Abstract:
Nutrient loss during drying of a shrinking product was determined. A diffusion model that takes into account the shrinkage of the product in the mass balance equation was used, together with a simplified energy balance with no thermal gradients, and convective boundary conditions for both balances. Nutrient loss prediction was obtained, for first and second order kinetics. Finally, a new methodology was proposed, to determine the activation energy and the preexponential of the deterioration reaction, even when the differential equations that rules the drying process are unknown, and only the thermal history of the product is available. This approach is also valid for sterilization calculations, if temperature gradients can be neglected, i.e. when Biot number for heat transfer is small. Nutrient loss during drying of a shrinking product was determined. A diffusion model that takes into account the shrinkage of the product in the mass balance equation was used, together with a simplified energy balance with no thermal gradients, and convective boundary conditions for both balances. Nutrient loss prediction was obtained, for first and second order kinetics. Finally, a new methodology was proposed, to determine the activation energy and the preexponential of the deterioration reaction, even when the differential equations that rules the drying process are unknown, and only the thermal history of the product is available. This approach is also valid for sterilization calculations, if temperature gradients can be neglected, i.e. when Biot number for heat transfer is small.
Registro:
Documento: |
Artículo
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Título: | Prediction of degrading reactions during drying of solid foodstuffs |
Autor: | Rovedo, C.O.; Viollaz, P.E. |
Ciudad: | New York |
Filiación: | Departamento de Industrias, Facultaä de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina Biological and Agricultural Engineering, University of California, Davis, CA, United States
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Palabras clave: | Activation energy; Boundary conditions; Degradation; Deterioration; Food products; Mathematical models; Reaction kinetics; Shrinkage; Biot number; Convective boundary condition; Diffusion model; Energy balance; Foodstuff; Mass balance equation; Nutrient loss; Drying; Degradation; Drying; foodstuff; nutrient; reaction |
Año: | 1998
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Volumen: | 16
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Número: | 3-5
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Página de inicio: | 561
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Página de fin: | 578
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DOI: |
http://dx.doi.org/10.1080/07373939808917424 |
Título revista: | Drying Technology
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Título revista abreviado: | Dry. Technol.
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ISSN: | 07373937
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CODEN: | DRTED
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07373937_v16_n3-5_p561_Rovedo |
Referencias:
- Aguerre, R.J., Suarez, C., Viollaz, P.E., Enthalpy-Entropy compensation in sorption phenomena: Application to the prediction of the effect of temperature on food isotherms (1986) J. Food Science, 51 (6), pp. 1547-1549
- Ashie, I.N.A., Simpson, B.K., Smith, J.P., Mechanisms for Controlling Enzymatic Reactions in Foods (1996) Critical Reviews in Food Science and Nutrition, 36 (1-2), pp. 1-30
- Banga, J.R., Singh, R.P., Optimization of Drying of Foods (1994) J. of Food Engineering, 23, pp. 189-211
- Palacios Viteri, N., Effect of temperature ori the aerobic degradation of vitamin C in citric fruit juices (1989) Archives Latinoamericanos De Nutriciön, 39 (4), p. 601612
- Karel, M., Nickerson, J.T.R., Effects of relative humidity, air and vacuum on browning of dehydrated orange juice (1964) Food Technology, 18, pp. 104-108
- Kincal, N.S., Giray, C., Kinetics of ascorbic acid degradation in potato blanching (1987) Int. J. of Food Science and Technology, 22 (3), pp. 249-254
- Lee, S.H., Labuza, T.P., Destruction of ascorbic acid as a function of water activity (1975) J. Food Science, 40, pp. 370-373
- Mishkin, M., Saguy, I., Karel, M., Minimizing ascorbic acid loss during air drying with a constraint on enzyme inactivation for a hypothetical foodstuff (1983) J. of Food Processing and Preservation, 7 (3), pp. 103-210
- Mohr, K.H., Quality-retaining drying by computer simulation (1987) Lebensmittelindustrie, 34 (4), pp. 151-152
- Nelson, K.A., (1994) Reaction Kinetics of Food Stability: Comparison of Glass Transition and Classical Models for Temperature and Moisture Dependence., , PhD Thesis, University of Minnesota, Minneapolis, MN. 55455, USA
- Prausnitz, J.M., Eckert, C.A., Orye, R.V., O'Connell, J.P., Computer calculations for multicomponent vapor-liquid equilibria (1967) Prentice Hall Int Series in the Physical and Chemical Eng. Sei. Englewood Cliffts, N.J., pp. p219
- Ramaswamy, H., Ghazala, S., Degradation kinetics of thiamin in aqueous systems at high temperatures (1990) Canadian Institute of Food Science and Technology Journal, 23 (2-3), pp. 125-130
- Ranganna, S., Lakshminarayana-Setty, Non-enzymatic discoloration in fruit and vegetable products (1989) Trends in Food Science and Technology', , ed. by Raghavendra Rao, M.R. et al. Conference. Mysore, India
- Rovedo, C.O., (1994) Transferencia Simultânea De Calor Y Materia En Sistemas Con Cambio De Volumen: Aplicacion Al Secado De Plaças De Papa., , PhD Thesis. Universidad de Buenos Aires, Argentina
- Rovedo, C.O., Suarez, C., Viollaz, P.E., Drying simulation of a solid slab with three dimensional shrinkage (1995) Drying Technology, 13, pp. 371-393
- Treybal, R.E., (1980) Operaciones De Transferencia De Masa, 2Ed, , Me Graw-Hill Books Co
- Wang, N., Brennan, J.G., Thermal conductivity of potato as a function of moisture content (1993) J. Food Engineering, 17, pp. 153-160
Citas:
---------- APA ----------
Rovedo, C.O. & Viollaz, P.E.
(1998)
. Prediction of degrading reactions during drying of solid foodstuffs. Drying Technology, 16(3-5), 561-578.
http://dx.doi.org/10.1080/07373939808917424---------- CHICAGO ----------
Rovedo, C.O., Viollaz, P.E.
"Prediction of degrading reactions during drying of solid foodstuffs"
. Drying Technology 16, no. 3-5
(1998) : 561-578.
http://dx.doi.org/10.1080/07373939808917424---------- MLA ----------
Rovedo, C.O., Viollaz, P.E.
"Prediction of degrading reactions during drying of solid foodstuffs"
. Drying Technology, vol. 16, no. 3-5, 1998, pp. 561-578.
http://dx.doi.org/10.1080/07373939808917424---------- VANCOUVER ----------
Rovedo, C.O., Viollaz, P.E. Prediction of degrading reactions during drying of solid foodstuffs. Dry. Technol. 1998;16(3-5):561-578.
http://dx.doi.org/10.1080/07373939808917424