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Abstract:

The first crystal structure of a simple metal(II) derivative of pyridine-2,4-dicarboxylic acid (lutidinic acid) is reported. The title compound crystallises in the monoclinic space group P21/a, with a=12.968(5), b=8.3152(9), c= 16.004(2) Å, β=103.36(2)°, Z=4. The structure was solved employing 2484 independent X-ray reflections with I>2σ(I) by Patterson and Fourier methods and refined by full-matrix least-squares to R1=0.074. The CuII ion is located in a pyramidal environment coordinating to two nitrogen atoms and two oxygen atoms from the lutidinate ligands; the apical position in the pyramid is occupied by a water group. The stereochemistry of the title compound is compared with that of other copper(II) pyridinedicarboxylates. Its thermal behaviour is also presented.

Registro:

Documento: Artículo
Título:Solid-state coordination chemistry of pyridinedicarboxylic acid isomers. II. Crystal and molecular structure of sodium bis(pyridine-2,4-dicarboxylato)cuprate(II) trihydrate
Autor:Sileo, E.E.; Rigotti, G.; Piro, O.E.
Filiación:Depto. Quimica Inorganica, A., Universidad de Buenos Aires, Ciudad Universitaria, 1428 Buenos Aires, Argentina
Departamento de Física, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, C.C. 67, 1900 La Plata, Argentina
Año:1999
Volumen:53
Número:8
Página de inicio:535
Página de fin:541
DOI: http://dx.doi.org/10.3891/acta.chem.scand.53-0535
Título revista:Acta Chemica Scandinavica
Título revista abreviado:Acta Chem. Scand.
ISSN:0904213X
CODEN:ACHSE
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0904213X_v53_n8_p535_Sileo

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Citas:

---------- APA ----------
Sileo, E.E., Rigotti, G. & Piro, O.E. (1999) . Solid-state coordination chemistry of pyridinedicarboxylic acid isomers. II. Crystal and molecular structure of sodium bis(pyridine-2,4-dicarboxylato)cuprate(II) trihydrate. Acta Chemica Scandinavica, 53(8), 535-541.
http://dx.doi.org/10.3891/acta.chem.scand.53-0535
---------- CHICAGO ----------
Sileo, E.E., Rigotti, G., Piro, O.E. "Solid-state coordination chemistry of pyridinedicarboxylic acid isomers. II. Crystal and molecular structure of sodium bis(pyridine-2,4-dicarboxylato)cuprate(II) trihydrate" . Acta Chemica Scandinavica 53, no. 8 (1999) : 535-541.
http://dx.doi.org/10.3891/acta.chem.scand.53-0535
---------- MLA ----------
Sileo, E.E., Rigotti, G., Piro, O.E. "Solid-state coordination chemistry of pyridinedicarboxylic acid isomers. II. Crystal and molecular structure of sodium bis(pyridine-2,4-dicarboxylato)cuprate(II) trihydrate" . Acta Chemica Scandinavica, vol. 53, no. 8, 1999, pp. 535-541.
http://dx.doi.org/10.3891/acta.chem.scand.53-0535
---------- VANCOUVER ----------
Sileo, E.E., Rigotti, G., Piro, O.E. Solid-state coordination chemistry of pyridinedicarboxylic acid isomers. II. Crystal and molecular structure of sodium bis(pyridine-2,4-dicarboxylato)cuprate(II) trihydrate. Acta Chem. Scand. 1999;53(8):535-541.
http://dx.doi.org/10.3891/acta.chem.scand.53-0535