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Abstract:

Hybrid materials were developed via in situ oxidative polymerization of aniline in presence of 0.5 wt% of nano-/micro-particles. Polymerization was carried out in hydrochloric acid (HCl) medium. Four types of particles were used (aluminum powder 140 mesh, carbon nanotubes and quartz dust in two sizes, 400 and 140 mesh). Polyaniline and hybrid materials were characterized by spectroscopic techniques (UV-Vis, FT-IR), thermal analyses (TGA, DSC), morphological studies (FE-SEM); electrical conductivity and wear resistance measurements. The most promising hybrids were obtained by the incorporation of aluminum (140 mesh) or quartz 400 mesh powders. In both cases, electrical conductivity was similar to the one measured for PANI but up to 40% higher wear resistance. © 2011 Elsevier B.V. All rights reserved.

Registro:

Documento: Artículo
Título:Effects of different nucleating particles on aniline polymerization
Autor:Lissarrague, M.H.; Lamanna, M.E.; D'Accorso, N.B.; Goyanes, S.
Filiación:LP and MC, Departamento de Física, Ciudad Universitaria 1428, Ciudad Autónoma de Buenos Aires, Argentina
CIHIDECAR-CONICET, Departamento de Química Orgánica, Ciudad Universitaria 1428, Ciudad Autónoma de Buenos Aires, Argentina
Palabras clave:Electrical conductivity; Hybrid materials; PANI; Wear resistance; Aluminum powders; Aniline polymerization; Electrical conductivity; In-situ; Morphological study; PANI; Quartz dust; Resistance measurement; Spectroscopic technique; Aluminum; Aniline; Electric conductivity; Hybrid materials; Hydrochloric acid; Polyaniline; Quartz; Thermoanalysis; Wear resistance; Polymerization
Año:2012
Volumen:162
Número:11-12
Página de inicio:1052
Página de fin:1058
DOI: http://dx.doi.org/10.1016/j.synthmet.2011.12.018
Título revista:Synthetic Metals
Título revista abreviado:Synth Met
ISSN:03796779
CODEN:SYMED
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03796779_v162_n11-12_p1052_Lissarrague

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Citas:

---------- APA ----------
Lissarrague, M.H., Lamanna, M.E., D'Accorso, N.B. & Goyanes, S. (2012) . Effects of different nucleating particles on aniline polymerization. Synthetic Metals, 162(11-12), 1052-1058.
http://dx.doi.org/10.1016/j.synthmet.2011.12.018
---------- CHICAGO ----------
Lissarrague, M.H., Lamanna, M.E., D'Accorso, N.B., Goyanes, S. "Effects of different nucleating particles on aniline polymerization" . Synthetic Metals 162, no. 11-12 (2012) : 1052-1058.
http://dx.doi.org/10.1016/j.synthmet.2011.12.018
---------- MLA ----------
Lissarrague, M.H., Lamanna, M.E., D'Accorso, N.B., Goyanes, S. "Effects of different nucleating particles on aniline polymerization" . Synthetic Metals, vol. 162, no. 11-12, 2012, pp. 1052-1058.
http://dx.doi.org/10.1016/j.synthmet.2011.12.018
---------- VANCOUVER ----------
Lissarrague, M.H., Lamanna, M.E., D'Accorso, N.B., Goyanes, S. Effects of different nucleating particles on aniline polymerization. Synth Met. 2012;162(11-12):1052-1058.
http://dx.doi.org/10.1016/j.synthmet.2011.12.018