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Abstract:

A robust and straightforward strategy allowing the controlled confinement of metal nanoparticles within the 3D framework of mesoporous films is presented. The chemical methodology is based on the inner surface modification of mesoporous silica films with polyelectrolyte brushes. We demonstrate that the macromolecular building blocks significantly enhance the site-selective preconcentration of nanoparticle precursors in the inner environment of the mesoporous film. Then, chemical reduction of the preconcentrated precursors led to the formation of metal nanoparticles locally addressed in the mesoporous structure. We show that the synergy taking place between two versatile functional nanobuilding blocks (ordered mesocavities and polymer brushes) can produce stable embedded nanoparticles with tuned optical properties in a very simple manner. As a general framework, the strategy can be easily adapted to different sets of polymer brushes and mesoporous films in order to regulate the monomer?precursor interactions and, consequently, manipulate the site-selective character of the different chemistries taking place in the film. We consider that the "integrative chemistry" approach described in this work provides new pathways to manipulate the physicochemical characteristics of hybrid organic?inorganic advanced functional assemblies based on the rational design of chemistry and topology in confined environments. © 2010 American Chemical Society.

Registro:

Documento: Artículo
Título:Nanochemistry in confined environments: Polyelectrolyte brush-assisted synthesis of gold nanoparticles inside ordered mesoporous thin films
Autor:Calvo, A.; Fuertes, M.C.; Yameen, B.; Williams, F.J.; Azzaroni, O.; Soler-Illia, G.J.A.A.
Filiación:Gerencia de Química, Comisión Nacional de Energía Atómica (CNEA), Argentina
Max-Planck-Institut für Polymerforschung, Mainz, Germany
INQUIMAE, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Argentina
Depto de Química Inorgánica, Analítica y Química Física, Universidad de Buenos Aires, Argentina
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas (INIFTA), Depto. de Química, Universidad Nacional de la Plata, Argentina
Palabras clave:Chemical reduction; Confined environment; Embedded nanoparticles; Gold Nanoparticles; Inner surfaces; Macromolecular building blocks; Mesoporous films; Mesoporous silica film; Mesoporous structures; Metal nanoparticles; Nano chemistry; Nanobuilding blocks; Nanoparticle precursors; Ordered mesoporous; Physicochemical characteristics; Polyelectrolyte brushes; Polymer brushes; Pre-concentration; Rational design; Site selective; Straightforward strategy; Brushes; Chemical modification; Design; Excitons; Functional polymers; Nanoparticles; Optical properties; Polyelectrolytes; Silica; Polymer films
Año:2010
Volumen:26
Número:8
Página de inicio:5559
Página de fin:5567
DOI: http://dx.doi.org/10.1021/la9038304
Título revista:Langmuir
Título revista abreviado:Langmuir
ISSN:07437463
CODEN:LANGD
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07437463_v26_n8_p5559_Calvo

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Citas:

---------- APA ----------
Calvo, A., Fuertes, M.C., Yameen, B., Williams, F.J., Azzaroni, O. & Soler-Illia, G.J.A.A. (2010) . Nanochemistry in confined environments: Polyelectrolyte brush-assisted synthesis of gold nanoparticles inside ordered mesoporous thin films. Langmuir, 26(8), 5559-5567.
http://dx.doi.org/10.1021/la9038304
---------- CHICAGO ----------
Calvo, A., Fuertes, M.C., Yameen, B., Williams, F.J., Azzaroni, O., Soler-Illia, G.J.A.A. "Nanochemistry in confined environments: Polyelectrolyte brush-assisted synthesis of gold nanoparticles inside ordered mesoporous thin films" . Langmuir 26, no. 8 (2010) : 5559-5567.
http://dx.doi.org/10.1021/la9038304
---------- MLA ----------
Calvo, A., Fuertes, M.C., Yameen, B., Williams, F.J., Azzaroni, O., Soler-Illia, G.J.A.A. "Nanochemistry in confined environments: Polyelectrolyte brush-assisted synthesis of gold nanoparticles inside ordered mesoporous thin films" . Langmuir, vol. 26, no. 8, 2010, pp. 5559-5567.
http://dx.doi.org/10.1021/la9038304
---------- VANCOUVER ----------
Calvo, A., Fuertes, M.C., Yameen, B., Williams, F.J., Azzaroni, O., Soler-Illia, G.J.A.A. Nanochemistry in confined environments: Polyelectrolyte brush-assisted synthesis of gold nanoparticles inside ordered mesoporous thin films. Langmuir. 2010;26(8):5559-5567.
http://dx.doi.org/10.1021/la9038304