Artículo

La versión final de este artículo es de uso interno. El editor solo permite incluir en el repositorio el artículo en su versión post-print. Por favor, si usted la posee enviela a
Consulte el artículo en la página del editor
Consulte la política de Acceso Abierto del editor

Abstract:

Pure Mg2Al(OH)6Cl·1.5H2O layered double hydroxide (LDH) has been synthesized at room temperature by a one-pot method, homogeneously driven by chloride-assisted glycidol rupture (epoxide route). Well-defined nanoplatelet texture was achieved and the LDH crystallization mechanism discussed. Nanoplatelets self-assemble in the form of highly oriented films with excellent optical properties. LDH films exhibited stability toward detaching in aqueous solutions and allowed a fast anionic exchange preserving a high transparency. © 2013 American Chemical Society.

Registro:

Documento: Artículo
Título:One pot synthesis of Mg2Al(OH)6Cl·1.5H 2O layered double hydroxides: The epoxide route
Autor:Oestreicher, V.; Jobbágy, M.
Filiación:INQUIMAE-DQIAQF, Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria, Buenos Aires, Argentina
Centro Interdisciplinario de Nanociencia y Nanotecnología, Buenos Aires, Argentina
Palabras clave:Anionic exchange; Crystallization mechanisms; High transparency; Highly oriented films; Layered double hydroxides; One-pot method; One-pot synthesis; Room temperature; Condensed matter physics; Electrochemistry; Chlorine compounds
Año:2013
Volumen:29
Número:39
Página de inicio:12104
Página de fin:12109
DOI: http://dx.doi.org/10.1021/la402260m
Título revista:Langmuir
Título revista abreviado:Langmuir
ISSN:07437463
CODEN:LANGD
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07437463_v29_n39_p12104_Oestreicher

Referencias:

