Artículo

Chiodini, G.; Cardellini, C.; Lamberti, M.C.; Agusto, M.; Caselli, A.; Liccioli, C.; Tamburello, G.; Tassi, F.; Vaselli, O.; Caliro, S. "Carbon dioxide diffuse emission and thermal energy release from hydrothermal systems at Copahue-Caviahue Volcanic Complex (Argentina)" (2015) Journal of Volcanology and Geothermal Research. 304:294-303
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Abstract:

The north-western sector of Caviahue caldera (Argentina), close to the active volcanic system of Copahue, is characterized by the presence of several hydrothermal sites that host numerous fumarolic emissions, anomalous soil diffuse degassing of CO 2 and hot soils. In March 2014, measurements of soil CO 2 fluxes in 5 of these sites (namely, Las Máquinas, Las Maquinitas I, Las Maquinitas II, Anfiteatro, and Termas de Copahue) allowed an estimation that ~165t of deeply derived CO 2 is daily released. The gas source is likely related to a relatively shallow geothermal reservoir containing a single vapor phase as also suggested by both the geochemical data from the 3 deep wells drilled in the 1980s and gas geoindicators applied to the fumarolic discharges. Gas equilibria within the H-C-O gas system indicate the presence of a large, probably unique, single phase vapor zone at 200-210°C feeding the hydrothermal manifestations of Las Máquinas, Las Maquinitas I and II and Termas de Copahue. A natural thermal release of 107MW was computed by using CO 2 as a tracer of the original vapor phase. The magmatic signature of the incondensable fumarolic gases, the wide expanse of the hydrothermal areas and the remarkable high amount of gas and heat released by fluid expulsion seem to be compatible with an active magmatic intrusion beneath this portion of the Caviahue caldera. © 2015 Elsevier B.V..

Registro:

Documento: Artículo
Título:Carbon dioxide diffuse emission and thermal energy release from hydrothermal systems at Copahue-Caviahue Volcanic Complex (Argentina)
Autor:Chiodini, G.; Cardellini, C.; Lamberti, M.C.; Agusto, M.; Caselli, A.; Liccioli, C.; Tamburello, G.; Tassi, F.; Vaselli, O.; Caliro, S.
Filiación:Istituto Nazionale di Geofisica e Vulcanologia, Sezione di Bologna, Via D. Creti 12, Bologna, 40128, Italy
Università degli Studi di Perugia, Dipartimento di Fisica e Geologia, Via G. Pascoli snc, Perugia, I-06123, Italy
IDEAN-GESVA, Dpto. Cs. Geológicas, FCEN, Universidad de Buenos Aires, Buenos Aires, Argentina
LESVA-IIPG, Universidad Nacional de Río Negro, General Roca, Argentina
Università degli Studi di Palermo, DiSTeM, Via Archirafi 36, Palermo, I-90123, Italy
Università degli Studi di Firenze, Dipartimento di Scienze della Terra, Via G La Pira 4, Firenze, I-50121, Italy
Istituto di Geoscience e Georisorse-Consiglio Nazionale delle Ricerche (CNR-IGG), Via La Pira, 4, Firenze, I-50121, Italy
Istituto Nazionale di Geofisica e Vulcanologia, Sezione di Napoli-Osservatorio Vesuviano, Via Diocleziano 328, Napoli, I-80124, Italy
Palabras clave:Caviahue Caldera; Copahue Volcano CO 2 diffuse degasing; Thermal energy; Carbon; Carbon dioxide; Geothermal fields; Phase equilibria; Soils; Thermal energy; Volcanoes; Caviahue Caldera; Copahue; Diffuse degassing; Geothermal reservoir; Hydrothermal areas; Hydrothermal system; Magmatic intrusions; Magmatic signatures; Gases; caldera; carbon dioxide; carbon emission; degassing; fumarole; hydrothermal system; soil carbon; Copahue; Neuquen; Southern Volcanic Zone
Año:2015
Volumen:304
Página de inicio:294
Página de fin:303
DOI: http://dx.doi.org/10.1016/j.jvolgeores.2015.09.007
Título revista:Journal of Volcanology and Geothermal Research
Título revista abreviado:J. Volcanol. Geotherm. Res.
