Abstract:
The effect of several transition metal halides on the rates and product distribution of the carbonylation of lithium-3-oxatetramethylenamide and lithium-pentamethylenamide in THF at 0°C was examined: It was found that whereas Ni(II) has almost no effect, Cu(I), Co(II) and Cr(III) produce a noticeable inhibition, presumably due to the formation of hetero transition metal-lithium complexes. © 1995, Walter de Gruyter. All rights reserved.
Registro:
Documento: |
Artículo
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Título: | Carbonylation of cyclic lithium amides in the presence of transition metal salts |
Autor: | Nudelman, N.S.; Linares, G.G.; Schulz, H. |
Filiación: | Depto. Quimica Organica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pab. II, P. 3, 1428, Buenos Aires, Argentina
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Año: | 1995
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Volumen: | 18
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Número: | 3
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Página de inicio: | 147
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Página de fin: | 154
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DOI: |
http://dx.doi.org/10.1515/MGMC.1995.18.3.147 |
Título revista: | Main Group Metal Chemistry
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Título revista abreviado: | Main Group Met. Chem.
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ISSN: | 07921241
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07921241_v18_n3_p147_Nudelman |
Referencias:
- Ozawa, F., Soyana, H., Yanagihara, H., Aoyama, T., Takino, H., Izawa, K., Yamamoto, T., Yamamoto, A., (1985) J. Am. Chem. Soc., 107, p. 3235
- Olah, G.A., (1987) Chem. Rev., 87, p. 671
- Knifton, J.F., (1985) Platinum Metals Rev., 29, p. 63
- Giannoccaro, P., Pannacciulli, E., (1986) Inorg. Chim. Acta, 117, p. 69. , references therein
- Nudelman, N.S., Carbonylation of Main-Group Organometallic Compounds (1989) The Chemistry of Double-Bonded Functional Groups, pp. 799-962. , S. Patai, Ed.; Wiley & Sons: Chichester, Chapter 13
- Whipple, W.L., Reich, H.J., (1991) J. Org. Chem., 56, p. 2911
- Fraenkel, G., Hsu, H., Su, B.P., (1985) Lithium Current Applications in Science, Medicine and Tecnology, , R. O. Bach, Ed.; Wiley: New York, Chapter 19
- Knapp, S., Levorse, A.T., (1988) J. Org. Chem., 53, p. 4006
- Miller, M.J., (1986) Acc. Chem. Res., 19, p. 49
- Griego, P.A., Hon, Y.S., Perez-Medrano, A., (1988) J. Am. Chem. Soc, 110, p. 630
- Battiste, M.A., Roca, J.R., Wydra, R.L., Tumlinson, J.H., III, Chuman, T., (1988) Tetrahedron Lett., 29, p. 6565
- Park, S., Rheingold, A.L., Roundhill, D.M., (1991) Organometallics, 10, p. 615
- Murahashi, S.I., Imada, Nishimura, K., (1994) Tetrahedron, 50, p. 453
- Bryndza, H.E., Tam, A., (1988) Chem Rev., 88, p. 1163
- Chen, J.T., Tzeng, W.H., Tsai, F.Y., Cheng, M.C., Wang, Y., (1991) Organometallics, 10, p. 3954
- Basolo, F., (1994) New J. Chem., 18, p. 19
- Roberto, D., Alper, H., (1990) Organometallics, 9, p. 1245
- Perez, D.G., Nudelman, N.S., (1988) J. Org. Chem, 53, p. 408
- Nudelman, N.S., Lewkowicz, E., Perez, D.G., (1990) Synthesis, p. 917. , refs. therein
- Mizuno, T., Nishiguchi, I., Hirashima, T., (1993) Tetrahedron, 49, p. 2403
- Orita, A., Ohe, H., Murai, S., (1994) Organometallics, 13, p. 1533
- Nudelman, N.S., Lewkowicz, E., Furlong, J.J.P., (1993) J. Org. Chem., 58, p. 1847
- Collman, J.P., Hegedus, L.S., Norton, J.R., Finke, R.G., (1987) Principles and Applications of Organotransition Metal Chemistry, , University Science Books, Mill Valey, California
- Shriver, D.T., (1969) The Manipulation of Air Sensitive Compounds, , McGraw-Hill: New York, Chapter 7
- Nudelman, N.S., Perez, D.G., (1983) J. Org. Chem., 48, p. 133
- Furlong, J.J.P., Lewkowicz, E., Nudelman, N.S., (1990) J. Chem. Soc. Perkin Trans 2, p. 144
- Nudelman, N.S., Lewkowicz, E., Furlong, J.J.P., (1993) J. Org. Chem, 58, p. 1847
- Adams, D.M., Raynor, J.B., (1965) Inert - Atmosphere Technique in Advanced Practical Inorganic Chemistry., p. 93. , Wiley & Sons, Ltd. London, New York
- Vogel, A., (1955) A. Textbook of Practical Organic Chemistry, p. 694. , Longman: Londres, 3th ed
- Bernstein, M.P., Collum, D.B., (1993) J. Am Chem. Soc., 115, p. 789
- Seebach, D., (1990) Angew. Chem., Int. Ed. Engl., 29, p. 3
- Jackman, L.M., Scarmoutzos, L.M., (1987) J. Am Chem. Soc., 109, p. 5348
- Gregory, K., Schleyer, P.V.R., Snaith, R., (1991) Adv. Inorg. Chem, 37, p. 47
- Hall, P.L., Gilchrist, J.H., Harrison, A.T., Fuller, D.J., Collum, D.B., (1991) J. Am Chem. Soc., 135, p. 9575
- Vieth, M., Spaniol, A., Pohlman, J., Gross, F., Huch, V., (1993) Chem Ber., 126, p. 2625
- Williard, P.G., Nichols, M.A., (1991) J. Am. Chem. Soc., 113, p. 9671
Citas:
---------- APA ----------
Nudelman, N.S., Linares, G.G. & Schulz, H.
(1995)
. Carbonylation of cyclic lithium amides in the presence of transition metal salts. Main Group Metal Chemistry, 18(3), 147-154.
http://dx.doi.org/10.1515/MGMC.1995.18.3.147---------- CHICAGO ----------
Nudelman, N.S., Linares, G.G., Schulz, H.
"Carbonylation of cyclic lithium amides in the presence of transition metal salts"
. Main Group Metal Chemistry 18, no. 3
(1995) : 147-154.
http://dx.doi.org/10.1515/MGMC.1995.18.3.147---------- MLA ----------
Nudelman, N.S., Linares, G.G., Schulz, H.
"Carbonylation of cyclic lithium amides in the presence of transition metal salts"
. Main Group Metal Chemistry, vol. 18, no. 3, 1995, pp. 147-154.
http://dx.doi.org/10.1515/MGMC.1995.18.3.147---------- VANCOUVER ----------
Nudelman, N.S., Linares, G.G., Schulz, H. Carbonylation of cyclic lithium amides in the presence of transition metal salts. Main Group Met. Chem. 1995;18(3):147-154.
http://dx.doi.org/10.1515/MGMC.1995.18.3.147