Navegar

Colección

Datos Estadísticas

Artículo

Calvo, A.; Angelomé, P.C.; Sánchez, V.M.; Scherlis, D.A.; Williams, F.J.; Soler-Illia, G.J.A.A. "Mesoporous aminopropyl-functionalized hybrid thin films with modulable surface and environment-responsive behavior" (2008) Chemistry of Materials. 20(14):4661-4668
La versión final de este artículo es de uso interno de la institución.
Consulte el artículo en la página del editor
Consulte la política de Acceso Abierto del editor

Abstract:

A first study of the behavior of amino functions in mesoporous hybrid thin films M1-x(Si-(CH2)3NH2) xO2-x/2 (M = Si, Ti, Zr; 0.05 ≤ x ≤ 0.2) with accessible Im3̄m- or Fm3̄m-derived pore mesostructures is presented. An XPS study of surface nitrogen species shows two different sites corresponding to amino and ammonium groups. The ratio of these species changes with pH and is related to the nature of M, suggesting that the interaction between the organic functions and the surface M-OH groups can be tailored to tune the surface acid-base behavior. Density functional theory (DFT) calculations were used to rationalize the XPS observations showing that -NH3 + functions irreversibly transfer a proton to neighboring M-O- surface groups. The acid-base surface properties can be further modified by adding a phosphonate "capping" on the M surface sites. Our findings have a series of interesting implications in surface functionalization: attachment of biomolecules to surfaces, design of perm-selective or philicity-selective membranes, or design of catalysts that show a well-defined organic reactive function near surface hydroxyl groups. © 2008 American Chemical Society.

Registro:

Documento: Artículo
Título:Mesoporous aminopropyl-functionalized hybrid thin films with modulable surface and environment-responsive behavior
Autor:Calvo, A.; Angelomé, P.C.; Sánchez, V.M.; Scherlis, D.A.; Williams, F.J.; Soler-Illia, G.J.A.A.
Filiación:Gerencia de Química, CNEA, Centro Atómico Constituyentes, Av. Gral Paz 1499, San Martín B1650KNA, Buenos Aires, Argentina
DQIAyQF, FCEN, Pabellón II, C1428EHA Buenos Aires, Argentina
CONICET, Av. Rivadavia 1917, C1033AAJ Buenos Aires, Argentina
Departamento de Química de Superficies y Recubrimientos, TENARIS, Simini 250, B2804MHA Campana, Buenos Aires, Argentina
Centro Interdisciplinario de Nanociencia y Nanotecnología, Av. Rivadavia 1917, C1033AAJ Buenos Aires, Argentina
Palabras clave:Amines; Thin films; Aminopropyl; Functionalized; Hybrid thin films; Mesoporous; Thick films
Año:2008
Volumen:20
Número:14
Página de inicio:4661
Página de fin:4668
DOI: http://dx.doi.org/10.1021/cm800597k
Título revista:Chemistry of Materials
Título revista abreviado:Chem. Mater.
ISSN:08974756
CODEN:CMATE
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_08974756_v20_n14_p4661_Calvo

Referencias:

