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Fidalgo, D.M.; Kolender, A.A.; Varela, O. "Stereoregular poly-O-methyl [m,n]-polyurethanes derived from D-mannitol" (2013) Journal of Polymer Science, Part A: Polymer Chemistry. 51(2):463-470
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Abstract:

Novel linear carbohydrate-derived [m,n]-polyurethanes are successfully prepared using D-mannitol as renewable and low cost starting material. The key comonomer, 1,6-di-O-phenylcarbonyl-2,3,4,5-tetra-O-methyl-D-mannitol is polymerized with a diamine synthesized from D-mannitol or with alkylenediamines. These polymerization reactions afford, respectively, a [6,6]-polyurethane entirely based on a carbohydrate derivative or [m,n]-polyurethanes constituted by a poly-O-methyl substituted unit alternating with a polymethylene chain. All these polymers are stereoregular, as result of the C2 axis of symmetry of mannitol. The optically active polyurethanes are characterized by standard methods (FTIR, RMN, GPC, TGA, and DSC). Thus, GPC analysis reveals weight-average molecular weights between 18,000 and 25,000 Da. Thermal studies (DSC) indicate that the polymers obtained are amorphous materials with T g values dependent on the structure and chain length of the diamine constituent. © 2012 Wiley Periodicals, Inc.

Registro:

Documento: Artículo
Título:Stereoregular poly-O-methyl [m,n]-polyurethanes derived from D-mannitol
Autor:Fidalgo, D.M.; Kolender, A.A.; Varela, O.
Filiación:Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellón 2, Ciudad Universitaria, 1428 Buenos Aires, Argentina
Palabras clave:biodegradable; biomaterials; carbohydrates; D -mannitol; polyurethanes; Axis of symmetry; biodegradable; Carbohydrate derivatives; Co-monomer; D-mannitol; FTIR; GPC analysis; Low costs; Optically Active; Polymerization reaction; Polymethylene chain; Standard method; Stereoregular; Thermal study; Weight-average molecular weight; Biological materials; Biomaterials; Carbohydrates; Drug products; Polymers; Polyurethanes
Año:2013
Volumen:51
Número:2
Página de inicio:463
Página de fin:470
DOI: http://dx.doi.org/10.1002/pola.26406
Título revista:Journal of Polymer Science, Part A: Polymer Chemistry
Título revista abreviado:J Polym Sci Part A
ISSN:0887624X
CODEN:JPACE
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0887624X_v51_n2_p463_Fidalgo

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Citas:

---------- APA ----------
Fidalgo, D.M., Kolender, A.A. & Varela, O. (2013) . Stereoregular poly-O-methyl [m,n]-polyurethanes derived from D-mannitol. Journal of Polymer Science, Part A: Polymer Chemistry, 51(2), 463-470.
http://dx.doi.org/10.1002/pola.26406
---------- CHICAGO ----------
Fidalgo, D.M., Kolender, A.A., Varela, O. "Stereoregular poly-O-methyl [m,n]-polyurethanes derived from D-mannitol" . Journal of Polymer Science, Part A: Polymer Chemistry 51, no. 2 (2013) : 463-470.
http://dx.doi.org/10.1002/pola.26406
---------- MLA ----------
Fidalgo, D.M., Kolender, A.A., Varela, O. "Stereoregular poly-O-methyl [m,n]-polyurethanes derived from D-mannitol" . Journal of Polymer Science, Part A: Polymer Chemistry, vol. 51, no. 2, 2013, pp. 463-470.
http://dx.doi.org/10.1002/pola.26406
---------- VANCOUVER ----------
Fidalgo, D.M., Kolender, A.A., Varela, O. Stereoregular poly-O-methyl [m,n]-polyurethanes derived from D-mannitol. J Polym Sci Part A. 2013;51(2):463-470.
http://dx.doi.org/10.1002/pola.26406