  • Liu, Z., Ma, R., Ebina, Y., Iyi, N., Takada, K., Sasaki, T., General synthesis and delamination of highly crystalline transition-metal-bearing layered double hydroxides (2007) Langmuir, 23 (2), pp. 861-867
  • Iyi, N., Ebina, Y., Sasaki, T., Water-swellable MgAl-LDH (layered double hydroxide) hybrids: Synthesis, characterization, and film preparation (2008) Langmuir, 24 (10), pp. 5591-5598
  • Wang, Q., O'Hare, D., Recent Advances in the Synthesis and Application of Layered Double Hydroxide (LDH) Nanosheets (2012) Chem. Rev., 112 (7), pp. 4124-4155
  • Liu, Z.P., Ma, R.Z., Osada, M., Iyi, N., Ebina, Y., Takada, K., Sasaki, T., Synthesis, anion exchange, and delamination of Co-Al layered double hydroxide: Assembly of the exfoliated nanosheet/polyanion composite films and magneto-optical studies (2006) J. Am. Chem. Soc., 128 (14), pp. 4872-4880
  • Li, L., Ma, R.Z., Iyi, N., Ebina, Y., Takada, K., Sasaki, T., Hollow nanoshell of layered double hydroxide (2006) Chem. Commun., 29, pp. 3125-3127
  • Yan, D., Qin, S., Chen, L., Lu, J., Ma, J., Wei, M., Evans, D.G., Duan, X., Thin film of sulfonated zinc phthalocyanine/layered double hydroxide for achieving multiple quantum well structure and polarized luminescence (2010) Chem. Commun., 46 (45), pp. 8654-8656
  • Xu, J., Zhao, S., Han, Z., Wang, X., Song, Y.-F., Layer-by-Layer Assembly of Na9[EuW10O 36]·32H2O and Layered Double Hydroxides Leading to Ordered Ultra-Thin Films: Cooperative Effect and Orientation Effect (2011) Chem. - Eur. J., 17 (37), pp. 10365-10371
  • Yan, D., Lu, J., Ma, J., Wei, M., Evans, D.G., Duan, X., Reversibly Thermochromic, Fluorescent Ultrathin Films with a Supramolecular Architecture (2011) Angew. Chem., Int. Ed., 50 (3), pp. 720-723
  • Sasaki, T., Watanabe, M., Osmotic swelling to exfoliation. Exceptionally high degrees of hydration of a layered titanate (1998) J. Am. Chem. Soc., 120 (19), pp. 4682-4689
  • Kayano, M., Ogawa, M., Preparation of large platy particles of Co-Al layered double hydroxides (2006) Clays Clay Miner., 54 (3), pp. 382-389
  • Arai, Y., Ogawa, M., Preparation of Co-Al layered double hydroxides by the hydrothermal urea method for controlled particle size (2009) Appl. Clay Sci., 42 (34), pp. 601-604
  • Yao, K., Taniguchi, M., Nakata, M., Takahashi, M., Yamagishi, A., Electrochemical scanning tunneling microscopy observation of ordered surface layers on an anionic clay-modified electrode (1998) Langmuir, 14 (10), pp. 2890-2895
  • Liu, X.H., Ma, R.Z., Bando, Y., Sasaki, T., Layered Cobalt Hydroxide Nanocones: Microwave-Assisted Synthesis, Exfoliation, and Structural Modification (2010) Angew. Chem., Int. Ed., 49 (44), pp. 8253-8256
  • Cai, H., Hillier, A.C., Franklin, K.R., Nunn, C.C., Ward, M.D., Nanoscale Imaging of Molecular Adsorption (1994) Science, 266 (5190), pp. 1551-1555
  • Costantino, U., Marmottini, F., Nocchetti, M., Vivani, R., New synthetic routes to hydrotalcite-like compounds - Characterisation and properties of the obtained materials (1998) Eur. J. Inorg. Chem., (10), pp. 1439-1446
  • Ogawa, M., Kaiho, H., Homogeneous precipitation of uniform hydrotalcite particles (2002) Langmuir, 18 (11), pp. 4240-4242
  • Benito, P., Herrero, M., Barriga, C., Labajos, F.M., Rives, V., Microwave-assisted homogeneous precipitation of hydrotalcites by urea hydrolysis (2008) Inorg. Chem., 47 (12), pp. 5453-5463
  • Jobbagy, M., Blesa, M.A., Regazzoni, A.E., Homogeneous precipitation of layered Ni(II)-Cr(III) double hydroxides (2007) J. Colloid Interface Sci., 309 (1), pp. 72-77
  • Oh, J.M., Hwang, S.H., Choy, J.H., The effect of synthetic conditions on tailoring the size of hydrotalcite particles (2002) Solid State Ionics, 151 (14), pp. 016727380200725-7
