Artículo
Santini, E.S.; Carusela, M.F.; Izquierdo, E.D. "Complementarity relation for irreversible processes near steady states" (2013) Physica A: Statistical Mechanics and its Applications. 392(20):4856-4867
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Abstract:
A relation giving a minimum for the irreversible work in quasi-equilibrium processes was derived by Sekimoto et al. [K. Sekimoto, S. Sasa, J. Phys. Soc. Japan 66 (1997) 3326] in the framework of stochastic energetics. This relation can also be written as a type of "uncertainty principle" in such a way that the precise determination of the Helmholtz free energy through the observation of the work 〈W〉 requires an indefinitely large experimental time Δt. In the present article, we extend this relation to the case of quasi-steady processes by using the concept of non-equilibrium Helmholtz free energy. We give a formulation of the second law for these processes that extends that presented by Sekimoto [K. Sekimoto, Prog. Theoret. Phys. Suppl. No. 130 (1998) 17] by a term of the first order in the inverse of the experimental time. As an application of our results, two possible experimental situations are considered: stretching of a RNA molecule and the drag of a dipolar particle in the presence of a gradient of electric force. © 2013 Elsevier B.V. All rights reserved.
Registro:
| Documento: | Artículo |
| Título: | Complementarity relation for irreversible processes near steady states |
| Autor: | Santini, E.S.; Carusela, M.F.; Izquierdo, E.D. |
| Filiación: | Comissão Nacional de Energia Nuclear, Rua General Severiano 90, Botafogo (22290-901), Rio de Janeiro, RJ, Brazil Universidad Nacional de General Sarmiento, Instituto de Ciencias, J. M. Gutiérrez 1150, Malvinas Argentinas (1613), Pcia de Buenos Aires, Argentina Centro Brasileiro de Pesquisas Físicas - ICRA-BR, Rua Dr. Xavier Sigaud 150, Urca (22290-180), Rio de Janeiro, RJ, Brazil Ciclo Básico Común, Universidad de Buenos Aires, Cdad. Universitaria, Pab. 3, (1428) Buenos Aires, Argentina Facultad de Agronomía, Universidad de Buenos Aires, Av. Av. San Martn 4453, Cap. Fed., Buenos Aires (C1417DSE), Argentina Consejo Nacional de Investigaciones Científicas y Técnicas, Av. Rivadavia 1917, (1033)-Buenos Aires, Argentina |
| Palabras clave: | Fluctuation phenomena; Langevin equation; Stochastic energetics; Thermodynamics; Complementarity relations; Fluctuation phenomena; Irreversible process; Langevin equation; Precise determinations; Quasi-equilibrium process; Stochastic energetics; Uncertainty principles; Differential equations; Free energy; RNA; Stochastic systems; Thermodynamics; Statistical mechanics |
| Año: | 2013 |
| Volumen: | 392 |
| Número: | 20 |
| Página de inicio: | 4856 |
| Página de fin: | 4867 |
| DOI: | http://dx.doi.org/10.1016/j.physa.2013.06.045 |
| Título revista: | Physica A: Statistical Mechanics and its Applications |
| Título revista abreviado: | Phys A Stat Mech Appl |
| ISSN: | 03784371 |
| CODEN: | PHYAD |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03784371_v392_n20_p4856_Santini |
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Citas:
---------- APA ----------
Santini, E.S., Carusela, M.F. & Izquierdo, E.D. (2013) . Complementarity relation for irreversible processes near steady states. Physica A: Statistical Mechanics and its Applications, 392(20), 4856-4867.http://dx.doi.org/10.1016/j.physa.2013.06.045
---------- CHICAGO ----------
Santini, E.S., Carusela, M.F., Izquierdo, E.D. "Complementarity relation for irreversible processes near steady states" . Physica A: Statistical Mechanics and its Applications 392, no. 20 (2013) : 4856-4867.http://dx.doi.org/10.1016/j.physa.2013.06.045
---------- MLA ----------
Santini, E.S., Carusela, M.F., Izquierdo, E.D. "Complementarity relation for irreversible processes near steady states" . Physica A: Statistical Mechanics and its Applications, vol. 392, no. 20, 2013, pp. 4856-4867.http://dx.doi.org/10.1016/j.physa.2013.06.045
---------- VANCOUVER ----------
Santini, E.S., Carusela, M.F., Izquierdo, E.D. Complementarity relation for irreversible processes near steady states. Phys A Stat Mech Appl. 2013;392(20):4856-4867.http://dx.doi.org/10.1016/j.physa.2013.06.045
