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Abstract:

Prussian Blue nanoparticles (PBNP) synthetized and adsorbed onto γ-Al2O3 spheres were prepared and characterized by transition and scanning electron microscopy (TEM, SEM), energy dispersive X-ray spectroscopy (EDS) and sorptometry. Adsorption and reaction runs were performed using aqueous solutions of a model azo dye Orange G. The adsorption capacity of the PBNP/γ-Al2O3 at 323 and 343 K at initial pH 3 and 6 was studied. The presence of PBNP increased the adsorption capacity of the support and this effect was more pronounced at initial pH 6. However, since the adsorbent life time was narrow and its regeneration quite difficult, PBNP/γ-Al2O3 was tested as a heterogeneous Fenton-like catalyst. The catalytic activity and stability for oxidation of Orange G were investigated in terms of discolouration, TOC and oxidant conversion. At the best operating condition studied (343 K and pH0 = 3), complete dye discolouration and 60% of mineralization were attained while reaction largely overcomes adsorption. At this temperature the catalyst activity and its characteristics remained almost invariable during 9 cycles of 5 h each and iron leaching occurred in low extent. © 2014 Elsevier B.V. All rights reserved.

Registro:

Documento: Artículo
Título:Efficient removal of Orange G using Prussian Blue nanoparticles supported over alumina
Autor:Doumic, L.; Salierno, G.; Cassanello, M.; Haure, P.; Ayude, M.
Filiación:INTEMA, Facultad de Ingeniería, UNMdP, J.B. Justo 4302, Mar del Plata, 7600, Argentina
LARSI, FCEyN, Universidad de Buenos Aires, Int. Güiraldes 2620, Buenos Aires, C1428BGA, Argentina
Palabras clave:Alumina; Azo dye; Heterogeneous Fenton-like oxidation; Prussian Blue nanoparticles; Azo dyes; Heterogeneous fenton; Orange G; Prussian blue nanoparticles; Alumina
Año:2015
Volumen:240
Número:PA
Página de inicio:67
Página de fin:72
DOI: http://dx.doi.org/10.1016/j.cattod.2014.03.064
Título revista:Catalysis Today
Título revista abreviado:Catal Today
ISSN:09205861
CODEN:CATTE
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09205861_v240_nPA_p67_Doumic

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Citas:

---------- APA ----------
Doumic, L., Salierno, G., Cassanello, M., Haure, P. & Ayude, M. (2015) . Efficient removal of Orange G using Prussian Blue nanoparticles supported over alumina. Catalysis Today, 240(PA), 67-72.
http://dx.doi.org/10.1016/j.cattod.2014.03.064
---------- CHICAGO ----------
Doumic, L., Salierno, G., Cassanello, M., Haure, P., Ayude, M. "Efficient removal of Orange G using Prussian Blue nanoparticles supported over alumina" . Catalysis Today 240, no. PA (2015) : 67-72.
http://dx.doi.org/10.1016/j.cattod.2014.03.064
---------- MLA ----------
Doumic, L., Salierno, G., Cassanello, M., Haure, P., Ayude, M. "Efficient removal of Orange G using Prussian Blue nanoparticles supported over alumina" . Catalysis Today, vol. 240, no. PA, 2015, pp. 67-72.
http://dx.doi.org/10.1016/j.cattod.2014.03.064
---------- VANCOUVER ----------
Doumic, L., Salierno, G., Cassanello, M., Haure, P., Ayude, M. Efficient removal of Orange G using Prussian Blue nanoparticles supported over alumina. Catal Today. 2015;240(PA):67-72.
http://dx.doi.org/10.1016/j.cattod.2014.03.064