ISSN:03770273
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03770273_v304_n_p294_Chiodini

Referencias:

  • Afanasyev, A.A., Multiphase compositional modelling of CO 2 injection under subcritical conditions: the impact of dissolution and phase transitions between liquid and gaseous CO 2 on reservoir temperature (2013) Int. J. Greenhouse Gas Control, 19, pp. 731-742. , http://dx.doi.org/http://dx.doi.org/10.1016/j.ijggc.2013.01.042
  • Agusto, M., Estudio geoquímico de los fluidos volcánicos e hidrotermales del Complejo Volcánico Copahue Caviahue y su aplicación para tareas de seguimiento (2011), p. 290. , Tesis Doctoral (unpublished). Universidad de Buenos Aires; Agusto, M., Varekamp, J., (2015) The Copahue Volcanic-Hydrothermal System and Applications for Volcanic Surveillance, , Copahue Volcano. Springer International Publishing, AG., F. En Tassi, O. Vaselli, A. y Caselli (Eds.)
  • Agusto, M., Caselli, A., Tassi, F., Dos Santos Alfonso, M., Vaselli, O., Seguimiento geoquímico de las aguas ácidas del sistema volcán Copahue-Río Agrio: posible aplicación para la identificación de precursores eruptivos (2012) Rev. Asoc. Geol. Argent., 69 (4), pp. 481-495
  • Agusto, M., Tassi, F., Caselli, A., Vaselli, O., Rouwet, D., Capaccioni, B., Caliro, S., Darrah, T., Gas geochemistry of the magmatic-hydrothermal fluid reservoir in the Copahue-Caviahue Volcanic Complex (Argentina) (2013) J. Volcanol. Geotherm. Res., 257, pp. 44-56
  • Aiuppa, A., Tamburello, G., Napoli, R., Cardellini, C., Chiodini, G., Giudice, G., Grassa, F., Pedone, M., First observations of the fumarolic gas output from a restless caldera: implications for the current period of unrest (2005-2013) at Campi Flegrei (2013) Geochemistry Geophysics Geosystems, 14, pp. 4153-4169
  • Bermúdez, A., Delpino, D., López Escobar, L., Caracterización geoquímica de lavas y piroclastos holocenos del volcán Copahue, incluyendo los originados en la erupción del año 2000 (2002) XV Congreso Geológico Argentino, Calafate. Actas, 1, pp. 377-382. , Comparación con otros volcanes de la Zona Volcánica Sur de los Andes
  • Berner, R.A., Lasaga, A.C., Modeling the geochemical carbon cycle (1989) Sci. Am., 260, pp. 74-81
  • Bloomberg, S., Werner, C., Rissmann, C., Mazot, A., Horton, T., Gravley, D., Kennedy, B., Oze, C., Soil CO 2 emissions as a proxy for heat and mass flow assessment, Taupo Volcanic Zone, New Zealand (2014) Geochem. Geophys. Geosyst., 15, pp. 4885-4904
  • Burton, M.R., Sawyer, G.M., Granieri, D., Deep carbon emissions from volcanoes (2013) Rev. Mineral. Geochem., 75, pp. 323-354
  • Cardellini, C., Chiodini, G., Frondini, F., Application of stochastic simulation to CO 2 flux from soil: mapping and quantification of gas release (2003) J. Geophys. Res., 108, p. 2425
  • Caselli, A., Agusto, M., Fazio, A., Cambios térmicos y goequímicos del lago cratérico del volcán Copahue (Neuquén): posibles variaciones cíclicas del sistema volcánico (2005) XVI Congreso Geológico Argentino, T1, pp. 751-756
  • Caselli, A., Agusto, M., Velez, M.L., Forte, P., Bengoa, C., Daga, R., Albite, J.M., Capaccioni, B., The 2012 eruption (2015) Copahue Volcano: The Smoking Mountain Between Argentina y Chile, , Springer International Publishing AG, (accepted for publication), F. Tassi, O. Vaselli, A. Caselli (Eds.)
