Abstract:
Transesterification reactions have been performed in systems in which both acyl acceptor and acyl donor are carbohydrates with the same skeleton. Basic catalysis proved to be much more efficient than nucleophylic catalysis. Partially acetylated sugar derivatives have been prepared by selective deacylation of peracetylated glycosides, using transesterification between a peracetylated sugar and a non-protected carbohydrate. This method compares favourably with known regioselective acylation methods.
Registro:
Documento: |
Artículo
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Título: | Transesterification between acetylated and free carbohydrates |
Autor: | Leit, S.; Moradei, O.; Du Mortier, C.; Fernandez Cirelli, A. |
Filiación: | Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria, 1428, Buenos Aires, Argentina
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Año: | 1997
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Volumen: | 85
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Número: | 1-2
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Página de inicio: | 87
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Página de fin: | 90
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Título revista: | Anales des la Asociacion Quimica Argentina
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ISSN: | 03650375
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03650375_v85_n1-2_p87_Leit |
Referencias:
- Moradei, O., Leit, S., Du Mortier, C., Fernández Cirelli, A., Thiem, J., (1993) J. Carbohydr. Chem., 12, p. 13
- Ogawa, T., Matsui, M., (1981) Tetrahedron, 35, p. 2363
- Koch, K., Chambers, R., (1993) Carbohydr. Res., 241, p. 2295
- David, S., Hanessian, B., (1985) Tetrahedron, 41, p. 643
- Sugimara, J.M., (1953) Adv. Carbohydr. Chem., 8, p. 1
- Haines, A.H., (1976) Adv. Carbohydr. Chem., 33, p. 11
- Roush, W.R., Russo-Rodríguez, S., (1985) J. Org. Chem., 50, p. 3224
- Taber, D.F., Amedio Jr., J.C., Patel, Y.K., (1985) J. Org. Chem., 50, p. 3618
- Bollenbach, G.N., (1962) Methods in Carbohydr. Chem., 2, p. 326
- Wolfrom, M.L., Thompson, J., (1962) Methods in Carbohydr. Chem., 2, p. 211
Citas:
---------- APA ----------
Leit, S., Moradei, O., Du Mortier, C. & Fernandez Cirelli, A.
(1997)
. Transesterification between acetylated and free carbohydrates. Anales des la Asociacion Quimica Argentina, 85(1-2), 87-90.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03650375_v85_n1-2_p87_Leit [ ]
---------- CHICAGO ----------
Leit, S., Moradei, O., Du Mortier, C., Fernandez Cirelli, A.
"Transesterification between acetylated and free carbohydrates"
. Anales des la Asociacion Quimica Argentina 85, no. 1-2
(1997) : 87-90.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03650375_v85_n1-2_p87_Leit [ ]
---------- MLA ----------
Leit, S., Moradei, O., Du Mortier, C., Fernandez Cirelli, A.
"Transesterification between acetylated and free carbohydrates"
. Anales des la Asociacion Quimica Argentina, vol. 85, no. 1-2, 1997, pp. 87-90.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03650375_v85_n1-2_p87_Leit [ ]
---------- VANCOUVER ----------
Leit, S., Moradei, O., Du Mortier, C., Fernandez Cirelli, A. Transesterification between acetylated and free carbohydrates. 1997;85(1-2):87-90.
Available from: https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03650375_v85_n1-2_p87_Leit [ ]