  • Iyi, N., Sasaki, T., Decarbonation of MgAl-LDHs (layered double hydroxides) using acetate-buffer/NaCl mixed solution (2008) J. Colloid Interface Sci., 322 (1), pp. 237-245
  • Iyi, N., Matsumoto, T., Kaneko, Y., Kitamura, K., Deintercalation of carbonate ions from a hydrotalcite-like compound: Enhanced decarbonation using acid-salt mixed solution (2004) Chem. Mater., 16 (15), pp. 2926-2932
  • Iyi, N., Yamada, H., Sasaki, T., Deintercalation of carbonate ions from carbonate-type layered double hydroxides (LDHs) using acid-alcohol mixed solutions (2011) Appl. Clay Sci., 54 (2), pp. 132-137
  • Iyi, N., Yamada, H., Efficient decarbonation of carbonate-type layered double hydroxide (CO32-LDH) by ammonium salts in alcohol medium (2011) Appl. Clay Sci., 6566, pp. 121-127
  • Antonyraj, C.A., Koilraj, P., Kannan, S., Synthesis of delaminated LDH: A facile two step approach (2010) Chem. Commun., 46 (11), pp. 1902-1904
  • Iyi, N., Matsumoto, T., Kaneko, Y., Kitamura, K., A novel synthetic route to layered double hydroxides using hexamethylenetetramine (2004) Chem. Lett., 33 (9), pp. 1122-1123
  • Brönsted, J.N., Kilpatrick, M., Kilpatrick, M., Kinetic studies on ethylene oxides (1929) J. Am. Chem. Soc., 51, pp. 428-461
  • Parker, R.E., Isaacs, N.S., Mechanisms of Epoxide Reactions (1959) Chem. Rev., 59 (4), pp. 737-799
  • Cui, H.T., Zayat, M., Levy, D., Controlled homogeneity of the precursor gel in the synthesis of SrTiO3 nanoparticles by an epoxide assisted sol-gel route (2007) J. Non-Cryst. Solids, 353 (1112), pp. 1011-1016
  • Cui, H.T., Zayat, M., Levy, D., A chemical strategy to control the shape of oxide nanoparticles (2009) J. Nanopart. Res., 11 (6), pp. 1331-1338
  • Gash, A.E., Tillotson, T.M., Satcher, J.H., Poco, J.F., Hrubesh, L.W., Simpson, R.L., Use of epoxides in the sol-gel synthesis of porous iron(III) oxide monoliths from Fe(III) salts (2001) Chem. Mater., 13 (3), pp. 999-1007
  • Gash, A.E., Tillotson, T.M., Satcher, J.H., Hrubesh, L.W., Simpson, R.L., New sol-gel synthetic route to transition and main-group metal oxide aerogels using inorganic salt precursors (2001) J. Non-Cryst. Solids, 285 (13), pp. 22-28
  • Gash, A.E., Satcher, J.H., Simpson, R.L., Monolithic nickel(II)-based aerogels using an organic epoxide: The importance of the counterion (2004) J. Non-Cryst. Solids, 350, pp. 145-151
  • Gash, A.E., Satcher, J.H., Simpson, R.L., Strong akaganeite aerogel monoliths using epoxides: Synthesis and characterization (2003) Chem. Mater., 15 (17), pp. 3268-3275
  • Zhang, H.D., Li, B., Zheng, Q.X., Jiang, M.H., Tao, X.T., Synthesis and characterization of monolithic Gd2O3 aerogels (2008) J. Non-Cryst. Solids, 354 (34), pp. 4089-4093
  • Ehrenberg, L., Hussain, S., Genetic Toxicity of Some Important Epoxides (1981) Mutat. Res., 86 (1), pp. 1-113
  • Bi, S.P., Wang, C.Y., Cao, Q., Zhang, C.H., Studies on the mechanism of hydrolysis and polymerization of aluminum salts in aqueous solution: Correlations between the ″core-links″ model and ″cage-like″ Keggin-Al-13 model (2004) Coord. Chem. Rev., 248 (56), pp. 441-455
  • Vermeulen, A.C., Geus, J.W., Stol, R.J., Debruyn, P.L., Hydrolysis-Precipitation Studies of Aluminum (III) Solutions 0.1. Titration of Acidified Aluminum Nitrate Solutions (1975) J. Colloid Interface Sci., 51 (3), pp. 449-458
  • Stol, R.J., Vanhelden, A.K., Debruyn, P.L., Hydrolysis-Precipitation Studies of Aluminum (3) Solutions 0.2. Kinetic Study and Model (1976) J. Colloid Interface Sci., 57 (1), pp. 115-131
  • Boclair, J.W., Braterman, P.S., Layered double hydroxide stability. 1. Relative stabilities of layered double hydroxides and their simple counterparts (1999) Chem. Mater., 11 (2), pp. 298-302
