Navegar

Colección

Datos Estadísticas

Artículo

La versión final de este artículo es de uso interno. El editor solo permite incluir en el repositorio el artículo en su versión post-print. Por favor, si usted la posee enviela a
Consulte el artículo en la página del editor
Consulte la política de Acceso Abierto del editor

Abstract:

The interfacial properties of a new family of nonionic surfactants derived from alkyl glucosides were studied. The physicochemical parameters of these dimeric compounds were compared with those of their monomeric counterparts. The effect of the position of the linkage, the anomeric configuration, the spacer functionality, and the spacer type (rigid or flexible) on the behavior of these surfactants was analyzed for a short-chain (butyl) series of compounds. Slight structural variations have a significant influence on their properties. The maximum length of the hydrophobic chains for obtaining gemini surfactants with improved efficiencies compared to those of the starting monomeric alkyl glucosides was estimated.

Registro:

Documento: Artículo
Título:New family of nonionic gemini surfactants. Determination and analysis of interfacial properties
Autor:Castro, M.J.L.; Kovensky, J.; Fernández Cirelli, A.
Filiación:Centro de Investigaciones en Hidratos de Carbono (CIHIDECAR, CONICET), Departamento de Quimica Organica, Facultad de Ciencias Exactas y Naturales, Pabellón II, Piso 3, 1428 Buenos Aires, Ciudad Universitaria, Argentina
Palabras clave:Nonionic gemini surfactants; Dimers; Hydrogen bonds; Hydrophobicity; Micelles; Monomers; Surface active agents
Año:2002
Volumen:18
Número:7
Página de inicio:2477
Página de fin:2482
DOI: http://dx.doi.org/10.1021/la001549e
Título revista:Langmuir
Título revista abreviado:Langmuir
ISSN:07437463
CODEN:LANGD
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07437463_v18_n7_p2477_Castro

Referencias:

