Abstract:
A robust and straightforward strategy allowing the controlled confinement of metal nanoparticles within the 3D framework of mesoporous films is presented. The chemical methodology is based on the inner surface modification of mesoporous silica films with polyelectrolyte brushes. We demonstrate that the macromolecular building blocks significantly enhance the site-selective preconcentration of nanoparticle precursors in the inner environment of the mesoporous film. Then, chemical reduction of the preconcentrated precursors led to the formation of metal nanoparticles locally addressed in the mesoporous structure. We show that the synergy taking place between two versatile functional nanobuilding blocks (ordered mesocavities and polymer brushes) can produce stable embedded nanoparticles with tuned optical properties in a very simple manner. As a general framework, the strategy can be easily adapted to different sets of polymer brushes and mesoporous films in order to regulate the monomer?precursor interactions and, consequently, manipulate the site-selective character of the different chemistries taking place in the film. We consider that the "integrative chemistry" approach described in this work provides new pathways to manipulate the physicochemical characteristics of hybrid organic?inorganic advanced functional assemblies based on the rational design of chemistry and topology in confined environments. © 2010 American Chemical Society.
Registro:
Documento: |
Artículo
|
Título: | Nanochemistry in confined environments: Polyelectrolyte brush-assisted synthesis of gold nanoparticles inside ordered mesoporous thin films |
Autor: | Calvo, A.; Fuertes, M.C.; Yameen, B.; Williams, F.J.; Azzaroni, O.; Soler-Illia, G.J.A.A. |
Filiación: | Gerencia de Química, Comisión Nacional de Energía Atómica (CNEA), Argentina Max-Planck-Institut für Polymerforschung, Mainz, Germany INQUIMAE, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Argentina Depto de Química Inorgánica, Analítica y Química Física, Universidad de Buenos Aires, Argentina Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas (INIFTA), Depto. de Química, Universidad Nacional de la Plata, Argentina
|
Palabras clave: | Chemical reduction; Confined environment; Embedded nanoparticles; Gold Nanoparticles; Inner surfaces; Macromolecular building blocks; Mesoporous films; Mesoporous silica film; Mesoporous structures; Metal nanoparticles; Nano chemistry; Nanobuilding blocks; Nanoparticle precursors; Ordered mesoporous; Physicochemical characteristics; Polyelectrolyte brushes; Polymer brushes; Pre-concentration; Rational design; Site selective; Straightforward strategy; Brushes; Chemical modification; Design; Excitons; Functional polymers; Nanoparticles; Optical properties; Polyelectrolytes; Silica; Polymer films |
Año: | 2010
|
Volumen: | 26
|
Número: | 8
|
Página de inicio: | 5559
|
Página de fin: | 5567
|
DOI: |
http://dx.doi.org/10.1021/la9038304 |
Título revista: | Langmuir
|
Título revista abreviado: | Langmuir
|
ISSN: | 07437463
|
CODEN: | LANGD
|
Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07437463_v26_n8_p5559_Calvo |
Referencias:
- Geckeler, K.E., Rosenberg, E., (2006) Functional Nanomaterials, , Eds.; American Scientific Publishers: Stevenson Ranch, CA