  • Chiodini, G., Granieri, D., Avino, R., Caliro, S., Costa, A., Werner, C., Carbon dioxide diffuse degassing and estimation of heat release from volcanic and hydrothermal systems (2005) J. Geophys. Res. Solid Earth, 110
  • Chiodini, G., Cioni, R., Guidi, M., Marini, L., Raco, B., Soil CO 2 measurements in volcanic and geothermal areas (1998) Appl. Geochem., 13, pp. 543-552
  • Chiodini, G., Frondini, F., Cardellini, C., Granieri, D., Marini, L., Ventura, G., CO 2 degassing and energy release at Solfatara volcano, Campi Flegrei, Italy (2001) J. Geophys. Res. Solid Earth, 106. , 16,213-16,221
  • Chiodini, G., Baldini, A., Barbieri, F., Carapezza, M., Cardellini, C., Frondini, F., Granieri, D., Ranaldi, M., Carbon dioxide degassing at Latera caldera (Italy): evidence of geothermal reservoir and evaluation of its potential energy (2007) J. Geophys. Res.
  • Chiodini, G., Caliro, S., Cardellini, C., Avino, R., Granieri, D., Schmidt, A., Carbon isotopic composition of soil CO 2 efflux, a powerful method to discriminate different sources feeding soil CO 2 degassing in volcanic-hydrothermal areas (2008) Earth Planet. Sci. Lett., 274 (3-4), pp. 372-379
  • Chiodini, G., Vandemeulebrouck, J., Caliro, S., D' Auria, L., De Martino, P., Mangiacapra, A., Petrillo, Z., Evidence of thermal-driven processes triggering the 2005-2014 unrest at Campi Flegrei caldera (2015) Earth Planet. Sci. Lett., 414, pp. 58-67
  • Dellapé, D., Pando, G., Relevamiento geológico de la cuenca geotérmica de Copahue (1975), p. 11. , Yacimientos Petrolíferos Fiscales. Unpublished Report No. 524; Delpino, D., Bermúdez, A., La actividad del volcán Copahue durante 1992 (1993) Provincia de Neuquén, Argentina. XII Congreso Geológico Argentino y II Congreso de Exploración de Hidrocarburos. Actas, 4, pp. 292-301. , Erupción con emisiones de azufre piroclástico
  • Delpino, D., Bermúdez, A., La erupción del volcán Copahue del año 2000 (2002) Impacto social y al medio natural 15° Congreso Geológico Argentino. Actas, 3, pp. 365-370
  • DeMets, C., Gordon, R., Argus, F., Stein, S., Effect of recent revisions of the geomagnetic time scale on estimates of current plate motions (1994) Geophys. Res. Lett., 21, pp. 2191-2194
  • Deutsch, C.V., Journel, A.G., (1998) Geostatistical Software Library and User's Guide, , Oxford University Press, New York
  • Dionis, S.M., Melián, G., Rodríguez, F., Hernández, P., Padrón, E., Pérez, N., Barrancos, J., Semedo, H., Diffuse volcanic gas emission and thermal energy release from the summit crater of Pico do Fogo, Cape Verde (2015) Bull. Volcanol.
