Artículo
Favaro, D.C.; Contreras, R.H.; Tormena, C.F. "The electronic origin of unusually large nJFN coupling constants in some fluoroximes" (2013) Magnetic Resonance in Chemistry. 51(6):334-338
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Abstract:
SOPPA(CCSD) calculations show that the FC term is the most important contribution to the through-space transmission of JFN coupling constants for the fluoroximes studied in this work. Because of the well-known behavior of FC term, a new rationalization for the experimental TSJFN SSCC is presented. It is mainly based on the overlap matrix (Sij) between fluorine and nitrogen lone pairs obtained from NBO analyses. An expression is proposed to take into account the influence of the electronic density (Dij) between coupled nuclei as well as the s% character at the site of the coupling nuclei of bonds and non-bonding electron pairs involved in Dij. In using this approach, a linear correlation between TSJFN versus Dij is obtained. The most important aspect of this rationalization is related to the facility for understanding the behavior of some unusual experimental coupling constants. It is shown that, at least in this case, the electronic origin of the so-called through-space coupling is transmitted through to the overlap of orbitals on the coupled atoms, suggesting that, at least for these compounds, instead of through-space coupling, it should better be dubbed as 'through overlapping orbital coupling'. Copyright © 2013 John Wiley & Sons, Ltd.
Registro:
| Documento: | Artículo |
| Título: | The electronic origin of unusually large nJFN coupling constants in some fluoroximes |
| Autor: | Favaro, D.C.; Contreras, R.H.; Tormena, C.F. |
| Filiación: | Chemistry Institute, State University of Campinas, P.O. Box 6154, 13084-971 Campinas, Sao Paulo, Brazil Department of Physics, FCEyN, University of Buenos Aires and IFIBA-CONICET, Buenos Aires, Argentina |
| Palabras clave: | nJFN through space coupling constants; dFN dependence; lone pairs interaction; overlap matrix; oxime; article; chemical structure; chemistry; electron; nuclear magnetic resonance spectroscopy; quantum theory; standard; Electrons; Magnetic Resonance Spectroscopy; Molecular Structure; Oximes; Quantum Theory; Reference Standards |
| Año: | 2013 |
| Volumen: | 51 |
| Número: | 6 |
| Página de inicio: | 334 |
| Página de fin: | 338 |
| DOI: | http://dx.doi.org/10.1002/mrc.3950 |
| Título revista: | Magnetic Resonance in Chemistry |
| Título revista abreviado: | Magn. Reson. Chem. |
| ISSN: | 07491581 |
| CODEN: | MRCHE |
| CAS: | Oximes |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07491581_v51_n6_p334_Favaro |
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Citas:
---------- APA ----------
Favaro, D.C., Contreras, R.H. & Tormena, C.F. (2013) . The electronic origin of unusually large nJFN coupling constants in some fluoroximes. Magnetic Resonance in Chemistry, 51(6), 334-338.http://dx.doi.org/10.1002/mrc.3950
---------- CHICAGO ----------
Favaro, D.C., Contreras, R.H., Tormena, C.F. "The electronic origin of unusually large nJFN coupling constants in some fluoroximes" . Magnetic Resonance in Chemistry 51, no. 6 (2013) : 334-338.http://dx.doi.org/10.1002/mrc.3950
---------- MLA ----------
Favaro, D.C., Contreras, R.H., Tormena, C.F. "The electronic origin of unusually large nJFN coupling constants in some fluoroximes" . Magnetic Resonance in Chemistry, vol. 51, no. 6, 2013, pp. 334-338.http://dx.doi.org/10.1002/mrc.3950
---------- VANCOUVER ----------
Favaro, D.C., Contreras, R.H., Tormena, C.F. The electronic origin of unusually large nJFN coupling constants in some fluoroximes. Magn. Reson. Chem. 2013;51(6):334-338.http://dx.doi.org/10.1002/mrc.3950
