Abstract:
Band shapes in the gas phase infrared spectrum of cyclooctatetraene (COT) have been recorded in the 3500-250 cm-1 range. With these and the existing vibrational data for COT and COT-d8, revised assignments of the fundamental modes have been made for both compounds. A normal coordinate analysis based on D2d symmetry has been carried out and used to support the vibrational assignments. © 1991.
Referencias:
- Lippincott, Lord, McDonald, (1951) J. Am. Chem. Soc., 73, p. 3370. , and Refs therein
- Kaufman, Fankuchen, Mark, (1948) Nature, 161, p. 165
- Hedberg, Schomaker, (1949) Abstracts, American Chemical Society Meeting, San Francisco, CA
- Karle, (1952) J. Chem. Phys., 20, p. 65
- Bastiansen, Hedberg, Hedberg, (1957) J. Chem. Phys., 27, p. 1311
- Traetteberg, The Molecular Structure of 1,3,5,7-Cyclo-octatetraene. (1966) Acta Chemica Scandinavica, 20, p. 1724
- Tabacik, Blaise, (1986) C.R. Acad. Sci., Ser. 2, 303, p. 539
- Gerhard, Dennison, (1933) Phys. Rev., 43, p. 197
- Teller, (1934) Hand und Jahrbuch der Chem. Physik, 9 (2), p. 125
- Edgell, Moynihan, (1966) J. Chem. Phys., 45, p. 1205. , and Refs therein
- Herzberg, (1945) Infrared and Raman Spectra, pp. 126-129. , D. Van Nostrand, New York
- Boyd, Longuet-Higgins, Coriolis Interaction between Vibration and Rotation in Symmetric Top Molecules (1952) Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, 213 A, p. 55
- Wilson, Decius, Cross, (1955) Molecular Vibrations, , McGraw Hill, New York
- Crawford, Jr, Overend, (1964) J. Mol. Spectrosc., 12, p. 307
- J. H. Schachtschneider, Technical Report No. 210-61, Shell Development Company, Emeryville, CA; a J. H. Schachctshneider, Technical Report No. 263-62, Shell Development Company, Emeryville, CA; Schachtschneider, Snyder, (1963) Spectrochim. Acta, 19, p. 117
- Crawford, Lancaster, Inskeep, (1953) J. Chem. Phys., 21, p. 678
- Mills, Duncan, (1962) J. Mol. Spectrosc., 9, p. 244
Citas:
---------- APA ----------
(1991)
. A reinvestigation of the vibrational spectra of cyclooctatetraene and cyclooctatetraene-d8. Spectrochimica Acta Part A: Molecular Spectroscopy, 47(6), 799-809.
http://dx.doi.org/10.1016/0584-8539(91)80152-9---------- CHICAGO ----------
Perec, M.
"A reinvestigation of the vibrational spectra of cyclooctatetraene and cyclooctatetraene-d8"
. Spectrochimica Acta Part A: Molecular Spectroscopy 47, no. 6
(1991) : 799-809.
http://dx.doi.org/10.1016/0584-8539(91)80152-9---------- MLA ----------
Perec, M.
"A reinvestigation of the vibrational spectra of cyclooctatetraene and cyclooctatetraene-d8"
. Spectrochimica Acta Part A: Molecular Spectroscopy, vol. 47, no. 6, 1991, pp. 799-809.
http://dx.doi.org/10.1016/0584-8539(91)80152-9---------- VANCOUVER ----------
Perec, M. A reinvestigation of the vibrational spectra of cyclooctatetraene and cyclooctatetraene-d8. Spectrochim. Acta Part A Mol. Spectrosc. 1991;47(6):799-809.
http://dx.doi.org/10.1016/0584-8539(91)80152-9