  • Folguera, A., Ramos, V., Hermanns, R., Naranjo, J., Neotectonics in the foothills of the Southernmost Central Andes (37°-38°S). Evidence of the strike-slip displacement along the Antiñir-Copahue fault zone (2004) Tectonics, 23, p. 23. , (TC 5008)
  • Folguera, A., Zapata, T., Ramos, V., Late Cenozoic extension and evolution of the Neuquén Andes (2006) GSA Special Paper, 407. , S. Kay, V. Ramos (Eds.) Evolution of the Andean Margin: A Tectonic and Magmatic View from the Andes to the Neuquén Basin (35°-39°S)
  • Forte, P., Bengoa, C., Caselli, A., Análisis preliminar de la actividad sísmica del complejo volcánico Copahue-Caviahue mediante técnicas de array (2012) 13° Congreso Geológico Chileno, pp. 574-576. , (acts)
  • Fridriksson, T., Kristjansson, B.R., Armannsson, H., Margretardottir, E., Olafsdottir, S., Chiodini, G., CO 2 emissions and heat flow through soil, fumaroles, and steam-heated mud pools at the Reykjanes geothermal area, SW Iceland (2006) Appl. Geochem., 21, pp. 1551-1569
  • Gammoms, C.H., Wood, S.A., Pedrozo, F., Varekamp, J.C., Nelson, B., Shope, C.L., Baffico, G., Hydrogeochemistry and rare earth element behavior in a volcanically acidified watershed in Patagonia (2005) Argentina. Chem. Geol., 222, pp. 249-267
  • Giggenbach, W.F., A simple method for the collection and analysis of volcanic gas samples (1975) Bull. Volcanol., 39 (1), pp. 132-145
  • Giggenbach, W.F., Goguel, R.L., Methods for the collection and analysis of geothermal and volcanic water and gas samples (1989) Department of Scientific and Industrial Research, Chemistry Division, Report, p. 2401
  • Giggenbach, W.F., Matsuo, S., Evaluation of results from Second and Third IAVCEI field workshops on Volcanic gases, Mt. Usu, Japan, and White Island, New Zealand (1991) Appl. Geochem., 6 (2), pp. 125-141
  • Granieri, D., Giovanni, C., Avino, R., Caliro, S., Carbon dioxide emission and heat release estimation for Pantelleria Island (Sicily, Italy) (2014) J. Vulcanol. Geotherm. Res., 275, pp. 22-33
  • Bulletin of the global volcanism network (2000) Volcanic Activity Reports, 25, pp. 10-14. , (N° 6)
  • Bulletin of the global volcanism network (2000) Volcanic Activity Reports, 25, pp. 1-3. , (N° 9)
  • Hernández, P.A., Pérez, N.M., Fridriksson, T., Egbert, J., Ilyinskaya, E., Thárhallsson, A., Ívarsson, G., Jónsson, B., Diffuse volcanic degassing and thermal energy release from Hengill volcanic system, Iceland (2012) Bull. Volcanol., 74, pp. 2435-2448
  • Ibáñez, J.M., Del Pezzo, E., Bengoa, C., Caselli, A., Badi, G., Almendros, J., Volcanic tremor and local earthquakes at Copahue volcanic complex, Southern Andes, Argentina (2008) J. Volcanol. Geotherm. Res., 174 (2008), pp. 284-294
  • The feasibility study on the Northern Neuquén Geothermal Development Project (Unpublished) (1992), p. 89. , Ente Provincial de Energía de la Provincia de Neuquén; Jurío, R.L., Características geoquímicas de los fluidos termales de Copahue (Neuquén - Argentina). Principales implicancias geotérmicas (1977) Minería, 172, p. 11
  • (1981) Estudio de Pospección Geotérmica en el área de Copahue, , COPADE, Neuquén
  • Lavenu, A., Cembrano, J., Compressional and transpressional stress pattern for Pliocene and Quaternary brittle deformation in fore-arc and intra-arc zones (Andes of Central and Southern Chile) (1999) J. Struct. Geol., 21, pp. 1669-1691
  • Lewicki, J.L., Oldenburg, C.M., Near-surface CO 2 monitoring and analysis to detect hidden geothermal systems (2005) PROCEEDINGS, Thirtieth Workshop on Geothermal Reservoir Engineering, , Stanford University SGP-TR-176
  • Lewicki, J.L., Bergfeld, D., Cardellini, C., Chiodini, G., Granieri, D., Varley, N., Werner, C., Comparative soil CO 2 flux measurements and geostatistical estimation methods on Masaya volcano, Nicaragua (2005) Bull. Volcanol., 68 (1), pp. 76-90
  • Martini, M., Bermúdez, A., Delfino, D., Giannini, L., The thermal manifestation of Copahue volcano area (1997) VIII Congreso Geológico Chileno, Antofagasta, 4, pp. 352-356. , Neuquen, Argentina
  • Mas, G.R., Mas, L.C., Bengochea, L., Alteración ácido-sulfática en el Campo Geotérmico Copahue, Provincia del Neuquén (1996) Asoc. Geol. Argent., 51 (1), pp. 78-86
