Abstract:
The synthesis of three new stereoregular AB-type polyamides based on D-ribono-1,4-lactone, L-arabinose, and D-xylose has been carried out by the active ester polycondensation method. These polyamides were characterized by elemental analysis, IR and NMR spectroscopies, and powder X-ray diffraction. They displayed optical activity and had a pronounced affinity to water, although they were not soluble in this solvent. The polyamide obtained from D-ribono-1,4-lactone was highly crystalline and yielded films with spherulitic texture. © 1997 John Wiley & Sons, Inc.
Registro:
Documento: |
Artículo
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Título: | Synthesis and characterization of optically active polyamides derived from carbohydrate-based monomers |
Autor: | Bueno, M.; Zamora, F.; Molina, I.; Orgueira, H.A.; Varela, O.; Galbis, J.A. |
Filiación: | Depto. de Quim. Organ. y Farmaceut., Facultad de Farmacia, Universidad de Sevilla, 41071-Sevilla, Spain Depto. de Quim. Orgánica, Fac. de Ciencias Exactas y Naturales, Universidad de Buenos Aires, 1428 Buenos Aires, Argentina
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Palabras clave: | Aminoaldonic acids; Stereoregular nylons; Stereoregular polyamides; Sugar polyamides; Amino acids; Carbohydrates; Crystalline materials; Monomers; Nylon polymers; Plastic films; Polycondensation; Synthesis (chemical); Textures; Water; X ray powder diffraction; Xylose; Aminoaldonic acids; Polyamides |
Año: | 1997
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Volumen: | 35
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Número: | 17
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Página de inicio: | 3645
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Página de fin: | 3653
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DOI: |
http://dx.doi.org/10.1002/(SICI)1099-0518(199712)35:17<3645::AID-POLA4>3.0.CO;2-R |
Título revista: | Journal of Polymer Science, Part A: Polymer Chemistry
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Título revista abreviado: | J Polym Sci Part A
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ISSN: | 0887624X
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CODEN: | JPACE
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0887624X_v35_n17_p3645_Bueno |
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Citas:
---------- APA ----------
Bueno, M., Zamora, F., Molina, I., Orgueira, H.A., Varela, O. & Galbis, J.A.
(1997)
. Synthesis and characterization of optically active polyamides derived from carbohydrate-based monomers. Journal of Polymer Science, Part A: Polymer Chemistry, 35(17), 3645-3653.
http://dx.doi.org/10.1002/(SICI)1099-0518(199712)35:17<3645::AID-POLA4>3.0.CO;2-R---------- CHICAGO ----------
Bueno, M., Zamora, F., Molina, I., Orgueira, H.A., Varela, O., Galbis, J.A.
"Synthesis and characterization of optically active polyamides derived from carbohydrate-based monomers"
. Journal of Polymer Science, Part A: Polymer Chemistry 35, no. 17
(1997) : 3645-3653.
http://dx.doi.org/10.1002/(SICI)1099-0518(199712)35:17<3645::AID-POLA4>3.0.CO;2-R---------- MLA ----------
Bueno, M., Zamora, F., Molina, I., Orgueira, H.A., Varela, O., Galbis, J.A.
"Synthesis and characterization of optically active polyamides derived from carbohydrate-based monomers"
. Journal of Polymer Science, Part A: Polymer Chemistry, vol. 35, no. 17, 1997, pp. 3645-3653.
http://dx.doi.org/10.1002/(SICI)1099-0518(199712)35:17<3645::AID-POLA4>3.0.CO;2-R---------- VANCOUVER ----------
Bueno, M., Zamora, F., Molina, I., Orgueira, H.A., Varela, O., Galbis, J.A. Synthesis and characterization of optically active polyamides derived from carbohydrate-based monomers. J Polym Sci Part A. 1997;35(17):3645-3653.
http://dx.doi.org/10.1002/(SICI)1099-0518(199712)35:17<3645::AID-POLA4>3.0.CO;2-R