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Abstract:

13C NMR spectra for 23 3‐substituted‐5β‐steroidal derivatives have been obtained and individual resonances assigned. The different chemical shifts due to conformational and side chain changes are rationalized in terms of steric interactions. From these results a preferred is conformer is proposed for the cholanoic acid side chain derivatives in solution. Copyright © 1986 John Wiley & Sons, Ltd.

Registro:

Documento: Artículo
Título:Studies on the conformations in solution of 5β‐steroids having different side chains by 13C NMR spectroscopy
Autor:Seldes, A.M.; Deluca, M.E.; Gros, E.G.
Filiación:Departamento de Quimica Orgànica Y Umymfor, Facultad de Ciencias Exactas Y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pab. 2, Buenos Aires, 1428, Argentina
Año:1986
Volumen:24
Número:3
Página de inicio:185
Página de fin:189
DOI: http://dx.doi.org/10.1002/mrc.1260240302
Título revista:Magnetic Resonance in Chemistry
Título revista abreviado:Magn. Reson. Chem.
ISSN:07491581
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07491581_v24_n3_p185_Seldes

Referencias:

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Citas:

---------- APA ----------
Seldes, A.M., Deluca, M.E. & Gros, E.G. (1986) . Studies on the conformations in solution of 5β‐steroids having different side chains by 13C NMR spectroscopy. Magnetic Resonance in Chemistry, 24(3), 185-189.
http://dx.doi.org/10.1002/mrc.1260240302
---------- CHICAGO ----------
Seldes, A.M., Deluca, M.E., Gros, E.G. "Studies on the conformations in solution of 5β‐steroids having different side chains by 13C NMR spectroscopy" . Magnetic Resonance in Chemistry 24, no. 3 (1986) : 185-189.
http://dx.doi.org/10.1002/mrc.1260240302
---------- MLA ----------
Seldes, A.M., Deluca, M.E., Gros, E.G. "Studies on the conformations in solution of 5β‐steroids having different side chains by 13C NMR spectroscopy" . Magnetic Resonance in Chemistry, vol. 24, no. 3, 1986, pp. 185-189.
http://dx.doi.org/10.1002/mrc.1260240302
---------- VANCOUVER ----------
Seldes, A.M., Deluca, M.E., Gros, E.G. Studies on the conformations in solution of 5β‐steroids having different side chains by 13C NMR spectroscopy. Magn. Reson. Chem. 1986;24(3):185-189.
http://dx.doi.org/10.1002/mrc.1260240302