  • Mas, L.C., Mas, G.R., Bengochea, L., Heatflow of Copahue geothermal field, its relation with tectonic scheme (2000) Proceedings of World Geothermal Congress, Tohoku, Japan, pp. 1419-1424
  • Mazot, A., Taran, Y., CO 2 flux from the volcanic lake of El Chichón (Mexico) (2009) Geofís. Int., 48 (1), pp. 73-83
  • Melnick, D., Folguera, A., Ramos, V.A., Structural control on arc volcanism: The Copahue-Agrio complex, South-Central Andes (37°50'S) (2006) J. S. Am. Earth Sci., 22, pp. 66-88
  • Naranjo, J.A., Polanco, E., The 2000AD eruption of Copahue Volcano, Southern Andes (2004) Rev. Geol. Chile, 31 (2), pp. 279-292
  • Panarello, H., Características isotópicas y termodinámicas de reservorio del campo geotérmico Copahue-Caviahue, provincia del Neuquén (2002) Rev. Asoc. Geol. Argent., 57 (2), pp. 182-194
  • Panarello, H., Levin, M., Albero, M.C., Sierra, J.L., Gingins, M.O., Isotopic and geochemical study of the vapor dominated geothermal field of Copahue (Neuquén, Argentina) (1988) Rev. Bras. Geofísica, 5 (2), pp. 275-282
  • Polanco, E., Evolución del volcán Copahue (37° 45' S), Andes del Sur (2003), p. 90. , Tesis de Maestría (unpublished), Universidad Nacional Autónoma de México; Radic, J.P., Las cuencas cenozoicas y su control en el volcanismo de los complejos Nevados de Chillán y Copahue-Callaqui (36°-39°S) (2010) Andean Geol., 37 (1), pp. 220-246
  • Raich, J.W., Schlesinger, W.H., The global carbon dioxide flux in soil respiration and its relationship to vegetation and climate (1992) Tellus, 44B, pp. 81-99
  • Raich, J.W., Tufekcioglu, A., Vegetation and soil respiration: correlations and controls (2000) Biogeochemistry, 48 (1), pp. 71-90
  • Ramos, V.A., Folguera, A., Tectonic evolution of the Andes of Neuquén: constraints derived from the magmatic arc and foreland deformation (2000) The Neuquén Basin, Argentina: A Case Study in Sequence Stratigraphy and Basin Dynamics: Geological Society, London, Special Publications, 252, pp. 15-35. , G.D. Veiga, L.A. Spalletti, J.A. Howell, E. Schwartz (Eds.)
  • Rissmann, C., Christenson, B., Werner, C., Leybourne, M., Cole, J., Gravley, D., Surface heat flow and CO 2 emissions within the Ohaaki hydrothermal field, Taupo Volcanic Zone, New Zealand (2012) Appl. Geochem., 27, pp. 223-239
  • Rojas Vera, E.A., Folguera, A., Zamora, V.G., Giménez, M., Ruiz, F., Martínez, P., Bottesi, G., Ramos, V.A., Neogene to Quaternary extensional reactivation of a fold and thrust belt: the Agrio belt in the Southern Central Andes and its relation to the Loncopué trough (38°-39°S) (2010) Tectonophysics, 92 (1-4), pp. 279-294
  • Sierra, J., D'Amore, F., Panarello, H., Pedro, G., Reservoir characteristics of the vapour dominatred geothermal field of Copahue, Neuquén, Argentina, as established by isotopic and geochemical techniques (1990) Final Proc. Nuclear Techniques in Geothermal Resources Investigation, San José, Costa Rica, pp. 13-30. , Geothermal Investigations with Isotope and Geochemical Tecniques in Latin America
  • Sinclair, A.J., Selection of threshold values in geochemical data using probability graphs (1974) J. Geochem. Explor., 3, pp. 129-149
  • Sierra, J., D'Amore, F., Panarello, H., Pedro, G., (1992) Reservoir characteristics of the vapour dominated geothermal field of Copahue, Neuquén, Argentina, as established by isotopic and geochemical techniques, , Geothermal Investigations with Isotope and Geochemical Tecniques in Latin America. Final Proc. Nuclear Techniques in Geothermal Resources Investigation. San José, Costa Rica, 13-30
  • Tamburello, G., Agusto, M., Caselli, A., Tassi, F., Vaselli, O., Calabrese, S., Rouwet, D., Aiuppa, A., Intense magmatic gas leakage through the Copahue crater lake (2015) J. Geophys. Res., , (in press)
  • Tassi, F., Agusto, M., Vaselli, O., Chiodini, G., Geochemistry of the magmatic-hydrothermal fluid reservoir of Copahue volcano (Argentina): insights from the chemical and isotopic features of fumarolic discharges (2015) Copahue Volcano: The Smoking Mountain Between Argentina y Chile, , Springer International Publishing AG, (accepted for publication), F. En Tassi, O. Vaselli, A. Caselli (Eds.)