  • Von Rybinski, W., Hill, K., (1998) Angew. Chem., Int. Ed. Engl., 37, p. 1328
  • Zana, R., (1998) Novel Surfactants Preparation, Applications, and Biodegradability, 74, p. 241. , Surfactant Science Series; Holmberg, K., Ed.; Marcel Dekker: New York
  • Eastoe, J., Rogueda, P., (1994) Langmuir, 10, p. 4429
  • Eastoe, J., Rogueda, P., (1996) Langmuir, 12, p. 2701
  • Pestman, J.M., Terpstra, K.R., Stuart, M.C.A., Van Doren, H.A., Brisson, A., Kellogg, R.M., Engberts, J.B.F.N., (1997) Langmuir, 13, p. 6857
  • Duivenvoorde, F.L., Martinus, C.F., Van der Gaast, S.J., Engberts, J.B.F.N., (1996) Langmuir, 13, p. 3737
  • Menger, F.M., Keiper, J.S., Azov, V., (2000) Langmuir, 16, p. 2062
  • Menger, F.M., Mbadugha, M.N.A., (2001) J. Am. Chem. Soc., 123, p. 875
  • McGregor, C., Perrin, C., Monck, M., Camilleri, P., Kirby, A.J., (2001) J. Am. Chem. Soc., 123, p. 6215
  • Castro, M.J.L., Kovensky, J., Fernández Cirelli, A., (1997) Tetrahedron Lett., 38, p. 3995
  • Castro, M.J.L., Kovensky, J., Fernández Cirelli, A., (1999) Tetrahedron, 55, p. 12711
  • Castro, M.J.L., Kovensky, J., Fernández Cirelli, A., (2000) J. Carbohydr. Chem., 29, p. 1174
  • Pérez, L., Torres, J.L., Manresa, A., Soians, C., Infante, M.R., (1996) Langmuir, 12, p. 5296
  • Jackson, S.W., Nicholson, S.H., Ross, D., (2000) Proceedings of the 5th World Surfactants Congress, p. 1073. , CESIO: Brussles, Belgium
  • Uppgård, L., Sjöström, M., Wold, S., (2000) Tenside Surf. Det., 37, p. 131
  • (1998) CS Chem 3D Pro and MOPAC Pro, , Cambridge Soft: Cambridge, MA
  • Kunitake, T., Okahata, Y., Shimomura, M., Yasunami, S., Takarabe, K., (1981) J. Am. Chem. Soc., 103, p. 5401
  • Schick, M.J., (1962) J. Colloid Sci., 17, p. 801
  • Rosen, M.J., (1993) CHEMTECH, pp. 30-33
  • Li, F., Rosen, M.J., Sulthana, S.B., (2001) Langmuir, 17, p. 1037
  • Sharma, L., Singh, S., (1995) Carbohydr. Res., 270, p. 43
  • Brown, G.M., Dubreuil, P., Ichhaporia, F.M., Desnoyers, J.E., (1970) Can. J. Chem., 48, p. 2525
  • Shinoda, K., Yamaguchi, T., Hori, R., (1961) Bull. Soc. Chem. Jpn., 34, p. 237
  • Böcker, T., Lindhorst, T., Thiem, J., Vill, V., (1992) Carbohydr. Res., 230, p. 245
  • (1989) ASTM Method D2667-89, , American Society for Testing and Materials, West Conshohocken, PA
  • Castro, M.J.L., Kovensky, J., Fernández Cirelli, A., Argentina National Patent Application AR990196476, in progress; Piasecki, A., Burczyk, B., Ruehala, P., (1998) J. Surfactants Deterg., 1, p. 29
  • Mukerjee, P., (1967) Adv. Colloid Interface Sci., p. 241
  • Menger, F.M., Littau, C.A., (1991) J. Am. Chem. Soc., 113, p. 1451
  • Menger, F.M., Littau, C.A., (1993) J. Am. Chem. Soc., 115, p. 10083
  • Void, M.J., (1990) J. Colloid Interface Sci., 135, p. 520
  • Shinoda, K., Yamanaka, T., Kiuoshita, K., (1959) J. Phys. Chem., 63, p. 648
  • Focher, B., Savelli, G., Torri, G., (1990) Chem. Phys. Lipids, 53, p. 141
  • Adasch, S., Hoffmann, B., Milius, W., Platz, G., Voss, G., (1998) Carbohydr. Res., 314, p. 177
  • Becher, P., (1965) Emulsions, Theory and Practice, , Litton Educational Publishing: New York
  • Fainerman, V.B., Miller, R., (1998) The Maximum Bubble Pressure Tensiometry. Drops and Bubbles in Interfacial Research, p. 279. , Möbius, D., Miller, R., Eds.; Elsevier Science: New York
  • Castro, M.J.L., Kovensky, J., Fernández Cirelli, A., (2001) J. Chem. Educ., 78, p. 347
  • Lide, D.R., (1997) CRC Handbook of Chemistry and Physics, pp. 6-135. , CRC Press: Boca Raton, FL
  • Rosen, M.J., (1989) Surfactants and Interracial Phenomena, , John Wiley: New York

Citas:

---------- APA ----------
Castro, M.J.L., Kovensky, J. & Fernández Cirelli, A. (2002) . New family of nonionic gemini surfactants. Determination and analysis of interfacial properties. Langmuir, 18(7), 2477-2482.
http://dx.doi.org/10.1021/la001549e
---------- CHICAGO ----------
Castro, M.J.L., Kovensky, J., Fernández Cirelli, A. "New family of nonionic gemini surfactants. Determination and analysis of interfacial properties" . Langmuir 18, no. 7 (2002) : 2477-2482.
http://dx.doi.org/10.1021/la001549e
---------- MLA ----------
Castro, M.J.L., Kovensky, J., Fernández Cirelli, A. "New family of nonionic gemini surfactants. Determination and analysis of interfacial properties" . Langmuir, vol. 18, no. 7, 2002, pp. 2477-2482.
http://dx.doi.org/10.1021/la001549e
---------- VANCOUVER ----------
Castro, M.J.L., Kovensky, J., Fernández Cirelli, A. New family of nonionic gemini surfactants. Determination and analysis of interfacial properties. Langmuir. 2002;18(7):2477-2482.
http://dx.doi.org/10.1021/la001549e