  • Soler-Illia, G.J.A.A., Sanchez, C., Lebeau, B., Patarin, J., (2002) Chem. Rev, 102, p. 4093
  • Soler-Illia, G.J.A.A., Crepaldi, E.L., Grosso, D., Sanchez, C., (2003) Curr. Opin. Colloid Interface Sci, 8, p. 109
  • Shi, J.L., Hua, Z.L., Zhang, L.X., (2004) J. Mater. Chem, 14, p. 795
  • Nicole, L., Boissière, C., Grosso, D., Quach, A., Sanchez, C., (2005) J. Mater. Chem, 15, p. 3598
  • Soler-Illia, G.J.A.A., Innocenzi, P., (2006) Chem. Eur. J, 12, p. 4478
  • Otal, E.H., Angelomé, P.C., Bilmes, S.A., Soler-Illia, G.J.A.A., (2006) Adv. Mater, 18, p. 934
  • Etienne, M., Quach, A., Grosso, D., Nicole, L., Sanchez, C., Walcarius, A., (2007) Chem. Mater, 19, p. 844
  • Sanchez, C., Boissière, C., Grosso, D., Laberty, C., Nicole, L., (2008) Chem. Mater, 20, p. 682
  • Grosso, D., Cagnol, F., Soler-Illia, G.J.A.A., Crepaldi, E.L., Amenitsch, H., Brunet-Bruneau, A., Bourgeois, A., Sanchez, C., (2004) Adv. Funct. Mater, 14 (4), p. 309
  • Burkett, S.L., Sims, S.D., Mann, S., (1996) Chem. Commun, p. 1367
  • Macquarrie, D.J., (1996) Chem. Commun, p. 1961
  • Fowler, C.E., Burkett, S.L., Mann, S., (1997) Chem. Commun, p. 1769
  • Lim, M.H., Blanford, C.F., Stein, A., (1997) J. Am. Chem. Soc, 119, p. 4090
  • Fowler, C.E., Lebeau, B., Mann, S., (1998) Chem. Commun, p. 1825
  • Hall, S.R., Fowler, C.E., Lebeau, B., Mann, S., (1999) Chem. Commun, p. 201
  • Hoffmann, F., Cornelius, M., Morell, J., Fröba, M., (2006) Angew. Chem., Int. Ed, 45, p. 3216
  • Sayari, A., Hamoudi, S., (2001) Chem. Mater, 13, p. 3151
  • Stein, A., Melde, B.J., Schroden, R.C., (2000) Adv. Mater, 12, p. 1403
  • Anwander, R., (2001) Chem. Mater, 13, p. 4419
  • Angelos, S., Johansson, E., Stoddart, J.F., Zink, J.I., (2007) Adv. Funct. Mater, 17, p. 2261
  • Liu, J., Shin, Y., Nie, Z., Chang, J.H., Wang, L.-Q., Fryxell, G.E., Samuels, W.D., Exarhos, G.J., (2000) J. Phys. Chem. A, 104, p. 8328
  • Dufaud, V., Davis, M.E., (2003) J. Am. Chem. Soc, 125, p. 9403
  • Notestein, A., Katz, J.M., (2006) Chem. Eur. J, 12, p. 3954
  • Goettmann, F., Grosso, D., Mercier, F., Mathey, F., Sanchez, C., (2004) Chem. Commun, p. 1240
  • Liu, N., Assink, R.A., Smarsly, B., Brinker, C.J., (2003) Chem. Commun, p. 1146
  • Liu, N., Assink, R.A., Smarsly, B., Brinker, C.J., (2003) Chem. Commun, p. 370
  • Cagnol, F., Grosso, D., Sanchez, C., (2004) Chem. Commun, p. 1742
  • Soler-Illia, G.J.A.A., Angelomé, P.C., Bozzano, P.B., (2004) Chem. Commun, p. 2854
  • Angelomé, P.C., Soler-Illia, G.J.A.A., (2005) J. Mater. Chem, 15, p. 3903
  • Newton, M.R., Bohaty, A.K., White, H.S., Zharov, I., (2005) J. Am. Chem. Soc, 127, p. 7268
  • Fattakhova-Rohlfing, D., Wark, M., Rathouský, J., (2007) Chem. Mater, 19, p. 2640
  • Yiu, H.H.P., Wright, P.A., (2005) J. Mater. Chem, 15, p. 3690
  • Lim, M.H., Stein, A., (1999) Chem. Mater, 11, p. 3285
  • Goletto, V., Bled, A.-C., Trimmel, G., Wong Chi Man, M., Woo, H.G., Durand, D., Babonneau, F., (2002) Mater. Res. Soc. Symp. Proc, 126 (Q6), p. 14
  • Shyue, J.J., De Guire, M.R., Nakanishi, T., Masuda, Y., Koumoto, K., Sukenik, C.N., (2004) Langmuir, 20, p. 8693
  • Bagwe, R.P., Hilliard, L.R., Tan, W., (2006) Langmuir, 22, p. 4357
  • George, I.; Viel, P.; Bureau, C.; Suski, J.; Lecayon, G. Surf. Interface Anal. 1996, 24, 774; Zhmud, B.V., Pechenyi, A.B., (1995) J. Colloid Interface Sci, 173, p. 71
  • Zhmud, B.V., Sonnefeld, J., (1996) J. Non-Cryst. Solids, 195, p. 16
  • Kranias, S.; Bureau, C.; Chong, D. P.; Brenner, V.; George, I.; Viel, P.; Lecayon, G. J. Phys. Chem. B 1997, 101, 10254; Caravajal, G.S., Leyden, D.E., Quinting, G.R., Maciel, G.E., (1988) Anal. Chem, 60, p. 1776
  • van der Lee, A., (2002) Solid State Sci, 2, p. 257
  • Giannozzi, P., De Angelis, F., Car, R., (2004) J. Chem. Phys, 120, p. 5903
  • Baroni, S., Dal Corso, A., de Gironcoli, S., Giannozzi, P., Cavazzoni, P., Ballabio, G., Scandolo, S., Marzari, N., Kokalj, A, , http://www.quantum-espresso.org, accessed November 2007
  • Perdew, J.P., Burke, K., Ernzerhof, M., (1996) Phys. Rev. Lett, 77, p. 3865
  • Vanderbilt, D., (1990) Phys. Rev. B, 41, p. 7892
  • Tate, M.P., Urade, V.N., Kowalski, J.D., Wei, T.-C., Hamilton, B.D., Eggiman, B.W., Hillhouse, H.W., (2006) J. Phys. Chem. B, 110, p. 9882
  • Soler-Illia, G.J.A.A., Crepaldi, E.L., Grosso, D., Sanchez, C., (2004) J. Mater. Chem, 14, p. 1879
  • Innocenzi, P., (2003) J. Non-Cryst. Solids, 316, p. 309
  • Socrates, G., (2001) Infrared and Raman Characteristic Group Frequencies, , 3rd ed, J. Wiley and Sons: Chichester
  • Wang, X., Tseng, Y.H., Chan, J.C.C., Cheng, S., (2005) J. Catal, 233, p. 266
  • Angelomé, P. C. Ph.D. Thesis, University of Buenos Aires, 2008. See also Zhan, Z.; Zeng, H. C. J. Non-Cryst. Solids 1999, 243, 26; Holmes-Farley, S.R., Reamey, R.H., McCarthy, T.J., Deutch, J., Whitesides, G.M., (1985) Langmuir, 1, p. 725
  • Rosenholm, J.M., Lindén, M., (2007) Chem. Mater, 19, p. 5023
  • Contescu, C.I., Schwartz, J.A., (1999) Surfaces of Nanoparticles and Nanoporous Materials; Surfactant Science Series, 78, p. 51. , Contescu, C. I, Schwartz, J. A, Eds, Marcel Dekker: New York
  • Kosmulski, M., (2002) J. Colloid Interface Sci, 253, p. 77
  • Angelomé, P.C., Bilmes, S.A., Calvo, M.E., Crepaldi, E.L., Grosso, D., Sanchez, C., Soler-Illia, G.J.A.A., (2005) New J. Chem, 29, p. 59
  • Angelomé, P.C., Soler-Illia, G.J.A.A., (2005) Chem. Mater, 17, p. 322