- Vollath, D., (2008) Nanomaterials: An Introduction to Synthesis, Properties and Applications, , VCH-Wiley: Wienheim
- Ozin, G.A., (1992) Adv. Mater., 4, p. 612
- Ozin, G.A., Arsenault, A.C., Cademartiri, L., Ozin, G.A., Cademartiri, L., (2009) Nanochemistry: A Chemical Approach to Nanomaterials, 5, p. 1240. , Royal Society of Chemistry: London, Small 2009
- Bréchignac, C., Houdy, P., Lahmani, M., (2007) Nanomaterials and Nanochemistry, , Eds.; Springer-Verlag: Heidelberg
- Descalzo, A.B., Martínez-Máñez, R., Sancenón, F., Hoffmann, K., Rurack, K., (2006) Angew. Chem., Int. Ed., 45, p. 5924
- Turco Liveri, V., (2006) Controlled Synthesis of Nanoparticles in Microheterogeneous Systems, pp. 75-90. , Chapter 2
- Diana, F.S., Lee, S.-H., Petroff, P.M., Kramer, E., (2003) J. Nano Lett., 3, p. 891
- Niu, Y.H., Yeung, L.K., Crooks, R.M., (2001) J. Am. Chem. Soc., 123, p. 6840
- Douglas, T., Dickson, D.P.E., Betteridge, S., Charnock, J., Garner, C.D., Mann, S., (1995) Science, 269, p. 54
- Lopes, W.A., Jaeger, H.M., (2001) Nature, 414, pp. 735-738
- Yameen, B., Ali, M., Neumann, R., Ensinger, W., Knoll, W., Azzaroni, O., (2009) J. Am. Chem. Soc., 131, p. 2070
- Yameen, B., Ali, M., Neumann, R., Ensinger, W., Knoll, W., (2009), 9, p. 2788; Chernysheva, M.V., Sapoletova, N.A., Eliseev, A.A., Lukashin, A.V., Tretyakov, Y.D., Goernert, P., (2006) Pure Appl. Chem., 78, p. 1749
- Liu, J., Wei, A., (2009) Chem. Commun., p. 4254
- Tang, X.-P., Mogilevsky, G., Kulkarni, H., Wu, Y., (2007) J. Phys. Chem. C, 111, p. 18615
- Okada, T., Harada, M., Ohki, T., (2009) Anal. Sci., 25, p. 167
- Corriu, R.J.P., (2005) J. Mater. Chem., 15, p. 4285
- Zhao, X.-G., Shi, J.-L., Hu, B., Zhang, L.-X., Hua, Z.-L., (2003) J. Mater. Chem., 13, p. 399
- Goettmann, F., Sanchez, C., (2007) J. Mater. Chem., 17, p. 24
- Schoonheydt, R.A., Weckhuysen, B.M., (2009) Phys. Chem. Chem. Phys., 11, p. 2794
- Wu, Y., Cheng, G., Katsov, K., Sides, S.W., Wang, J., Tang, J., Frederickson, G.H., Stucky, G.D., (2004) Nat. Mater., 3, p. 816
- Huck, W.T.S., (2005) Chem. Commun., p. 4143
- Aprile, C., Abad, A., García, H., Corma, A., (2005) J. Mater. Chem., 15, p. 4408
- Gu, J.L., Shi, J.L., You, G.J., Xiong, L.M., Qiang, S.X., Hua, Z.L., Chen, H.R., (2005) Adv. Mater., 17, p. 557
- Stein, A., Melde, B.J., Schroden, R.C., (2000) Adv. Mater., 12, p. 1403
- Cortial, G., (2006) Small, 2, p. 1042
- Henao, J.D., Suh, Y.-W., Lee, J.-K., Kung, M.C., Kung, H.H., (2008) J. Am. Chem. Soc., 130, p. 16142
- Chau, J.L.H., ; Tang, Z., Sheng, P., (2003), pp. 228-234. , Eds.; Taylor & Francis: London Chapter 27; Beckstein, O., Biggin, P.C., Sansom, M.S.P., (2001) J. Phys. Chem. B, 105, p. 12902
- Sanchez, C., Boissière, C., Grosso, D., Laberty, C., Nicole, L., (2008) Chem. Mater., 20, p. 682
- (2008) Chem. Mater., 20 (3). , See, for example, the special issue dedicated to templated materials
- Soler-Illia, G.J.A.A., Sanchez, C., Lebeau, B., Patarin, J., (2002) J. Chem. Rev., 102, p. 4093. , See also
- Soler-Illia, G.J.A.A., Innocenzi, P., (2006) Chem.-Eur. J., 12, p. 4478
- Soler-Illia, G.J.A.A., Crepaldi, E.L., Grosso, D., Sanchez, C., (2003) Curr. Opin. Colloid Interface Sci., 8, p. 109
