Artículo
Abstract:
The kinetics of hydrogen evolution reaction (HER) was studied on nickel catalysts prepared using a ruthenium spontaneous deposition method. Rotating disk electrode (RDE) and electrochemical impedance spectroscopy (EIS) were used for electrochemical characterization, and the results of the analysis were compared with pure nickel catalysts. Three different deposition times were used to obtain different ruthenium loads and to analyze their impact on the electrocatalytic activity. Kinetic and thermodynamic parameters of the reaction were obtained for freshly synthesized catalysts, and also for catalysts aged using a short chronoamperometric procedure. The presence of ruthenium was found to shift the reaction onset potential up to about 160 mV to lower overpotentials comparing with pure nickel, which not increases after ageing, showing a substantial improvement in catalytic activity. Results of Tafel and Koutecky-Levich (K-L) analysis have shown that the HER rate determining step is the Volmer reaction with Langmuir type adsorption for both, Ni/Ru fresh and aged catalysts. © 2015 Hydrogen Energy Publications, LLC.
Registro:
| Documento: | Artículo |
| Título: | Kinetics of hydrogen evolution reaction on nickel modified by spontaneous Ru deposition: A rotating disk electrode and impedance spectroscopy approach |
| Autor: | Franceschini, E.A.; Lacconi, G.I.; Corti, H.R. |
| Filiación: | Departamento de Física de la Materia Condensada, Centro Atómico Constituyentes, Comisión Nacional de Energía Atómica, Av. Gral. Paz 1499 (B1650KNA) San Martín, Buenos Aires, Argentina INFIQC-CONICET, Dto. de Fisicoquímica - Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, Ciudad Universitaria, 5000, Córdoba, Argentina Departamento de Química Inorgánica, Analítica y Química Física and INQUIMAE-CONICET, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón II, C1428EHA, Buenos Aires, Argentina |
| Palabras clave: | Hydrogen generation; Impedance spectroscopy; Nickel/ruthenium; Rotating disk electrode; Spontaneous deposition; Catalyst activity; Catalysts; Deposition; Electrochemical electrodes; Electrochemical impedance spectroscopy; Electrodes; Hydrogen production; Kinetics; Nickel; Reaction kinetics; Ruthenium; Spectroscopy; Spectrum analysis; Electrocatalytic activity; Electrochemical characterizations; Hydrogen evolution reactions; Hydrogen generations; Impedance spectroscopy; Kinetic and thermodynamic parameters; Rotating disk electrodes; Spontaneous deposition; Rotating disks |
| Año: | 2015 |
| DOI: | http://dx.doi.org/10.1016/j.ijhydene.2015.12.143 |
| Título revista: | International Journal of Hydrogen Energy |
| Título revista abreviado: | Int J Hydrogen Energy |
| ISSN: | 03603199 |
| CODEN: | IJHED |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03603199_v_n_p_Franceschini |
Citas:
---------- APA ----------
Franceschini, E.A., Lacconi, G.I. & Corti, H.R. (2015) . Kinetics of hydrogen evolution reaction on nickel modified by spontaneous Ru deposition: A rotating disk electrode and impedance spectroscopy approach. International Journal of Hydrogen Energy.http://dx.doi.org/10.1016/j.ijhydene.2015.12.143
---------- CHICAGO ----------
Franceschini, E.A., Lacconi, G.I., Corti, H.R. "Kinetics of hydrogen evolution reaction on nickel modified by spontaneous Ru deposition: A rotating disk electrode and impedance spectroscopy approach" . International Journal of Hydrogen Energy (2015).http://dx.doi.org/10.1016/j.ijhydene.2015.12.143
---------- MLA ----------
Franceschini, E.A., Lacconi, G.I., Corti, H.R. "Kinetics of hydrogen evolution reaction on nickel modified by spontaneous Ru deposition: A rotating disk electrode and impedance spectroscopy approach" . International Journal of Hydrogen Energy, 2015.http://dx.doi.org/10.1016/j.ijhydene.2015.12.143
---------- VANCOUVER ----------
Franceschini, E.A., Lacconi, G.I., Corti, H.R. Kinetics of hydrogen evolution reaction on nickel modified by spontaneous Ru deposition: A rotating disk electrode and impedance spectroscopy approach. Int J Hydrogen Energy. 2015.http://dx.doi.org/10.1016/j.ijhydene.2015.12.143