Citas:

---------- APA ----------
Calvo, A., Angelomé, P.C., Sánchez, V.M., Scherlis, D.A., Williams, F.J. & Soler-Illia, G.J.A.A. (2008) . Mesoporous aminopropyl-functionalized hybrid thin films with modulable surface and environment-responsive behavior. Chemistry of Materials, 20(14), 4661-4668.
http://dx.doi.org/10.1021/cm800597k
---------- CHICAGO ----------
Calvo, A., Angelomé, P.C., Sánchez, V.M., Scherlis, D.A., Williams, F.J., Soler-Illia, G.J.A.A. "Mesoporous aminopropyl-functionalized hybrid thin films with modulable surface and environment-responsive behavior" . Chemistry of Materials 20, no. 14 (2008) : 4661-4668.
http://dx.doi.org/10.1021/cm800597k
---------- MLA ----------
Calvo, A., Angelomé, P.C., Sánchez, V.M., Scherlis, D.A., Williams, F.J., Soler-Illia, G.J.A.A. "Mesoporous aminopropyl-functionalized hybrid thin films with modulable surface and environment-responsive behavior" . Chemistry of Materials, vol. 20, no. 14, 2008, pp. 4661-4668.
http://dx.doi.org/10.1021/cm800597k
---------- VANCOUVER ----------
Calvo, A., Angelomé, P.C., Sánchez, V.M., Scherlis, D.A., Williams, F.J., Soler-Illia, G.J.A.A. Mesoporous aminopropyl-functionalized hybrid thin films with modulable surface and environment-responsive behavior. Chem. Mater. 2008;20(14):4661-4668.
http://dx.doi.org/10.1021/cm800597k