Navegar

Colección

Datos Estadísticas

Artículo

El editor solo permite decargar el artículo en su versión post-print desde el repositorio. Por favor, si usted posee dicha versión, enviela a
Consulte el artículo en la página del editor
Consulte la política de Acceso Abierto del editor

Abstract:

The crystalline chloride form of layered double hydroxide (LDH) with the formula Mg0.75Al0.25(OH)2Cl 0.25·mH2O was gradually exchanged with F -, Br-, or I- up to a total displacement of Cl-. For the three anions, both the exchange isotherms as well as the structural changes were inspected along the whole range of chloride displacement. The bulkier Br- and I- followed an ideal exchange behavior isotherm while F- denoted strong deviations from the ideal regime as well as phase segregation. The exchange constants recorded herein were contrasted with bibliographic data belonging to an analogous LDH host, revealing a strong linear free energy correlation. Higher Al(III) to Mg(II) ratios, or layer charge densities, favor a stronger selectivity for smaller halides. For both hosts, the exchange free energy was satisfactorily described in terms of strictly electrostatic-based models. © 2014 American Chemical Society.

Registro:

Documento: Artículo
Título:Halide exchange on Mg(II)-Al(III) layered double hydroxides: Exploring affinities and electrostatic predictive models
Autor:Oestreicher, V.; Jobbágy, M.; Regazzoni, A.E.
Filiación:INQUIMAE-DQIAQF, Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria, C1428EHA, Buenos Aires, Argentina
Centro Interdisciplinario de Nanociencia y Nanotecnología, Argentina
Unidad de Actividad Química, Centro Atómico Constituyentes, Comisión Nacional de Energía Atómica, Avenida General Paz 1499, B1650KNA-San-Martín, Argentina
Instituto de Tecnología Jorge Sábato, Universidad Nacional de General San Martín, Avenida General Paz 1499, B1650KNA-San-Martín, Argentina
Palabras clave:Chlorine compounds; Electrostatics; Free energy; Isotherms; Bibliographic data; Chloride displacement; Exchange constants; Layer charge density; Layered double hydroxides; Linear free energy; Phase segregations; Predictive models; Aluminum
Año:2014
Volumen:30
Número:28
Página de inicio:8408
Página de fin:8415
DOI: http://dx.doi.org/10.1021/la5015187
Título revista:Langmuir
Título revista abreviado:Langmuir
ISSN:07437463
CODEN:LANGD
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07437463_v30_n28_p8408_Oestreicher

Referencias:

