Abstract:
ABSTRACT Structured elastomer films (100-150 μm) presenting piezo and magneto resistance are described. The films are composites of filler particles, which are both electrically conductive and magnetic, dispersed in an elastomeric matrix. The particles consist of magnetite (6 nm) grouped in silver-coated aggregates (Fe3O4@Ag). The matrix is styrene-butadiene rubber (SBR) in which diethylene glycol (DEG) is added. The particles, SBR and DEG, are dispersed in toluene and then placed between two rare earth magnets. Formation of pseudo-chains (needles) of inorganic material aligned in the direction of the magnetic field is obtained after solvent evaporation. The addition of DEG is substantial to obtain an electrically conductive material. The electrical conductivity is anisotropic and increases when applying normal stresses and/or magnetic fields in the direction of the needles. The elastomers, particles, and needless were characterized by XRD, SEM, EDS, FTIR, DSC, TGA, VSM, profilometry, and stress-strain analysis. © 2015 Wiley Periodicals, Inc.
Registro:
Documento: |
Artículo
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Título: | Structured elastomeric submillimeter films displaying magneto and piezo resistivity |
Autor: | Ruiz, M.M.; Claudia Marchi, M.; Perez, O.E.; Jorge, G.E.; Fascio, M.; D'Accorso, N.; Martín Negri, R. |
Filiación: | Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina Centro de Microscopías Avanzadas (CMA), Departamento de Química Inorgánica, Universidad de Buenos Aires, Buenos Aires, Argentina Departamento de Industrias, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina Instituto de Ciencias, Universidad Nacional de General Sarmiento, Buenos Aires, Argentina Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina
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Palabras clave: | composites; elastomers; magnetoresistive composites; piezoresistive elastomers; sensors; structured elastomers; Agglomeration; Composite materials; Conductive films; Conductive materials; Elastomers; Glycols; Magnetic fields; Needles; Plastics; Rubber; Sensors; Styrene; Elastomeric matrices; Electrical conductivity; Electrically conductive; Magnetoresistive composites; Piezoresistive elastomers; Solvent evaporation; Stress-strain analysis; Styrene butadiene rubber; Silver |
Año: | 2015
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Volumen: | 53
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Número: | 8
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Página de inicio: | 574
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Página de fin: | 586
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DOI: |
http://dx.doi.org/10.1002/polb.23672 |
Título revista: | Journal of Polymer Science, Part B: Polymer Physics
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Título revista abreviado: | J Polym Sci Part B
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ISSN: | 08876266
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CODEN: | JPBPE
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_08876266_v53_n8_p574_Ruiz |
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Citas:
---------- APA ----------
Ruiz, M.M., Claudia Marchi, M., Perez, O.E., Jorge, G.E., Fascio, M., D'Accorso, N. & Martín Negri, R.
(2015)
. Structured elastomeric submillimeter films displaying magneto and piezo resistivity. Journal of Polymer Science, Part B: Polymer Physics, 53(8), 574-586.
http://dx.doi.org/10.1002/polb.23672---------- CHICAGO ----------
Ruiz, M.M., Claudia Marchi, M., Perez, O.E., Jorge, G.E., Fascio, M., D'Accorso, N., et al.
"Structured elastomeric submillimeter films displaying magneto and piezo resistivity"
. Journal of Polymer Science, Part B: Polymer Physics 53, no. 8
(2015) : 574-586.
http://dx.doi.org/10.1002/polb.23672---------- MLA ----------
Ruiz, M.M., Claudia Marchi, M., Perez, O.E., Jorge, G.E., Fascio, M., D'Accorso, N., et al.
"Structured elastomeric submillimeter films displaying magneto and piezo resistivity"
. Journal of Polymer Science, Part B: Polymer Physics, vol. 53, no. 8, 2015, pp. 574-586.
http://dx.doi.org/10.1002/polb.23672---------- VANCOUVER ----------
Ruiz, M.M., Claudia Marchi, M., Perez, O.E., Jorge, G.E., Fascio, M., D'Accorso, N., et al. Structured elastomeric submillimeter films displaying magneto and piezo resistivity. J Polym Sci Part B. 2015;53(8):574-586.
http://dx.doi.org/10.1002/polb.23672