Abstract:
The title compound was synthesized in four steps from D-glucono-1,5-lactone, Reduction of 2,4,6-tri-O-benzoyl-3-deoxy-D-arabino-hexono-l,5-lactone (1) with disiamylborane afforded 2,4,6-tri-O-benzoyl-3-deoxy-D-arabino-hexopyranose (2) which, on debenzoylation, gave 3-deoxy-D-arabino-hexose (3).Tautomeric equilibrium of 3 was studied by lH and 13C NMR spectroscopy. © 1984, Taylor & Francis Group, LLC. All rights reserved.
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Citas:
---------- APA ----------
du Mortier, C. & de Lederkremer, R.M.
(1984)
. A new synthesis of 3-deoxy-d-arabino-hexose and its tautomeric equilibrium. Journal of Carbohydrate Chemistry, 3(2), 219-228.
http://dx.doi.org/10.1080/07328308408058816---------- CHICAGO ----------
du Mortier, C., de Lederkremer, R.M.
"A new synthesis of 3-deoxy-d-arabino-hexose and its tautomeric equilibrium"
. Journal of Carbohydrate Chemistry 3, no. 2
(1984) : 219-228.
http://dx.doi.org/10.1080/07328308408058816---------- MLA ----------
du Mortier, C., de Lederkremer, R.M.
"A new synthesis of 3-deoxy-d-arabino-hexose and its tautomeric equilibrium"
. Journal of Carbohydrate Chemistry, vol. 3, no. 2, 1984, pp. 219-228.
http://dx.doi.org/10.1080/07328308408058816---------- VANCOUVER ----------
du Mortier, C., de Lederkremer, R.M. A new synthesis of 3-deoxy-d-arabino-hexose and its tautomeric equilibrium. J. Carbohydr. Chem. 1984;3(2):219-228.
http://dx.doi.org/10.1080/07328308408058816