  • Parks, G.A., The isoelectric points of solid oxides, solid hydroxides, and aqueous hydroxo complex systems (1965) Chem. Rev., 65 (2), pp. 177-198
  • Jobbagy, M., Regazzoni, A.E., Dissolution of nano-size Mg-Al-Cl hydrotalcite in aqueous media (2011) Appl. Clay Sci., 51 (3), pp. 366-369
  • Iyi, N., Fujii, K., Okamoto, K., Sasaki, T., Factors influencing the hydration of layered double hydroxides (LDHs) and the appearance of an intermediate second staging phase (2007) Appl. Clay Sci., 35 (34), pp. 218-227
  • Hibino, T., Ohya, H., Synthesis of crystalline layered double hydroxides: Precipitation by using urea hydrolysis and subsequent hydrothermal reactions in aqueous solutions (2009) Appl. Clay Sci., 45 (3), pp. 123-132
  • Scheidegger, A.M., Lamble, G.M., Sparks, D.L., Spectroscopic evidence for the formation of mixed-cation hydroxide phases upon metal sorption on clays and aluminum oxides (1997) J. Colloid Interface Sci., 186 (1), pp. 118-128
  • D'Espinose De La Caillerie, J.B., Kermarec, M., Clause, O., Impregnation of gamma-alumina with Ni(II) or Co(II) ions at neutral pH: Hydrotalcite-type coprecipitate formation and characterization (1995) J. Am. Chem. Soc., 117 (46), pp. 11471-11481
  • D'Espinose De La Caillerie, J.B., Clause, O., Promotion of gamma-alumina dissolution by metal ions during impregnation. Thermal stability of the formed coprecipitates (1996) Stud. Surf. Sci. Catal., 101, pp. 1321-1330
  • Hiemstra, T., Yong, H., Van Riemsdijk, W.H., Interfacial charging phenomena of aluminum (hydr)oxides (1999) Langmuir, 15 (18), pp. 5942-5955
  • Kosmulski, M., PH-dependent surface charging and points of zero charge III. Update (2006) J. Colloid Interface Sci., 298 (2), pp. 730-741
  • Kosmulski, M., Plak, A., Surface charge of anatase and alumina in mixed solvents (1999) Colloids Surf., A: Physicochem. Eng. Aspects, 149 (13), pp. 409-412
  • Yang, Y., Zhao, X., Zhu, Y., Zhang, F., Transformation mechanism of magnesium and aluminum precursor solution into crystallites of layered double hydroxide (2012) Chem. Mater., 24 (1), pp. 81-87
  • Okamoto, K., Iyi, N., Sasaki, T., Factors affecting the crystal size of the MgAl-LDH (layered double hydroxide) prepared by using ammonia-releasing reagents (2007) Appl. Clay Sci., 37 (12), pp. 23-31
  • Lang, K., Kubat, P., Mosinger, J., Bujdak, J., Hof, M., Janda, P., Sykora, J., Iyi, N., Photoactive oriented films of layered double hydroxides (2008) Phys. Chem. Chem. Phys., 10 (30), pp. 4429-4434
  • Yan, D.P., Lu, J., Wei, M., Evans, D.G., Duan, X., Sulforhodamine B Intercalated Layered Double Hydroxide Thin Film with Polarized Photoluminescence (2009) J. Phys. Chem. B, 113 (5), pp. 1381-1388

Citas:

---------- APA ----------
Oestreicher, V. & Jobbágy, M. (2013) . One pot synthesis of Mg2Al(OH)6Cl·1.5H 2O layered double hydroxides: The epoxide route. Langmuir, 29(39), 12104-12109.
http://dx.doi.org/10.1021/la402260m
---------- CHICAGO ----------
Oestreicher, V., Jobbágy, M. "One pot synthesis of Mg2Al(OH)6Cl·1.5H 2O layered double hydroxides: The epoxide route" . Langmuir 29, no. 39 (2013) : 12104-12109.
http://dx.doi.org/10.1021/la402260m
---------- MLA ----------
Oestreicher, V., Jobbágy, M. "One pot synthesis of Mg2Al(OH)6Cl·1.5H 2O layered double hydroxides: The epoxide route" . Langmuir, vol. 29, no. 39, 2013, pp. 12104-12109.
http://dx.doi.org/10.1021/la402260m
---------- VANCOUVER ----------
Oestreicher, V., Jobbágy, M. One pot synthesis of Mg2Al(OH)6Cl·1.5H 2O layered double hydroxides: The epoxide route. Langmuir. 2013;29(39):12104-12109.
http://dx.doi.org/10.1021/la402260m