Abstract:
A new oxido-vanadium(V) complex, [VO(L)(PrOH)(OPr)] (L = [(3-methoxy-2oxidobenzylidene)benzohydrazidato], PrOH = propanol, OPr = propanolato) has been synthesized and characterized by means of elemental analysis, Fourier transform infrared (FTIR), proton nuclear magnetic resonance (1HNMR), ultaviolet-visible (UV-Vis) spectroscopy, voltammetry and molar conductivity measurement. The structure of the complex has also determined using single crystal X-ray diffraction. The geometric structure around the V(V) ion has been found to be octahedral in which the positions around the central ion are occupied by ONO ligand donors, oxido groups, and oxygen atoms of coordinated propanol and propoxide group. Electrochemical behavior of this complex is also discussed in more details. In vitro antimicrobial effect of the title complex has investigated exhibiting significant activities against some Gram-positive (Staphylococcus aureus, Micrococcus luteus, Bacillus cereus, Eterococcus faecalis) and Gram-negative bacteria (Pseudomonas aeruginosa, Escherichia coli, Klebsiella sp, Pseudomonas sp) and fungus strain (Candida albicans). © 2015 Springer Science+Business Media Dordrecht.
Registro:
Documento: |
Artículo
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Título: | A novel oxido-vanadium(V) Schiff base complex: Synthesis, spectral characterization, crystal structure, electrochemical evaluation, and biological activity |
Autor: | Ebrahimipour, S.Y.; Mohamadi, M.; Sheikhshoaie, I.; Suárez, S.; Baggio, R.; Khaleghi, M. |
Filiación: | Department of Chemistry, Faculty of Science, Shahid Bahonar University of Kerman, Kerman, 76169-14111, Iran Department of Chemistry, Payame Noor University (PNU), Tehran, 19395-4697, Iran Departamento de Química Inorgínica, Analítica y Química, Física, INQUIMAE-CONICET, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina Gerencia de Investigación y Aplicaciones, Centro Atómico Constituyentes, Comisión Nacional de Energía Atómica, Buenos Aires, Argentina Department of Biology, Faculty of Science, Shahid Bahonar University of Kerman, Kerman, Iran
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Palabras clave: | Anti-microbial activity; Biofilm formation; Electrochemical behavior; Schiff base ligand; V(V) complex; Bacillus cereus; Bacteria; Bacteriology; Bioactivity; Complexation; Crystal atomic structure; Escherichia coli; Fourier transform infrared spectroscopy; Functional groups; Ligands; Nuclear magnetic resonance spectroscopy; Propanol; Single crystals; Spectrum analyzers; Vanadium compounds; X ray diffraction; Anti-microbial activity; Biofilm formation; Electrochemical behaviors; Electrochemical evaluations; Fourier transform infrared; Proton nuclear magnetic resonance; Schiff-base ligands; Single crystal x-ray diffraction; Crystal structure |
Año: | 2016
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Volumen: | 42
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Número: | 2
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Página de inicio: | 611
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Página de fin: | 623
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DOI: |
http://dx.doi.org/10.1007/s11164-015-2045-y |
Título revista: | Research on Chemical Intermediates
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Título revista abreviado: | Res Chem Intermed
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ISSN: | 09226168
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CODEN: | RCINE
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09226168_v42_n2_p611_Ebrahimipour |
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Citas:
---------- APA ----------
Ebrahimipour, S.Y., Mohamadi, M., Sheikhshoaie, I., Suárez, S., Baggio, R. & Khaleghi, M.
(2016)
. A novel oxido-vanadium(V) Schiff base complex: Synthesis, spectral characterization, crystal structure, electrochemical evaluation, and biological activity. Research on Chemical Intermediates, 42(2), 611-623.
http://dx.doi.org/10.1007/s11164-015-2045-y---------- CHICAGO ----------
Ebrahimipour, S.Y., Mohamadi, M., Sheikhshoaie, I., Suárez, S., Baggio, R., Khaleghi, M.
"A novel oxido-vanadium(V) Schiff base complex: Synthesis, spectral characterization, crystal structure, electrochemical evaluation, and biological activity"
. Research on Chemical Intermediates 42, no. 2
(2016) : 611-623.
http://dx.doi.org/10.1007/s11164-015-2045-y---------- MLA ----------
Ebrahimipour, S.Y., Mohamadi, M., Sheikhshoaie, I., Suárez, S., Baggio, R., Khaleghi, M.
"A novel oxido-vanadium(V) Schiff base complex: Synthesis, spectral characterization, crystal structure, electrochemical evaluation, and biological activity"
. Research on Chemical Intermediates, vol. 42, no. 2, 2016, pp. 611-623.
http://dx.doi.org/10.1007/s11164-015-2045-y---------- VANCOUVER ----------
Ebrahimipour, S.Y., Mohamadi, M., Sheikhshoaie, I., Suárez, S., Baggio, R., Khaleghi, M. A novel oxido-vanadium(V) Schiff base complex: Synthesis, spectral characterization, crystal structure, electrochemical evaluation, and biological activity. Res Chem Intermed. 2016;42(2):611-623.
http://dx.doi.org/10.1007/s11164-015-2045-y