  • Rives, V., Layered Double Hydroxides: Present and Future, , Nova Publishers: New York, 2001
  • Evans, D.G., Slade, R.C.T., Structural aspects of layered double hydroxides (2006) Layered Double Hydroxides, 119, pp. 1-87. , Springer: New York
  • Sideris, P.J., Nielsen, U.G., Gan, Z.H., Grey, C.P., Mg/Al ordering in layered double hydroxides revealed by multinuclear NMR spectroscopy (2008) Science, 321, pp. 113-117
  • Rives, V., Ulibarri, M.A., Layered double hydroxides (LDH) intercalated with metal coordination compounds and oxometalates (1999) Coord. Chem. Rev., 181, pp. 61-120
  • Newman, S.P., Jones, W., Synthesis, characterization and applications of layered double hydroxides containing organic guests (1998) New J. Chem., 22, pp. 105-115
  • Leroux, F., Besse, J.P., Polymer interleaved layered double hydroxide: A new emerging class of nanocomposites (2001) Chem. Mater., 13, pp. 3507-3515
  • Costantino, U., Coletti, N., Nocchetti, M., Aloisi, G.G., Elisei, F., Anion exchange of methyl orange into Zn-Al synthetic hydrotalcite and photophysical characterization of the intercalates obtained (1999) Langmuir, 15, pp. 4454-4460
  • Costantino, U., Coletti, N., Nocchetti, M., Aloisi, G.G., Elisei, F., Latterini, L., Surface uptake and intercalation of fluorescein anions into Zn-Al-hydrotalcite. Photophysical characterization of materials obtained (2000) Langmuir, 16, pp. 10351-10358
  • Prasanna, S.V., Kamath, P.V., Chromate uptake characteristics of the pristine layered double hydroxides of Mg with Al (2008) Solid State Sci., 10, pp. 260-266
  • Prasanna, S.V., Kamath, P.V., Anion-exchange reactions of layered double hydroxides: Interplay between coulombic and H-bonding interactions (2009) Ind. Eng. Chem. Res., 48, pp. 6315-6320
  • Wang, H.T., Chen, J., Cai, Y.F., Ji, J.F., Lin, L.W., Teng, H.H., Defluoridation of drinking water by Mg/Al hydrotalcite-like compounds and their calcined products (2007) Appl. Clay Sci., 35 (12), pp. 59-66
  • Wang, S.L., Liu, C.H., Wang, M.K., Chuang, Y.H., Chiang, P.N., Arsenate adsorption by Mg/Al-NO3 layered double hydroxides with varying the Mg/Al ratio (2009) Appl. Clay Sci., 43 (1), pp. 79-85
  • Das, J., Patra, B.S., Baliarsingh, N., Parida, K.M., Adsorption of phosphate by layered double hydroxides in aqueous solutions (2006) Appl. Clay Sci., 32 (34), pp. 252-260
  • Das, N.N., Konar, J., Mohanta, M.K., Srivastava, S.C., Adsorption of Cr(VI) and Se(IV) from their aqueous solutions onto Zr 4+-substituted ZnAl/MgAl-layered double hydroxides: Effect of Zr 4+ substitution in the layer (2004) J. Colloid Interface Sci., 270 (1), pp. 1-8
  • Das, J., Patra, B.S., Baliarsingh, N., Parida, K.M., Calcined Mg-Fe-CO3 LDH as an adsorbent for the removal of selenite (2007) J. Colloid Interface Sci., 316, pp. 216-223
  • Chuang, Y.H., Tzou, Y.M., Wang, M.K., Liu, C.H., Chiang, P.N., Removal of 2-chlorophenol from aqueous solution by Mg/Al layered double hydroxide (LDH) and modified LDH (2008) Ind. Eng. Chem. Res., 47 (11), pp. 3813-3819
  • Chitrakar, R., Tezuka, S., Sonoda, A., Sakane, K., Ooi, K., Hirotsu, T., Adsorption of phosphate from seawater on calcined MgMn-layered double hydroxides (2005) J. Colloid Interface Sci., 290 (1), pp. 45-51
  • Jobbagy, M., Regazzoni, A.E., Partition of non-ionic organics in hybrid-hydrotalcite/water systems (2006) Chem. Phys. Lett., 433 (13), pp. 62-66
  • Lazaridis, N.K., Karapantsios, T.D., Georgantas, D., Kinetic analysis for the removal of a reactive dye from aqueous solution onto hydrotalcite by adsorption (2003) Water Res., 37 (12), pp. 3023-3033
  • Lakraimi, M., Legrouri, A., Barroug, A., De Roy, A., Besse, J.P., Removal of pesticides from water by anionic clays (1999) J. Chim. Phys., 96 (3), pp. 470-478
  • Bascialla, G., Regazzoni, A.E., Immobilization of anionic dyes by intercalation into hydrotalcite (2008) Colloids Surf., A, 328 (13), pp. 34-39
  • Ookubo, A., Ooi, K., Tani, F., Hayashi, H., Phase-transition of Cl-intercalated hydrotalcite-like compound during ion-exchange with phosphates (1994) Langmuir, 10 (2), pp. 407-411
  • Ookubo, A., Ooi, K., Hayashi, H., Preparation and phosphate ion-exchange properties of a hydrotalcite-like compound (1993) Langmuir, 9 (5), pp. 1418-1422
  • Goh, K.H., Lim, T.T., Dong, Z., Application of layered double hydroxides for removal of oxyanions: A review (2008) Water Res., 42 (67), pp. 1343-1368
  • Miyata, S., Anion-exchange properties of hydrotalcite-like compounds (1983) Clays Clay Miner., 31 (4), pp. 305-311
  • Israëli, Y., Taviot-Gueho, T., Beese, J.P., Morel, J.P., Morel-Desrosiers, N., Thermodynamics of anion exchange on a chloride-intercalated zinc-aluminum layered double hydroxide: A microcalorimetric study (2000) Dalton, 5, pp. 791-796
  • Costa, D.G., Rocha, A.B., Souza, W.F., Chiaro, S.S.X., Leitao, A.A., Comparative structural, thermodynamic and electronic analyses of Zn-Al-An - Hydrotalcite-like compounds An -=Cl -, F-, Br-, OH-, CO3 2- or NO3-: An ab initio study (2012) Appl. Clay Sci., 56, pp. 16-22
