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Abstract:

A novel photoaddressable copolymer with low glass transition temperature was synthesised and its optical properties were studied. The photoresponsive material was obtained from chemical modification of a poly(styrene-co-acrylic acid) copolymer. A holographic polarization grating was recorded in the material and was monitored by measuring its diffraction efficiency. It is shown that the holographic grating stored in the material is highly stable in time, despite the fact that the polymer glass transition temperature is near room temperature. This stability is a consequence of electrostatic interactions between the azo-groups and the carboxylic substituent group of the main polymer chain. © 2015 Elsevier B.V. All rights reserved.

Registro:

Documento: Artículo
Título:Optical recording of stable holographic grating in a low Tg statistical copolymer covalently functionalized with an azo-dye
Autor:Cambiasso, J.; Garate, H.; D'Accorso, N.; Ledesma, S.; Goyanes, S.
Filiación:Image Processing Laboratory (LPI), Physics Department, FCEyN, UBA, Ciudad Universitaria, Ciudad Autónoma de Buenos Aires, 1428, Argentina
CIHIDECAR-CONICET, Organic Chemistry Dept., FCEyN, UBA, Ciudad Universitaria, Ciudad Autónoma de Buenos Aires, 1428, Argentina
Laboratory of Polymers and Composite Materials (LPandMC), Physics Department, IFIBA-CONICET, FCEyN-UBA, Ciudad Universitaria, Ciudad Autónoma de Buenos Aires, 1428, Argentina
Palabras clave:Azobenzene; Azopolymer; Copolymer; Diffraction gratings; Azo dyes; Azobenzene; Chemical modification; Copolymers; Diffraction; Diffraction gratings; Glass; Holographic gratings; Holography; Nanocomposites; Optical properties; Styrene; Temperature; Azopolymer; Low glass transition temperatures; Near room temperature; Photo-responsive; Polarization gratings; Poly(styreneco-acrylic acid); Polymer glass transition; Statistical copolymers; Glass transition
Año:2015
Volumen:49
Página de inicio:141
Página de fin:146
DOI: http://dx.doi.org/10.1016/j.optmat.2015.09.006
Título revista:Optical Materials
Título revista abreviado:Opt Mater
ISSN:09253467
CODEN:OMATE
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09253467_v49_n_p141_Cambiasso

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Citas:

---------- APA ----------
Cambiasso, J., Garate, H., D'Accorso, N., Ledesma, S. & Goyanes, S. (2015) . Optical recording of stable holographic grating in a low Tg statistical copolymer covalently functionalized with an azo-dye. Optical Materials, 49, 141-146.
http://dx.doi.org/10.1016/j.optmat.2015.09.006
---------- CHICAGO ----------
Cambiasso, J., Garate, H., D'Accorso, N., Ledesma, S., Goyanes, S. "Optical recording of stable holographic grating in a low Tg statistical copolymer covalently functionalized with an azo-dye" . Optical Materials 49 (2015) : 141-146.
http://dx.doi.org/10.1016/j.optmat.2015.09.006
---------- MLA ----------
Cambiasso, J., Garate, H., D'Accorso, N., Ledesma, S., Goyanes, S. "Optical recording of stable holographic grating in a low Tg statistical copolymer covalently functionalized with an azo-dye" . Optical Materials, vol. 49, 2015, pp. 141-146.
http://dx.doi.org/10.1016/j.optmat.2015.09.006
---------- VANCOUVER ----------
Cambiasso, J., Garate, H., D'Accorso, N., Ledesma, S., Goyanes, S. Optical recording of stable holographic grating in a low Tg statistical copolymer covalently functionalized with an azo-dye. Opt Mater. 2015;49:141-146.
http://dx.doi.org/10.1016/j.optmat.2015.09.006