- Ciferri, A., Hamley, I.W., (2005) Supramolecular Polymers, , Ed.; CRC Press: Boca Raton, FL,. In Introduction to Soft Matter: Synthetic and Biological Self-Assembling Materials; John Wiley & Sons: West Sussex, 2007
- Gómez-Romero, P., Sanchez, C., Kickelbick, G., (2004) Functional Hybrid Materials, pp. 1-14. , VCH-Wiley: Weinheim,; Chapter 1, Hybrid Materials: Synthesis, Characterization and Applications;, Ed.; Wiley-VCH: Weinheim, 2007
- Yoo, S., Lunn, J.D., González, S., Ristich, J.A., Simanek, E.E., Shantz, D.F., (2006) Chem. Mater., 18, p. 2935
- Reynhardt, J.P.K., Yang, Y., Sayari, A., Alper, H., (2006) Adv. Funct. Mater., 15, p. 1641
- Tian, B.-S., Yang, C., (2009) J. Phys. Chem. C, 113, p. 4925
- Rzayev, J., Hillmyer, M.A., (2005) J. Am. Chem. Soc., 127, p. 13373
- Rosenholm, J.M., (2008) Chem. Mater., 20, p. 1126
- Rosenholm, J.M., (2006) Chem. Commun., p. 3909
- Save, M., Granvorka, G., Bernard, J., Charleux, B., Boissiére, C., Grosso, D., Sanchez, C., (2006) Macromol. Rapid Commun., 27, p. 393
- Ford, D.M., Simanek, E.E., Shantz, D.F., (2000) Nanotechnology, 16, pp. S458
- Choi, M., Kleitz, F., Liu, D., Lee, H.Y., Ahn, W.-S., Ryoo, R., (2005) J. Am. Chem. Soc., 127, p. 1924
- Kruk, M., Dufour, B., Celer, E.B., Kowalewski, T., Jaroniec, M., Matyjaszewski, K., (2008) Macromolecules, 41, p. 8584
- Kruk, M., Dufour, B., Celer, E.B., Kowalewski, T., Jaroniec, M., Matyjaszewski, K., (2005) J. Phys. Chem. B, 109, p. 9216
- Moreno, J., Sherrington, D.C., (2008) Chem. Mater., 20, p. 4468
- (2006) Responsive Polymer Materials: Design and Applications, , Minko, S., Ed.; Blackwell Publishing: Ames
- Azzaroni, O., Trappmann, B., Van Rijn, P., Zhou, F., Kong, B., Huck, W.T.S., (2006) Angew. Chem., Int. Ed., 45, p. 7440
- Yameen, B., (2008) J. Am. Chem. Soc., 130, p. 13140
- Azzaroni, O., Zheng, Z., Yang, Z., Huck, W.T.S., (2006) Langmuir, 26, p. 6730
- Barbey, R., (2009) Chem. Rev., 109, p. 5437
- Ayres, N., (2010) Polym. Chem., , DOI: 10.1039/b9py00246d
- Calvo, A., Yameen, B., Williams, F.J., Azzaroni, O., Soler-Illia, G.J.A.A., (2009) Chem. Commun., 131, p. 2553
- Calvo, A., Yameen, B., Williams, F.J., Soler-Illia, G.J.A.A., Azzaroni, O., (2009) J. Am. Chem. Soc., 131, p. 10866
- Schepelina, O., Zharov, I., (2008) Langmuir, 24, p. 14188
- Fukuoka, A., Araki, H., Sakamoto, Y., Sugimoto, N., Tsukada, H., Kumai, Y., Akimoto, Y., Ichikawa, M., (2002) Nano Lett., 2, p. 793
- Mukherjee, P., Patra, C.R., Ghosh, A., Kumar, R., Sastry, M., (2002) Chem. Mater., 14, p. 1678
- Petkov, N., Stock, N., Bein, T., (2005) J. Phys. Chem. B, 109, p. 10737
- Fan, H., (2004) J. Science, 304, p. 567
- Kolsmulski, M., (2002) J. Colloid Interface Sci., 253, p. 77
- Calvo, A., Angelomé, P.C., Sánchez, V.M., Scherlis, D.A., Williams, F.J., Soler-Illia, G.J.A.A., (2008) Chem. Mater., 20, p. 4661
- Calvo, A., Joselevich, M., Soler-Illia, G.J.A.A., Williams, F.J., (2009) Microporous Mesoporous Mater., 121, p. 67
- Boissière, C., Grosso, D., Lepoutre, S., Nicole, L., Brunet-Bruneau, A., Sanchez, C., (2005) Langmuir, 21, p. 12362
- Advincula, R., Jordan, R., (2006) Surface-Initiated Polymerization i, p. 107. , Ed.; Springer-Verlag: Heidelberg
- Huang, W., Skanth, G., Baker, G.L., Bruening, M.L.M.L., (2001) Langmuir, 17, p. 1731
- Socrates, G., (2001) Infrared and Raman Characteristic Group Frequencies, , 3 rd ed.; John Wiley & Sons: Chichester
