Abstract:
Mesoporous metal chalcogenides (e.g., ZnS, CuS, and derived mixed sulfide or selenides) show an extremely high potential in technological areas like catalysis, sensors, environmental protection, and photovoltaics. Although chemical bath deposition methods allow obtaining stable and porous metal chalcogenide films under mild and simple conditions, the reproducible preparation of highly ordered mesoporous sulfide thin films has been challenging so far. Herein, we present a simple and efficient synthetic method to prepare ZnS mesoporous thin films using a combination of a nanocasting approach and a successive ionic layer adsorption and reaction (SILAR) process for the infiltration. A mesoporous silica thin film, prepared by evaporation induced self-assembly (EISA), serves as the hard exotemplate for the formation of the mesostructured zinc sulfide. After selective etching of the silica framework, a stable and porous ZnS thin film is obtained, which replicates the pore structure of the hard template. A thorough combination of characterization techniques is used to assess the exotemplating process as well as the template removal. © 2012 American Chemical Society.
Registro:
Documento: |
Artículo
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Título: | Mesoporous ZnS thin films prepared by a nanocasting route |
Autor: | Fischereder, A.; Martinez-Ricci, M.L.; Wolosiuk, A.; Haas, W.; Hofer, F.; Trimmel, G.; Soler-Illia, G.J.A.A. |
Filiación: | Institute for Chemistry and Technology of Materials, Graz University of Technology, Stremayrgasse 9, 8010 Graz, Austria Christian Doppler Laboratory for Nanocomposite Solar Cells, Graz University of Technology and NanoTecCenter, Weiz Forschungsgesellschaft GmbH, Austria Institute for Electron Microscopy and Fine Structure Research, Graz University of Technology, Steyrergasse 17, 8010 Graz, Austria Gerencia Química, Centro Atómico Constituyentes Comisión Nacional de Energía Atómica, Avenida Gral Paz 1499, B1650KNA San Martín, Argentina DQIAQF, Universidad de Buenos Aires, Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria Pab. II, C1428EHA Buenos Aires, Argentina
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Palabras clave: | mesoporous film; nanocasting; SILAR; zinc sulfide; Characterization techniques; Chemical bath deposition methods; Hard templates; High potential; Mesoporous; Mesoporous films; Mesoporous metal; Mesoporous silica thin films; Mesoporous thin films; Mesostructured; Nanocasting; Ordered mesoporous; Photovoltaics; Porous metal; Selective etching; Selenides; SILAR; Successive ionic layer adsorption and reactions; Sulfide thin films; Synthetic methods; Template removal; ZnS thin films; Adsorption; Deposition; Ionic liquids; Mesoporous materials; Phase change memory; Selenium compounds; Silica; Sulfur compounds; Thin films; Vapor deposition; Zinc; Zinc sulfide; Film preparation |
Año: | 2012
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Volumen: | 24
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Número: | 10
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Página de inicio: | 1837
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Página de fin: | 1845
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DOI: |
http://dx.doi.org/10.1021/cm300395m |
Título revista: | Chemistry of Materials
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Título revista abreviado: | Chem. Mater.
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ISSN: | 08974756
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CODEN: | CMATE
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_08974756_v24_n10_p1837_Fischereder |
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Citas:
---------- APA ----------
Fischereder, A., Martinez-Ricci, M.L., Wolosiuk, A., Haas, W., Hofer, F., Trimmel, G. & Soler-Illia, G.J.A.A.
(2012)
. Mesoporous ZnS thin films prepared by a nanocasting route. Chemistry of Materials, 24(10), 1837-1845.
http://dx.doi.org/10.1021/cm300395m---------- CHICAGO ----------
Fischereder, A., Martinez-Ricci, M.L., Wolosiuk, A., Haas, W., Hofer, F., Trimmel, G., et al.
"Mesoporous ZnS thin films prepared by a nanocasting route"
. Chemistry of Materials 24, no. 10
(2012) : 1837-1845.
http://dx.doi.org/10.1021/cm300395m---------- MLA ----------
Fischereder, A., Martinez-Ricci, M.L., Wolosiuk, A., Haas, W., Hofer, F., Trimmel, G., et al.
"Mesoporous ZnS thin films prepared by a nanocasting route"
. Chemistry of Materials, vol. 24, no. 10, 2012, pp. 1837-1845.
http://dx.doi.org/10.1021/cm300395m---------- VANCOUVER ----------
Fischereder, A., Martinez-Ricci, M.L., Wolosiuk, A., Haas, W., Hofer, F., Trimmel, G., et al. Mesoporous ZnS thin films prepared by a nanocasting route. Chem. Mater. 2012;24(10):1837-1845.
http://dx.doi.org/10.1021/cm300395m