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Abstract:

The Raman spectrum of tartrazine has been mistakenly reported as being that of Indian yellow in the literature, which has serious consequences for the identification of this pigment in art works regarding their authentication. Unlike tartrazine, Indian yellow (a natural mixture of the magnesium and calcium salts of euxanthic acid) exhibits in its Raman spectrum a strong fluorescent background when visible excitation is used, however, excitation in the near infrared (1064 nm) permitted the observation of the Raman bands from the raw pigment with the main features placed at 1346, 1368, 1425, 1441 and 1626 cm−1. Indian yellow identification was assured by 1H and 13C Nuclear Magnetic Resonance characterization and the complete assignment of the proton and carbon resonances was accomplished using heteronuclear single quantum correlation (HSQC), heteronuclear multiple bond correlation (HMBC), nuclear overhauser effect spectroscopy (NOESY) and 1H–1H correlation spectroscopy (COSY). Scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS) and X-ray fluorescence (XRF) analyzes were also conducted on a genuine sample of this historical pigment. © 2016 Elsevier Ireland Ltd

Registro:

Documento: Artículo
Título:A definitive analytical spectroscopic study of Indian yellow, an ancient pigment used for dating purposes
Autor:de Faria, D.L.A.; Edwards, H.G.M.; Careaga, V.; Walt, N.; Maier, M.S.
Filiación:Institute of Chemistry, University of São Paulo, Av. Prof. Lineu Prestes, 748, Butantã, São Paulo, SP 05508-000, Brazil
Interinstitutional Graduate Program in Museology (PPGMus-USP), University of São Paulo, Av. Prof. Almeida Prado, 1466, São Paulo, SP 05508-070, Brazil
Department of Chemical and Forensic Sciences, University of Bradford, Bradford, West Yorkshire BD7 1DP, United Kingdom
UMYMFOR and Departamento de Química Orgánica, Universidad de Buenos Aires, Pabellón 2, Ciudad Universitaria, Buenos Aires, 1428, Argentina
L. Cornelissen & Son Ltd., 105 Great Russell Street, London, WC1B 3RY, United Kingdom
Palabras clave:Artwork; Indian yellow; Pigment; Raman spectroscopy; Tartrazine; tartrazine; Article; carbon nuclear magnetic resonance; controlled study; energy dispersive X ray spectroscopy; heteronuclear multiple bond correlation; heteronuclear single quantum coherence; limit of quantitation; nuclear Overhauser effect; photon correlation spectroscopy; priority journal; proton nuclear magnetic resonance; Raman spectrometry; scanning electron microscopy; X ray fluorescence
Año:2017
Volumen:271
Página de inicio:1
Página de fin:7
DOI: http://dx.doi.org/10.1016/j.forsciint.2016.11.037
Título revista:Forensic Science International
Título revista abreviado:Forensic Sci. Int.
ISSN:03790738
CODEN:FSIND
CAS:tartrazine, 1934-21-0
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03790738_v271_n_p1_deFaria

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Citas:

---------- APA ----------
de Faria, D.L.A., Edwards, H.G.M., Careaga, V., Walt, N. & Maier, M.S. (2017) . A definitive analytical spectroscopic study of Indian yellow, an ancient pigment used for dating purposes. Forensic Science International, 271, 1-7.
http://dx.doi.org/10.1016/j.forsciint.2016.11.037
---------- CHICAGO ----------
de Faria, D.L.A., Edwards, H.G.M., Careaga, V., Walt, N., Maier, M.S. "A definitive analytical spectroscopic study of Indian yellow, an ancient pigment used for dating purposes" . Forensic Science International 271 (2017) : 1-7.
http://dx.doi.org/10.1016/j.forsciint.2016.11.037
---------- MLA ----------
de Faria, D.L.A., Edwards, H.G.M., Careaga, V., Walt, N., Maier, M.S. "A definitive analytical spectroscopic study of Indian yellow, an ancient pigment used for dating purposes" . Forensic Science International, vol. 271, 2017, pp. 1-7.
http://dx.doi.org/10.1016/j.forsciint.2016.11.037
---------- VANCOUVER ----------
de Faria, D.L.A., Edwards, H.G.M., Careaga, V., Walt, N., Maier, M.S. A definitive analytical spectroscopic study of Indian yellow, an ancient pigment used for dating purposes. Forensic Sci. Int. 2017;271:1-7.
http://dx.doi.org/10.1016/j.forsciint.2016.11.037