Artículo
Sciaini, G.; Marceca, E.; Fernández-Prini, R. "Solubility of crystalline alkali metal iodides in supercritical ammonia" (2005) Journal of Supercritical Fluids. 35(2):106-110
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Abstract:
The solubilities of crystalline NaI, KI and CsI in supercritical ammonia (SCA) were determined for temperatures around 420 K and different ammonia densities smaller than the critical density using the spectral charge-transfer-to-solvent (ctts) band of iodides. The optical absorptivity of the ctts band was also determined with the potassium salt and shown to be density independent. The results show that the solubility of the alkali metal iodides exhibit a very simple dependence on fluid density; this implies that over the density range we have explored, the first solvation shell of the ion pairs is mostly complete even at the lowest studied density. © 2005 Elsevier B.V. All rights reserved.
Registro:
| Documento: | Artículo |
| Título: | Solubility of crystalline alkali metal iodides in supercritical ammonia |
| Autor: | Sciaini, G.; Marceca, E.; Fernández-Prini, R. |
| Filiación: | INQUIMAE/DQIAQF, Facultad de Ciencias Exactas y Naturales, Pabellón II, Buenos Aires 1428, Argentina Unidad Actividad Química, Comisión Nacional de Energía Atómica, Av. Libertador 8250, Buenos Aires 1429, Argentina |
| Palabras clave: | Alkali metal iodide; Charge-transfer-to-solvent; Solubility; Solvation; Supercritical ammonia; Ammonia; Charge transfer; Light absorption; Precipitation (chemical); Solubility; Solutions; Ultraviolet radiation; Alkali metal iodide; Charge-transfer-to-solvent; Solvation; Supercritical ammonia; Alkali metals |
| Año: | 2005 |
| Volumen: | 35 |
| Número: | 2 |
| Página de inicio: | 106 |
| Página de fin: | 110 |
| DOI: | http://dx.doi.org/10.1016/j.supflu.2004.12.013 |
| Título revista: | Journal of Supercritical Fluids |
| Título revista abreviado: | J. Supercritical Fluids |
| ISSN: | 08968446 |
| CODEN: | JSFLE |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_08968446_v35_n2_p106_Sciaini |
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Citas:
---------- APA ----------
Sciaini, G., Marceca, E. & Fernández-Prini, R. (2005) . Solubility of crystalline alkali metal iodides in supercritical ammonia. Journal of Supercritical Fluids, 35(2), 106-110.http://dx.doi.org/10.1016/j.supflu.2004.12.013
---------- CHICAGO ----------
Sciaini, G., Marceca, E., Fernández-Prini, R. "Solubility of crystalline alkali metal iodides in supercritical ammonia" . Journal of Supercritical Fluids 35, no. 2 (2005) : 106-110.http://dx.doi.org/10.1016/j.supflu.2004.12.013
---------- MLA ----------
Sciaini, G., Marceca, E., Fernández-Prini, R. "Solubility of crystalline alkali metal iodides in supercritical ammonia" . Journal of Supercritical Fluids, vol. 35, no. 2, 2005, pp. 106-110.http://dx.doi.org/10.1016/j.supflu.2004.12.013
---------- VANCOUVER ----------
Sciaini, G., Marceca, E., Fernández-Prini, R. Solubility of crystalline alkali metal iodides in supercritical ammonia. J. Supercritical Fluids. 2005;35(2):106-110.http://dx.doi.org/10.1016/j.supflu.2004.12.013
