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Sanz, D.; Ponce, M.A.; Claramunt, R.M.; Fernández-Castaño, C.; Foces-Foces, C.; Elguero, J. "Synthesis and structural studies of symmetric and unsymmetric adamantylmethyleneazines" (1999) Journal of Physical Organic Chemistry. 12(6):455-469
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Abstract:

The synthesis and spectroscopic properties (1H, 13C and 15N NMR, in solution and in the solid state) of six new 1-adamantylmethlene azines are reported. The crystal and molecular structures of 1-adamantylcarbaldehyde azine and 1-adamantyl methyl ketone azine, which exist in the solid state in the E,E-configuration, were determined by x-ray analysis. The geometric characteristics of the azine central bridge and the preferred configuration with regard to it (E,E, E,Z, or Z,Z) were investigated by means of the crystallographic data retrieved from the Cambridge Structural Database and ab initio quantum chemical calculations. Copyright © 1999 John Wiley & Sons, Ltd.

Registro:

Documento: Artículo
Título:Synthesis and structural studies of symmetric and unsymmetric adamantylmethyleneazines
Autor:Sanz, D.; Ponce, M.A.; Claramunt, R.M.; Fernández-Castaño, C.; Foces-Foces, C.; Elguero, J.
Filiación:Depto. de Quim. Organ. y Biol., Facultad de Ciencias, UNED, Senda del Rey s/n, E-28040 Madrid, Spain
Departamento de Cristalografia, Inst. de Quim. Fisica Rocasolano, CSIC, Serrano 119, E-28006 Madrid, Spain
Inst. de Quím. Médica, CSIC, Juan de la Cierva 3, E-28006 Madrid, Spain
Depto. de Quim. Orgánica, Fac. de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina
Palabras clave:ab initio calculations; Adamantylmethyleneazines; Cross-polarization magic angle spinning NMR; Multinuclear magnetic resonance; X-ray structures
Año:1999
Volumen:12
Número:6
Página de inicio:455
Página de fin:469
DOI: http://dx.doi.org/10.1002/(SICI)1099-1395(199906)12:6<455::AID-POC146>3.0.CO;2-3
Título revista:Journal of Physical Organic Chemistry
Título revista abreviado:J Phys Org Chem
ISSN:08943230
CODEN:JPOCE
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_08943230_v12_n6_p455_Sanz

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Citas:

---------- APA ----------
Sanz, D., Ponce, M.A., Claramunt, R.M., Fernández-Castaño, C., Foces-Foces, C. & Elguero, J. (1999) . Synthesis and structural studies of symmetric and unsymmetric adamantylmethyleneazines. Journal of Physical Organic Chemistry, 12(6), 455-469.
http://dx.doi.org/10.1002/(SICI)1099-1395(199906)12:6<455::AID-POC146>3.0.CO;2-3
---------- CHICAGO ----------
Sanz, D., Ponce, M.A., Claramunt, R.M., Fernández-Castaño, C., Foces-Foces, C., Elguero, J. "Synthesis and structural studies of symmetric and unsymmetric adamantylmethyleneazines" . Journal of Physical Organic Chemistry 12, no. 6 (1999) : 455-469.
http://dx.doi.org/10.1002/(SICI)1099-1395(199906)12:6<455::AID-POC146>3.0.CO;2-3
---------- MLA ----------
Sanz, D., Ponce, M.A., Claramunt, R.M., Fernández-Castaño, C., Foces-Foces, C., Elguero, J. "Synthesis and structural studies of symmetric and unsymmetric adamantylmethyleneazines" . Journal of Physical Organic Chemistry, vol. 12, no. 6, 1999, pp. 455-469.
http://dx.doi.org/10.1002/(SICI)1099-1395(199906)12:6<455::AID-POC146>3.0.CO;2-3
---------- VANCOUVER ----------
Sanz, D., Ponce, M.A., Claramunt, R.M., Fernández-Castaño, C., Foces-Foces, C., Elguero, J. Synthesis and structural studies of symmetric and unsymmetric adamantylmethyleneazines. J Phys Org Chem. 1999;12(6):455-469.
http://dx.doi.org/10.1002/(SICI)1099-1395(199906)12:6<455::AID-POC146>3.0.CO;2-3