  • Iyi, N., Matsumoto, T., Kaneko, Y., Kitamura, K., Deintercalation of carbonate ions from a hydrotalcite-like compound: Enhanced decarbonation using acid-salt mixed solution (2004) Chem. Mater., 16 (15), pp. 2926-2932
  • Iyi, N., Ebina, Y., Sasaki, T., Water-swellable MgAl-LDH (layered double hydroxide) hybrids: Synthesis, characterization, and film preparation (2008) Langmuir, 24 (10), pp. 5591-5598
  • Iyi, N., Sasaki, T., Decarbonation of MgAl-LDHs (layered double hydroxides) using acetate-buffer/NaCl mixed solution (2008) J. Colloid Interface Sci., 322 (1), pp. 237-245
  • Jobbágy, M., Regazzoni, A.E., Dissolution of nano-size Mg-Al-Cl hydrotalcite in aqueous media (2011) Appl. Clay Sci., 51 (3), pp. 366-369
  • Jobbágy, M., Regazzoni, A.E., Anion-exchange equilibrium and phase segregation in hydrotalcite systems: Intercalation of hexacyanoferrate(III) ions (2005) J. Phys. Chem. B, 109 (1), pp. 389-393
  • Iyi, N., Fujii, K., Okamoto, K., Sasaki, T., Factors influencing the hydration of layered double hydroxides (LDHs) and the appearance of an intermediate second staging phase (2007) Appl. Clay Sci., 35 (34), pp. 218-227
  • Aimoz, L., Taviot-Gueho, C., Churakov, S.V., Chukalina, M., Dahn, R., Curti, E., Bordet, P., Vespa, M., Anion and cation order in iodide-bearing Mg/Zn-Al layered double hydroxides (2012) J. Phys. Chem. C, 116 (9), pp. 5460-5475
  • Jobbagy, M., Iyi, N., Interplay of charge density and relative humidity on the structure of nitrate layered double hydroxides (2010) J. Phys. Chem. C, 114 (42), pp. 18153-18158
  • Prasanna, S.V., Radha, A.V., Kamath, P.V., Kannan, S., Bromide-ion distribution in the interlayer of the layered double hydroxides of Zn and Al: Observation of positional disorder (2009) Clays Clay Miner., 57 (1), pp. 82-92
  • Bastianini, M., Costenaro, D., Bisio, C., Marchese, L., Costantino, U., Vivani, R., Nocchetti, M., On the intercalation of the iodine-iodide couple on layered double hydroxides with different particle sizes (2012) Inorg. Chem., 51 (4), pp. 2560-2568
  • Sposito, G., (1981) The Thermodynamics of Soil Solutions, , Oxford Science Publ. Oxford, U.K
  • Nagendran, S., Kamath, P.V., Structure of the chloride- and bromide-intercalated layered double hydroxides of Li and Al. Interplay of Coulombic and hydrogen-bonding interactions in the interlayer gallery (2013) Eur. J. Inorg. Chem., 2013 (26), pp. 4686-4693
  • Hines, D.R., Solin, S.A., Costantino, U., Nocchetti, M., Physical properties of fixed-charge layer double hydroxides (2000) Phys. Rev. B, 61, pp. 11348-11358
  • Kalinichev, A.G., Kirkpatrick, R.J., Molecular dynamics modeling of chloride binding to the surfaces of calcium hydroxide, hydrated calcium aluminate, and calcium silicate phases (2002) Chem. Mater., 14 (8), pp. 3539-3549
  • Kalinichev, A.G., Kirkpatrick, R.J., Cygan, R.T., Molecular modeling of the structure and dynamics of the interlayer and surface species of mixed-metal layered hydroxides: Chloride and water in hydrocalumite (Friedels salt) (2000) Am. Mineral., 85 (78), pp. 1046-1052
  • Thomas, G.S., Kamath, P.V., Kannan, S., Variable temperature PXRD studies of LiAl2(OH) 6X.H2O (X = Cl, Br): Observation of disorder → order transformation in the interlayer (2007) J. Phys. Chem. C, 111 (51), pp. 18980-18984
  • Li, H., Ma, J., Evans, D.G., Zhou, T., Li, F., Duan, X., Molecular dynamics modeling of the structures and binding energies of alpha-nickel hydroxides and nickel-aluminum layered double hydroxides containing various interlayer guest anions (2006) Chem. Mater., 18 (18), pp. 4405-4414
  • Gaines, G.L., Thomas, H.C., Adsorption studies on clay minerals. II. A formulation of the thermodynamics of exchange adsorption (1953) J. Chem. Phys., 21 (4), pp. 714-718
  • Cavani, F., Trifiro, F., Vaccari, A., Hydrotalcite-type anionic clays: Preparation, properties and applications (1991) Catal. Today, 11 (2), pp. 173-301
  • Bravo-Suárez, J.J., Paez-Mozo, E.A., Oyama, S.T., Models for the estimation of thermodynamic properties of layered double hydroxides: Application to the study of their anion exchange characteristics (2004) Quim. Nova, 27 (4), pp. 574-581
  • Barrer, R.M., Townsend, R.P., Transition-metal ion exchange in zeolites. 2. Amines of Co2+, Cu2+ and Zn2+ in clinoptilolite, mordenite and phillpsite (1976) J. Chem. Soc., Faraday Trans. 1, 72, pp. 2650-2660
  • Barrer, R.M., Klinowski, J., Influence of framework charge density on ion-exchange properties of zeolites (1972) J. Chem. Soc., Faraday Trans. 1, 68, pp. 1956-1963
  • Shannon, R.D., Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides (1976) Acta Crystallogr. Sect. B., 32, pp. 751-767
  • Eisenman, G., Cation selective glass electrodes and their mode of operation (1962) Biophys. J., 2, pp. 259-323
  • Xu, Z.P., Zeng, H.C., Abrupt structural transformation in hydrotalcite-like compounds Mg 1- xAlx(OH)2(NO3) x· n H2O as a continuous function of nitrate anions (2001) J. Phys. Chem. B, 105 (9), pp. 1743-1749
  • Richardson, I.G., Clarification of possible ordered distributions of trivalent cations in layered double hydroxides and an explanation for the observed variation in the lower solid-solution limit (2013) Acta Crystallogr., Sect. B, 69 (6), pp. 629-633

