Artículo
Biondic, M.; Giacopello, S.; Erra Bassells, R.; Encinas, M.V.; Lissi, E.A. "Polymerization photoinitiated by carbonyl compounds. XI. Styrene polymerization photoinitiated by cyclododecanones" (1996) Journal of Polymer Science, Part A: Polymer Chemistry. 34(10):1941-1944
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Abstract:
To establish their potential as source of biradicals to initiate free-radical polymerization, 2-methyl- and 2,2,12-trimethylcyclododecanones were photolyzed in the presence of styrene. The initiation efficiency of both ketones is low - 0.03. The molecular weight of the obtained polymer is ca. 25% higher than that obtained employing photoinitiators that produce monoradicals. This difference is explained in terms of a mixed polymerization mechanism comprising mono- and biradicals. © 1996 John Wiley & Sons, Inc.
Registro:
| Documento: | Artículo |
| Título: | Polymerization photoinitiated by carbonyl compounds. XI. Styrene polymerization photoinitiated by cyclododecanones |
| Autor: | Biondic, M.; Giacopello, S.; Erra Bassells, R.; Encinas, M.V.; Lissi, E.A. |
| Filiación: | Depto. de Quim. Orgánica, Fac. de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Argentina Fac. de Quim. y Biología, Universidad de Santiago de Chile, Santiago, Chile |
| Palabras clave: | Cyclododecanones; Photoinitiation; Photopolymerization; Initiators (chemical); Ketones; Photochemical reactions; Reaction kinetics; Styrene; Cyclododecanones; Photoinitiation; Free radical polymerization |
| Año: | 1996 |
| Volumen: | 34 |
| Número: | 10 |
| Página de inicio: | 1941 |
| Página de fin: | 1944 |
| DOI: | http://dx.doi.org/10.1002/(SICI)1099-0518(19960730)34:10<1941::AID-POLA11>3.0.CO;2-I |
| Título revista: | Journal of Polymer Science, Part A: Polymer Chemistry |
| Título revista abreviado: | J Polym Sci Part A |
| ISSN: | 0887624X |
| CODEN: | JPACE |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0887624X_v34_n10_p1941_Biondic |
Referencias:
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Citas:
---------- APA ----------
Biondic, M., Giacopello, S., Erra Bassells, R., Encinas, M.V. & Lissi, E.A. (1996) . Polymerization photoinitiated by carbonyl compounds. XI. Styrene polymerization photoinitiated by cyclododecanones. Journal of Polymer Science, Part A: Polymer Chemistry, 34(10), 1941-1944.http://dx.doi.org/10.1002/(SICI)1099-0518(19960730)34:10<1941::AID-POLA11>3.0.CO;2-I
---------- CHICAGO ----------
Biondic, M., Giacopello, S., Erra Bassells, R., Encinas, M.V., Lissi, E.A. "Polymerization photoinitiated by carbonyl compounds. XI. Styrene polymerization photoinitiated by cyclododecanones" . Journal of Polymer Science, Part A: Polymer Chemistry 34, no. 10 (1996) : 1941-1944.http://dx.doi.org/10.1002/(SICI)1099-0518(19960730)34:10<1941::AID-POLA11>3.0.CO;2-I
---------- MLA ----------
Biondic, M., Giacopello, S., Erra Bassells, R., Encinas, M.V., Lissi, E.A. "Polymerization photoinitiated by carbonyl compounds. XI. Styrene polymerization photoinitiated by cyclododecanones" . Journal of Polymer Science, Part A: Polymer Chemistry, vol. 34, no. 10, 1996, pp. 1941-1944.http://dx.doi.org/10.1002/(SICI)1099-0518(19960730)34:10<1941::AID-POLA11>3.0.CO;2-I
---------- VANCOUVER ----------
Biondic, M., Giacopello, S., Erra Bassells, R., Encinas, M.V., Lissi, E.A. Polymerization photoinitiated by carbonyl compounds. XI. Styrene polymerization photoinitiated by cyclododecanones. J Polym Sci Part A. 1996;34(10):1941-1944.http://dx.doi.org/10.1002/(SICI)1099-0518(19960730)34:10<1941::AID-POLA11>3.0.CO;2-I