- Fuertes, M.C., Marchena, M., Marchi, M.C., Wolosiuk, A., Soler-Illia, G.J.A.A., (2009) Small, 5, p. 272
- Gibaud, A., Hazra, S., (2000) Curr. Sci., 78, p. 1467
- Van Der Lee, A., (2000) Solid State Sci., 2, p. 257
- Azzaroni, O., Brown, A.A., Cheng, N., Wei, A., Jonas, A.M., Huck, W.T.S., (2007) J. Mater. Chem., 17, p. 3433
- Walcarius, A., Kuhn, A., (2008) Trends Anal. Chem., 27, p. 593
- Fattakhova-Rohlfing, D., Wark, M., Rathouský, J., (2007) Chem. Mater., 19, p. 1640
- Etienne, M., Quach, A., Grosso, D., Nicole, L., Sanchez, C., Walcarius, A., (2007) Chem. Mater., 19, p. 844
- Rodríguez Presa, M.J., Gassa, L.M., Azzaroni, O., Gervasi, C.A., (2009) Anal. Chem., 81, p. 7936
- Odian, G., (2004) Principles of Polymerization, , John Wiley & Sons: Hoboken, NJ
- Pérez, M.D., Otal, E., Bilmes, S.A., Soler-Illia, G.J.A.A., Crepaldi, E.L., Grosso, D., Sanchez, C., (2004) Langmuir, 20, p. 29
- Myroshnychenko, V., Rodríguez-Fernández, J., Pastoriza-Santos, I., Funston, A.M., Novo, C., Mulvaney, P., Liz-Marzán, L.M., García De Abajo, F.J., (2008) Chem. Soc. Rev., 37, p. 1792
- Eustis, S., El-Sayed, M., (2006) Chem. Soc. Rev., 35, p. 209
- Angelomé, P.C., Fuertes, M.C., Soler-Illia, G.J.A.A., (2006) Adv. Mater., 18, p. 2397
- Fuertes, M.C., López-Alcaraz, F.J., Marchi, M.C., Troiani, H., Luca, V., Míguez, H., Soler-Illia, G.J.A.A., (2007) Adv. Funct. Mater., 17, p. 1247
- Martínez, E.D., Bellino, M.G., Soler-Illia, G.J.A.A., (2009) ACS Appl. Mater. Interface, 1, p. 746
- Prouzet, E., Ravaine, S., Sanchez, C., Backov, R., Dujardin, E., Mann, S., (2008) New J. Chem., 32, p. 1284
- Fowler, C.E., Khushalani, D., Lebeau, B., Mann, S., (2001) Adv. Mater., 13, pp. 649-652
- Bein, T., (1992) Supramolecular Architecture: Synthetic Control in Thin Films and Solids, pp. 1-7. , Bein, T., Ed.; American Chemical Society: Washington, DC Chapter 1
- Sanchez, C., Giraud Guille, M.M., Arribart, H., (2005) Nat. Mater., 4, p. 277
Citas:
---------- APA ----------
Calvo, A., Fuertes, M.C., Yameen, B., Williams, F.J., Azzaroni, O. & Soler-Illia, G.J.A.A.
(2010)
. Nanochemistry in confined environments: Polyelectrolyte brush-assisted synthesis of gold nanoparticles inside ordered mesoporous thin films. Langmuir, 26(8), 5559-5567.
http://dx.doi.org/10.1021/la9038304---------- CHICAGO ----------
Calvo, A., Fuertes, M.C., Yameen, B., Williams, F.J., Azzaroni, O., Soler-Illia, G.J.A.A.
"Nanochemistry in confined environments: Polyelectrolyte brush-assisted synthesis of gold nanoparticles inside ordered mesoporous thin films"
. Langmuir 26, no. 8
(2010) : 5559-5567.
http://dx.doi.org/10.1021/la9038304---------- MLA ----------
Calvo, A., Fuertes, M.C., Yameen, B., Williams, F.J., Azzaroni, O., Soler-Illia, G.J.A.A.
"Nanochemistry in confined environments: Polyelectrolyte brush-assisted synthesis of gold nanoparticles inside ordered mesoporous thin films"
. Langmuir, vol. 26, no. 8, 2010, pp. 5559-5567.
http://dx.doi.org/10.1021/la9038304---------- VANCOUVER ----------
Calvo, A., Fuertes, M.C., Yameen, B., Williams, F.J., Azzaroni, O., Soler-Illia, G.J.A.A. Nanochemistry in confined environments: Polyelectrolyte brush-assisted synthesis of gold nanoparticles inside ordered mesoporous thin films. Langmuir. 2010;26(8):5559-5567.
http://dx.doi.org/10.1021/la9038304