Abstract:
The stereospecific synthesis of methyl 3-0-benzoyl-6-0-(tert-butyldiphenylsilyl)-2-deoxy-a-D-e/j//iro-hexopyranosid-4-ulose (5) - a Thromboxane B2 (TXB2) precursor - starting from D-galactose is described. Facile and established methods including selective benzoylation, oxidation-elimination and a stereocontrolled hydrogenation (Pd /charcoal) were employed effectively. © 1995, Taylor & Francis Group, LLC. All rights reserved.
Registro:
Documento: |
Artículo
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Título: | Simple stereocontrolled synthesis of methyl 2-deoxy-d-£/mffl(?-hexopyranosid-4-uloses, thromboxane B2 (txb2) precursors, from d-galactose |
Autor: | Moradei, O.; Mortier, C.D.; Alicia, F.A.; Joachim, J.; Ihiem, I. |
Filiación: | Departamento de Quimica Orgánica, Facultad de Ciencias Exactas v Naturales, Universidad de Buenos Aires, Pab. II Ciudad Universitaria, Buenos Aires, Argentina Institut rur Orgamsche Chemie, Hamburg, United Kingdom
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Año: | 1995
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Volumen: | 14
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Número: | 4-5
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Página de inicio: | 525
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Página de fin: | 532
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DOI: |
http://dx.doi.org/10.1080/07328309508005355 |
Título revista: | Journal of Carbohydrate Chemistry
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Título revista abreviado: | J. Carbohydr. Chem.
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ISSN: | 07328303
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07328303_v14_n4-5_p525_Moradei |
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Citas:
---------- APA ----------
Moradei, O., Mortier, C.D., Alicia, F.A., Joachim, J. & Ihiem, I.
(1995)
. Simple stereocontrolled synthesis of methyl 2-deoxy-d-£/mffl(?-hexopyranosid-4-uloses, thromboxane B2 (txb2) precursors, from d-galactose. Journal of Carbohydrate Chemistry, 14(4-5), 525-532.
http://dx.doi.org/10.1080/07328309508005355---------- CHICAGO ----------
Moradei, O., Mortier, C.D., Alicia, F.A., Joachim, J., Ihiem, I.
"Simple stereocontrolled synthesis of methyl 2-deoxy-d-£/mffl(?-hexopyranosid-4-uloses, thromboxane B2 (txb2) precursors, from d-galactose"
. Journal of Carbohydrate Chemistry 14, no. 4-5
(1995) : 525-532.
http://dx.doi.org/10.1080/07328309508005355---------- MLA ----------
Moradei, O., Mortier, C.D., Alicia, F.A., Joachim, J., Ihiem, I.
"Simple stereocontrolled synthesis of methyl 2-deoxy-d-£/mffl(?-hexopyranosid-4-uloses, thromboxane B2 (txb2) precursors, from d-galactose"
. Journal of Carbohydrate Chemistry, vol. 14, no. 4-5, 1995, pp. 525-532.
http://dx.doi.org/10.1080/07328309508005355---------- VANCOUVER ----------
Moradei, O., Mortier, C.D., Alicia, F.A., Joachim, J., Ihiem, I. Simple stereocontrolled synthesis of methyl 2-deoxy-d-£/mffl(?-hexopyranosid-4-uloses, thromboxane B2 (txb2) precursors, from d-galactose. J. Carbohydr. Chem. 1995;14(4-5):525-532.
http://dx.doi.org/10.1080/07328309508005355