gel; Aminopropyltriethoxysilane; Aqueous media; Cetyltrimethylammonium bromide; Crosslinker; Glass slides; In-situ; Luminescence quenching; Organic precursor; Ppb levels; Sensor device; Sol-gel technique; Stern-Volmer constants; Templated; Templating agents; Transparent films; Amides; Ammonium compounds; Bromine compounds; Europium; Gels; Glass transition; Hybrid materials; Iron compounds; Luminescence; Metal ions; Quenching; Silicon compounds; Sol-gel process; Sol-gels; Sols; Surface active agents; Transition metals; Sensors
Año:2011
Volumen:158
Número:1
Página de inicio:214
Página de fin:222
DOI: http://dx.doi.org/10.1016/j.snb.2011.06.006
Título revista:Sensors and Actuators, B: Chemical
Título revista abreviado:Sens Actuators, B Chem
ISSN:09254005
CODEN:SABCE
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09254005_v158_n1_p214_Barja

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Citas:

---------- APA ----------
Barja, B.C., Bari, S.E., Marchi, M.C., Iglesias, F.L. & Bernardi, M. (2011) . Luminescent Eu(III) hybrid sensors for in situ copper detection. Sensors and Actuators, B: Chemical, 158(1), 214-222.
http://dx.doi.org/10.1016/j.snb.2011.06.006
---------- CHICAGO ----------
Barja, B.C., Bari, S.E., Marchi, M.C., Iglesias, F.L., Bernardi, M. "Luminescent Eu(III) hybrid sensors for in situ copper detection" . Sensors and Actuators, B: Chemical 158, no. 1 (2011) : 214-222.
http://dx.doi.org/10.1016/j.snb.2011.06.006
---------- MLA ----------
Barja, B.C., Bari, S.E., Marchi, M.C., Iglesias, F.L., Bernardi, M. "Luminescent Eu(III) hybrid sensors for in situ copper detection" . Sensors and Actuators, B: Chemical, vol. 158, no. 1, 2011, pp. 214-222.
http://dx.doi.org/10.1016/j.snb.2011.06.006
---------- VANCOUVER ----------
Barja, B.C., Bari, S.E., Marchi, M.C., Iglesias, F.L., Bernardi, M. Luminescent Eu(III) hybrid sensors for in situ copper detection. Sens Actuators, B Chem. 2011;158(1):214-222.
http://dx.doi.org/10.1016/j.snb.2011.06.006