Abstract:
Two samples of ochre painting residues (crayons) obtained from the archaeological site Cave Loncomán (Río Negro, Argentina) were analysed by ATR-IR and FT-Raman spectroscopy revealing the presence of haematite as the red pigment. Further analysis by FTIR of the chloroform/methanol extracts from both archaeological pastes showed the presence of carboxylic acids, indicative of hydrolysis of triacylglycerols in the pastes. Analysis by GC and GC/MS indicated that the main organic constituents of both pastes were saturated (C16:0 and C18:0) and unsaturated (C16:1 and C18:1) fatty acids. Our results show that the combined FTIR and Raman spectroscopic evaluation of archaeological pastes and their organic extracts provides a very useful and simple methodology to characterize the inorganic pigment and the presence of organic binders in an archaeological sample. © 2006 Elsevier B.V. All rights reserved.
Registro:
Documento: |
Artículo
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Título: | Combined use of vibrational spectroscopy and GC-MS methods in the characterization of archaeological pastes from Patagonia |
Autor: | Maier, M.S.; de Faria, D.L.A.; Boschín, M.T.; Parera, S.D.; del Castillo Bernal, M.F. |
Filiación: | Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellon 2, Ciudad Universitaria, 1428 Buenos Aires, Argentina Departamento de Química Fundamental, Instituto de Química, Universidade de Sao Paulo, Av. Prof. Lineu Prestes 748, 05508-000 Sao Paulo, Brazil Centro Nacional Patagónico, Consejo Nacional de Investigaciones Científicas y Técnicas, Boulevard Brown s/n, Puerto Madryn, 9120 Chubut, Argentina
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Palabras clave: | Archaeological pastes; FT-Raman; Haematite; Infrared spectroscopy; Lipids; Carboxylic acids; Fourier transform infrared spectroscopy; Gas chromatography; Hematite; Hydrolysis; Lipids; Mass spectrometry; Raman spectroscopy; Vibrational spectroscopy; Archaeological pastes; Organic binders; Organic extracts; Triacylglycerols; Painting |
Año: | 2007
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Volumen: | 44
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Número: | 1
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Página de inicio: | 182
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Página de fin: | 186
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DOI: |
http://dx.doi.org/10.1016/j.vibspec.2006.09.003 |
Título revista: | Vibrational Spectroscopy
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Título revista abreviado: | Vib. Spectrosc.
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ISSN: | 09242031
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CODEN: | VISPE
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09242031_v44_n1_p182_Maier |
Referencias:
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Citas:
---------- APA ----------
Maier, M.S., de Faria, D.L.A., Boschín, M.T., Parera, S.D. & del Castillo Bernal, M.F.
(2007)
. Combined use of vibrational spectroscopy and GC-MS methods in the characterization of archaeological pastes from Patagonia. Vibrational Spectroscopy, 44(1), 182-186.
http://dx.doi.org/10.1016/j.vibspec.2006.09.003---------- CHICAGO ----------
Maier, M.S., de Faria, D.L.A., Boschín, M.T., Parera, S.D., del Castillo Bernal, M.F.
"Combined use of vibrational spectroscopy and GC-MS methods in the characterization of archaeological pastes from Patagonia"
. Vibrational Spectroscopy 44, no. 1
(2007) : 182-186.
http://dx.doi.org/10.1016/j.vibspec.2006.09.003---------- MLA ----------
Maier, M.S., de Faria, D.L.A., Boschín, M.T., Parera, S.D., del Castillo Bernal, M.F.
"Combined use of vibrational spectroscopy and GC-MS methods in the characterization of archaeological pastes from Patagonia"
. Vibrational Spectroscopy, vol. 44, no. 1, 2007, pp. 182-186.
http://dx.doi.org/10.1016/j.vibspec.2006.09.003---------- VANCOUVER ----------
Maier, M.S., de Faria, D.L.A., Boschín, M.T., Parera, S.D., del Castillo Bernal, M.F. Combined use of vibrational spectroscopy and GC-MS methods in the characterization of archaeological pastes from Patagonia. Vib. Spectrosc. 2007;44(1):182-186.
http://dx.doi.org/10.1016/j.vibspec.2006.09.003