Citas:

---------- APA ----------
Oestreicher, V., Jobbágy, M. & Regazzoni, A.E. (2014) . Halide exchange on Mg(II)-Al(III) layered double hydroxides: Exploring affinities and electrostatic predictive models. Langmuir, 30(28), 8408-8415.
http://dx.doi.org/10.1021/la5015187
---------- CHICAGO ----------
Oestreicher, V., Jobbágy, M., Regazzoni, A.E. "Halide exchange on Mg(II)-Al(III) layered double hydroxides: Exploring affinities and electrostatic predictive models" . Langmuir 30, no. 28 (2014) : 8408-8415.
http://dx.doi.org/10.1021/la5015187
---------- MLA ----------
Oestreicher, V., Jobbágy, M., Regazzoni, A.E. "Halide exchange on Mg(II)-Al(III) layered double hydroxides: Exploring affinities and electrostatic predictive models" . Langmuir, vol. 30, no. 28, 2014, pp. 8408-8415.
http://dx.doi.org/10.1021/la5015187
---------- VANCOUVER ----------
Oestreicher, V., Jobbágy, M., Regazzoni, A.E. Halide exchange on Mg(II)-Al(III) layered double hydroxides: Exploring affinities and electrostatic predictive models. Langmuir. 2014;30(28):8408-8415.
http://dx.doi.org/10.1021/la5015187