  • Varekamp, J.C., The volcanic acidification of glacial Lake Caviahue, Province of Neuquen (2008) Argentina, 178, pp. 184-196
  • Varekamp, J.C., Ouimette, A.P., Herman, S.W., Flynn, K.D., Bermudez, A., Delpino, D., Naturally acid waters from Copahue volcano, Argentina (2009) Applied Geochemistry, 24, pp. 208-220
  • Varekamp, J.C., Ouimette, A., Hermán, S., Bermúdez, A., Delpino, D., Hydrothermal element fluxes from Copahue, Argentina: a "beehive" volcano in turmoil (2001) Geology, 29 (11), pp. 1059-1062
  • Werner, C., Cardellini, C., Comparison of carbon dioxide emissions with fluid upflow, chemistry, and geologic structures at the Rotorua geothermal system, New Zealand (2006) Geothermics, 35, pp. 221-238
  • Yuan, X., Asch, G., Bataille, K., Bock, G., Bohm, M., Echtler, H., Kind, R., Wölbern, I., Deep seismic images of the Southern Andes (2006) GSA Special Paper, 407, pp. 61-72. , K.S. Ramos VA (Ed.) Evolution of the Andean Margin: a Tectonic and Magmatic View from the Andes to the Neuquen Basin (35°-39°S)

Citas:

---------- APA ----------
Chiodini, G., Cardellini, C., Lamberti, M.C., Agusto, M., Caselli, A., Liccioli, C., Tamburello, G.,..., Caliro, S. (2015) . Carbon dioxide diffuse emission and thermal energy release from hydrothermal systems at Copahue-Caviahue Volcanic Complex (Argentina). Journal of Volcanology and Geothermal Research, 304, 294-303.
http://dx.doi.org/10.1016/j.jvolgeores.2015.09.007
---------- CHICAGO ----------
Chiodini, G., Cardellini, C., Lamberti, M.C., Agusto, M., Caselli, A., Liccioli, C., et al. "Carbon dioxide diffuse emission and thermal energy release from hydrothermal systems at Copahue-Caviahue Volcanic Complex (Argentina)" . Journal of Volcanology and Geothermal Research 304 (2015) : 294-303.
http://dx.doi.org/10.1016/j.jvolgeores.2015.09.007
---------- MLA ----------
Chiodini, G., Cardellini, C., Lamberti, M.C., Agusto, M., Caselli, A., Liccioli, C., et al. "Carbon dioxide diffuse emission and thermal energy release from hydrothermal systems at Copahue-Caviahue Volcanic Complex (Argentina)" . Journal of Volcanology and Geothermal Research, vol. 304, 2015, pp. 294-303.
http://dx.doi.org/10.1016/j.jvolgeores.2015.09.007
---------- VANCOUVER ----------
Chiodini, G., Cardellini, C., Lamberti, M.C., Agusto, M., Caselli, A., Liccioli, C., et al. Carbon dioxide diffuse emission and thermal energy release from hydrothermal systems at Copahue-Caviahue Volcanic Complex (Argentina). J. Volcanol. Geotherm. Res. 2015;304:294-303.
http://dx.doi.org/10.1016/j.jvolgeores.2015.09.007