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Abstract:

The O2/Li2O2 electrode reaction has been studied on low surface area Au electrodes in three solvent-electrolyte pairs (0.1 M LiPF6/DMSO, LiPF6/ACN, and LiBF4/ACN) using an electrochemical cell coupled to UHV XPS spectrometer, EQCM, AFM, and DEMS. The XPS spectra of the surfaces after treatment at selected electrode potentials for the O2 reduction and reoxidation of the surface show the presence of C and S from solvent decomposition and of F and P from electrolyte decomposition. Furthermore, Li 1s and O 1s peaks due to Li2O2 and decomposition products such as carbonate, organics, LiF, high oxidation sulfur, and phosphorus compounds were also observed. Using ACN instead of DMSO results in less solvent decomposition, whereas using LiBF4 results in less electrolyte decomposition. XPS, AFM, and EQCM show that O2 reduction products removal only takes place at very high overpotentials. In agreement with XPS which shows removal of carbonate surface species, DEMS confirms evolution of CO2 and consumption of O2 at 4.5 V, but LiF cannot be removed completely in a round trip of the Li-O2 battery cathode. © 2015 American Chemical Society.

Registro:

Documento: Artículo
Título:Surface Study of Lithium-Air Battery Oxygen Cathodes in Different Solvent-Electrolyte pairs
Autor:Marchini, F.; Herrera, S.; Torres, W.; Tesio, A.Y.; Williams, F.J.; Calvo, E.J.
Filiación:INQUIMAE, Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria, Pabellón 2, Buenos Aires, AR-1428, Argentina
Palabras clave:Cathodes; Electric batteries; Electrodes; Electrolytes; Lithium; Lithium batteries; Phosphorus compounds; Reduction; Solvents; X ray photoelectron spectroscopy; Carbonate surfaces; Decomposition products; Different solvents; Electrode potentials; Electrode reactions; Electrolyte decomposition; Lithium-air battery; Solvent decompositions; Electrochemical electrodes
Año:2015
Volumen:31
Número:33
Página de inicio:9236
Página de fin:9245
DOI: http://dx.doi.org/10.1021/acs.langmuir.5b02130
Título revista:Langmuir
Título revista abreviado:Langmuir
ISSN:07437463
CODEN:LANGD
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07437463_v31_n33_p9236_Marchini

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Citas:

---------- APA ----------
Marchini, F., Herrera, S., Torres, W., Tesio, A.Y., Williams, F.J. & Calvo, E.J. (2015) . Surface Study of Lithium-Air Battery Oxygen Cathodes in Different Solvent-Electrolyte pairs. Langmuir, 31(33), 9236-9245.
http://dx.doi.org/10.1021/acs.langmuir.5b02130
---------- CHICAGO ----------
Marchini, F., Herrera, S., Torres, W., Tesio, A.Y., Williams, F.J., Calvo, E.J. "Surface Study of Lithium-Air Battery Oxygen Cathodes in Different Solvent-Electrolyte pairs" . Langmuir 31, no. 33 (2015) : 9236-9245.
http://dx.doi.org/10.1021/acs.langmuir.5b02130
---------- MLA ----------
Marchini, F., Herrera, S., Torres, W., Tesio, A.Y., Williams, F.J., Calvo, E.J. "Surface Study of Lithium-Air Battery Oxygen Cathodes in Different Solvent-Electrolyte pairs" . Langmuir, vol. 31, no. 33, 2015, pp. 9236-9245.
http://dx.doi.org/10.1021/acs.langmuir.5b02130
---------- VANCOUVER ----------
Marchini, F., Herrera, S., Torres, W., Tesio, A.Y., Williams, F.J., Calvo, E.J. Surface Study of Lithium-Air Battery Oxygen Cathodes in Different Solvent-Electrolyte pairs. Langmuir. 2015;31(33):9236-9245.
http://dx.doi.org/10.1021/acs.langmuir.5b02130