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Abstract:

The stereospecific synthesis of methyl 3-0-benzoyl-6-0-(tert-butyldiphenylsilyl)-2-deoxy-a-D-e/j//iro-hexopyranosid-4-ulose (5) - a Thromboxane B2 (TXB2) precursor - starting from D-galactose is described. Facile and established methods including selective benzoylation, oxidation-elimination and a stereocontrolled hydrogenation (Pd /charcoal) were employed effectively. © 1995, Taylor & Francis Group, LLC. All rights reserved.

Registro:

Documento: Artículo
Título:Simple stereocontrolled synthesis of methyl 2-deoxy-d-£/mffl(?-hexopyranosid-4-uloses, thromboxane B2 (txb2) precursors, from d-galactose
Autor:Moradei, O.; Mortier, C.D.; Alicia, F.A.; Joachim, J.; Ihiem, I.
Filiación:Departamento de Quimica Orgánica, Facultad de Ciencias Exactas v Naturales, Universidad de Buenos Aires, Pab. II Ciudad Universitaria, Buenos Aires, Argentina
Institut rur Orgamsche Chemie, Hamburg, United Kingdom
Año:1995
Volumen:14
Número:4-5
Página de inicio:525
Página de fin:532
DOI: http://dx.doi.org/10.1080/07328309508005355
Título revista:Journal of Carbohydrate Chemistry
Título revista abreviado:J. Carbohydr. Chem.
ISSN:07328303
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07328303_v14_n4-5_p525_Moradei

Referencias:

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Citas:

---------- APA ----------
Moradei, O., Mortier, C.D., Alicia, F.A., Joachim, J. & Ihiem, I. (1995) . Simple stereocontrolled synthesis of methyl 2-deoxy-d-£/mffl(?-hexopyranosid-4-uloses, thromboxane B2 (txb2) precursors, from d-galactose. Journal of Carbohydrate Chemistry, 14(4-5), 525-532.
http://dx.doi.org/10.1080/07328309508005355
---------- CHICAGO ----------
Moradei, O., Mortier, C.D., Alicia, F.A., Joachim, J., Ihiem, I. "Simple stereocontrolled synthesis of methyl 2-deoxy-d-£/mffl(?-hexopyranosid-4-uloses, thromboxane B2 (txb2) precursors, from d-galactose" . Journal of Carbohydrate Chemistry 14, no. 4-5 (1995) : 525-532.
http://dx.doi.org/10.1080/07328309508005355
---------- MLA ----------
Moradei, O., Mortier, C.D., Alicia, F.A., Joachim, J., Ihiem, I. "Simple stereocontrolled synthesis of methyl 2-deoxy-d-£/mffl(?-hexopyranosid-4-uloses, thromboxane B2 (txb2) precursors, from d-galactose" . Journal of Carbohydrate Chemistry, vol. 14, no. 4-5, 1995, pp. 525-532.
http://dx.doi.org/10.1080/07328309508005355
---------- VANCOUVER ----------
Moradei, O., Mortier, C.D., Alicia, F.A., Joachim, J., Ihiem, I. Simple stereocontrolled synthesis of methyl 2-deoxy-d-£/mffl(?-hexopyranosid-4-uloses, thromboxane B2 (txb2) precursors, from d-galactose. J. Carbohydr. Chem. 1995;14(4-5):525-532.
http://dx.doi.org/10.1080/07328309508005355