In continuation of the study of the structure of boron hydrodihalides, calculations have been made of the fundamental vibration frequencies of dibromoborane. Using the available experimental infra-red data we have made the assignment of the stretching frequencies of BBr and BH, as well as the bending frequencies of HBBr, BrBBr and out-of-plane, using a consistent system of force constants and interatomic distances, taking the angles as 120° and assuming a planar structure. The calculations show a satisfactory interpretation of the experimental spectrum. © 1965.
Documento: | Artículo |
Título: | Vibrational assignments and force constants of dibromoborane |
Autor: | de Mandirola, O.B.; Westerkamp, J.F. |
Filiación: | Departamento de Física, FCEN, Universidad de Buenos Aires, Argentina |
Año: | 1965 |
Volumen: | 21 |
Número: | 6 |
Página de inicio: | 1101 |
Página de fin: | 1103 |
Título revista: | Spectrochimica Acta |
ISSN: | 03711951 |
Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03711951_v21_n6_p1101_deMandirola |