Artículo
Iglesias, L.E.; Baldessari, A. "Lipase-catalyzed alcoholysis of 2-thioacetoxyethyl acetate" (1998) Anales des la Asociacion Quimica Argentina. 86(3-6):203-207
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Abstract:
Lipase-catalyzed alcoholysis of 2-thioacetoxyethyl acetate is described. Results depended on the biocatalyst, the nucleophile and the substrate/nucleophile ratio. When the reaction of the diester was carried out with one equivalent of 1-octanol under Candida antarctica lipase catalysis, it was found that 2-mercaptoethyl acetate is mainly obtained through S-acetyl removal.
Registro:
| Documento: | Artículo |
| Título: | Lipase-catalyzed alcoholysis of 2-thioacetoxyethyl acetate |
| Autor: | Iglesias, L.E.; Baldessari, A. |
| Filiación: | Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria, 1428 Buenos Aires, Argentina |
| Año: | 1998 |
| Volumen: | 86 |
| Número: | 3-6 |
| Página de inicio: | 203 |
| Página de fin: | 207 |
| Título revista: | Anales des la Asociacion Quimica Argentina |
| ISSN: | 03650375 |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03650375_v86_n3-6_p203_Iglesias |
Referencias:
- Wong, C.H., Whitesides, G.M., (1994) Tetrahedron Organic Chemistry Series, 12, p. 41. , Enzymes in synthetic organic chemistry (J.E. Baldwin Ed.), Pergamon
- Koskinen, A.M.P., Klibanov, A.M., (1996) Enzymatic Reactions in Organic Media, , Chapman & Hall, Glasgow
- Palmer, D.C., Terradas, F., (1994) Tetrahedron Lett., 35, p. 1673
- Baldessari, A., Bruttomesso, A.C., Gros, E.G., (1996) Helv.Chim.Acta, 79, p. 999
- Baldessari, A., Maier, M.S., Gros, E.G., (1995) Tetrahedron Lett., 36, p. 4349
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- Baldessari, A., Iglesias, L.E., Gros, E.G., (1992) J.Chem.Research, p. 204
- Baldessari, A., Iglesias, L.E., Gros, E.G., (1994) Biotechnol.Lett., 16, p. 479
- Iglesias, L.E., Baldessari, A., Gros, E.G., (1996) Bioorg.Med.Chem.Lett., 6, p. 853
- Iglesias, L.E., Baldessari, A., Gros, E.G., (1998) An.Asoc.Quim.Argent., 86, p. 63
- Iglesias, L.E., Baldessari, A., Gros, E.G., (1998) Biotechnol.Lett., 20, p. 275
- Baldessari, A., Iglesias, L.E., Gros, E.G., (1993) J.Chem.Research, p. 382
- Harding, J.S., Owen, L.N., (1954) J.Chem.Soc., p. 1528
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- Ogino, K., Fujihara, H., (1992) Organic Sulfur Chemistry: Biochemical Aspects, p. 72. , p. 72, CRC Press, Boca Raton, Florida
- Reference 2, p. 240; Moggridge, R.C.G., (1946) J.Chem.Soc., p. 1105
Citas:
---------- APA ----------
Iglesias, L.E. & Baldessari, A. (1998) . Lipase-catalyzed alcoholysis of 2-thioacetoxyethyl acetate. Anales des la Asociacion Quimica Argentina, 86(3-6), 203-207.Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03650375_v86_n3-6_p203_Iglesias [ ]
---------- CHICAGO ----------
Iglesias, L.E., Baldessari, A. "Lipase-catalyzed alcoholysis of 2-thioacetoxyethyl acetate" . Anales des la Asociacion Quimica Argentina 86, no. 3-6 (1998) : 203-207.Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03650375_v86_n3-6_p203_Iglesias [ ]
---------- MLA ----------
Iglesias, L.E., Baldessari, A. "Lipase-catalyzed alcoholysis of 2-thioacetoxyethyl acetate" . Anales des la Asociacion Quimica Argentina, vol. 86, no. 3-6, 1998, pp. 203-207.Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03650375_v86_n3-6_p203_Iglesias [ ]
---------- VANCOUVER ----------
Iglesias, L.E., Baldessari, A. Lipase-catalyzed alcoholysis of 2-thioacetoxyethyl acetate. 1998;86(3-6):203-207.Available from: https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03650375_v86_n3-6_p203_Iglesias [ ]
