Artículo
Alvarez, J.L.; Fernandez-Prini, R.; Japas, M.L. "Aqueous nonionic solutes at infinite dilution: Thermodynamic description, including the near-critical region" (2000) Industrial and Engineering Chemistry Research. 39(10):3625-3630
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Abstract:
The possibility of describing the thermodynamic behavior of solutes at infinite dilution using a procedure based upon the Krichevskii function J = (δp/δx)(T,V)/(∞) has been explored using properties of N2, CO2, NH3, and B(OH)3 dissolved in water. The expressions obtained by fitting one property of the binary systems over a wide range of temperature and fluid density could be used to predict successfully other properties of the same solution over the same range of thermodynamic states, including the near-critical region. Alternative routes to obtain J are discussed. The possibility of describing the thermodynamic behavior of solutes at infinite dilution using a procedure based upon the Krichevskii function J = (∂p/∂x)T,V∞ has been explored using properties of N2, CO2, NH3, and B(OH)3 dissolved in water. The expressions obtained by fitting one property of the binary systems over a wide range of temperature and fluid density could be used to predict successfully other properties of the same solution over the same range of thermodynamic states, including the near-critical region. Alternative routes to obtain J are discussed.
Registro:
| Documento: | Artículo |
| Título: | Aqueous nonionic solutes at infinite dilution: Thermodynamic description, including the near-critical region |
| Autor: | Alvarez, J.L.; Fernandez-Prini, R.; Japas, M.L. |
| Filiación: | Unidad Actividad Química, Comisión National de Energía Atomica, Av. Libertador 8250, 1429 Buenos Aires, Argentina INQUIMAE, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Argentina Escuela de Ciencia y Tecnología, Universidad Nacional de General San Martín, 1651 San Andrés, Prov. Buenos Aires, Argentina |
| Palabras clave: | Krichevskii function; Ammonia; Boron compounds; Carbon dioxide; Density (specific gravity); Dissolution; Functions; Mathematical models; Nitrogen; Thermal effects; Thermodynamic properties; Water; Supercritical fluids; water; aqueous solution; article; calculation; density; dilution; solubility; solvation; temperature; thermodynamics |
| Año: | 2000 |
| Volumen: | 39 |
| Número: | 10 |
| Página de inicio: | 3625 |
| Página de fin: | 3630 |
| Título revista: | Industrial and Engineering Chemistry Research |
| Título revista abreviado: | Ind. Eng. Chem. Res. |
| ISSN: | 08885885 |
| CODEN: | IECRE |
| CAS: | water, 7732-18-5 |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_08885885_v39_n10_p3625_Alvarez |
Referencias:
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- Sedlbauer, J., O'Connell, J.P., Wood, R.H., Equation of state for correlation and prediction of thermodynamic properties at infinite dilution of aqueous electrolytes and nonelectrolytes (2000) Chem. Geol., 163, p. 43
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Citas:
---------- APA ----------
Alvarez, J.L., Fernandez-Prini, R. & Japas, M.L. (2000) . Aqueous nonionic solutes at infinite dilution: Thermodynamic description, including the near-critical region. Industrial and Engineering Chemistry Research, 39(10), 3625-3630.Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_08885885_v39_n10_p3625_Alvarez [ ]
---------- CHICAGO ----------
Alvarez, J.L., Fernandez-Prini, R., Japas, M.L. "Aqueous nonionic solutes at infinite dilution: Thermodynamic description, including the near-critical region" . Industrial and Engineering Chemistry Research 39, no. 10 (2000) : 3625-3630.Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_08885885_v39_n10_p3625_Alvarez [ ]
---------- MLA ----------
Alvarez, J.L., Fernandez-Prini, R., Japas, M.L. "Aqueous nonionic solutes at infinite dilution: Thermodynamic description, including the near-critical region" . Industrial and Engineering Chemistry Research, vol. 39, no. 10, 2000, pp. 3625-3630.Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_08885885_v39_n10_p3625_Alvarez [ ]
---------- VANCOUVER ----------
Alvarez, J.L., Fernandez-Prini, R., Japas, M.L. Aqueous nonionic solutes at infinite dilution: Thermodynamic description, including the near-critical region. Ind. Eng. Chem. Res. 2000;39(10):3625-3630.Available from: https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_08885885_v39_n10_p3625_Alvarez [ ]
